An antistatic transparent hardened film

A hardening film and anti-static technology, applied in the direction of chemical instruments and methods, synthetic resin layered products, layered products, etc., can solve the problems of opacity, affecting the visual effect of products, affecting the transparency of hard coatings, etc., to achieve non-interference texture, superior total light transmittance effect

Active Publication Date: 2016-04-20
HEFEI LUCKY SCI & TECH IND +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1. Prevent static electricity on the surface of the hardened film by adding metal oxide conductive particles to the hardened layer. However, this method needs to add a large amount of conductive particles to the hardened layer to meet the anti-static requirements. Due to the general conductive metal oxidation The substance is heavily colored and opaque, and the addition of a large number of conductive particles seriously affects the transparency of the hard coat
[0005] 2. Adopt a double-layer structure, that is, set an antistatic layer on the hard coat layer. Although this method ensures the transparency of the hardened film, the difference in the refractive index between the two coatings will cause the surface of the film to be damaged. Obvious rainbow-like interference patterns, the existence of such interference patterns will seriously affect the visual effect of the product and affect the application of the product

Method used

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  • An antistatic transparent hardened film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] 1. Preparation of titanium dioxide dispersion:

[0039] 20 parts by weight of nano titanium dioxide and 80 parts by weight of butanone were mixed together, dispersed on a high-speed mixer for 30 minutes, then ball milled for 1 hour with a ball mill, and filtered to obtain titanium dioxide with an average particle size of 0.8 μm and a solid content of 20%. Dispersions.

[0040] 2. Preparation of coating material for transparent hardened layer

[0041] 6195-1009.6 parts by weight,

[0042] 1840.4 parts by weight,

[0043] 12.0 parts by weight of titanium dioxide dispersion,

[0044] Byk-3770.05 parts by weight,

[0045] Butanone 27.87 parts by weight,

[0046] Dissolve 9.6 parts by weight of aliphatic urethane acrylate prepolymer 6195-100 [Changxing Chemical; functionality 10] into 27.87 parts by weight of methyl ethyl ketone solvent, add 0.05 parts by weight of polyether-modified polydimethylsiloxane fluid Leveling agent BYK-377 [Bick Chemical], and add 0.40 parts ...

Embodiment 2

[0057] 1. Preparation of zirconia dispersion:

[0058] 20 parts by weight of nano zirconia and 80 parts by weight of butanone were mixed together, dispersed on a high-speed mixer for 30 minutes, then ball milled for 1.5 hours with a ball mill, and filtered to obtain a solid content of 20% and an average particle size of 0.6 μm. Zirconia dispersion.

[0059] 2. Preparation of coating material for transparent hardened layer

[0060] UXE10009.0 parts by weight,

[0061] 1840.4 parts by weight,

[0062] Zirconia dispersion 15.0 parts by weight,

[0063] Levaslip4320.05 parts by weight,

[0064] Butanone 25.5 parts by weight,

[0065] Dissolve 9.0 parts by weight of aliphatic urethane acrylate prepolymer UXE1000 [manufactured by Huayao Chemical (Wuxi) Co., Ltd., functionality 4] into 25.5 parts by weight of methyl ethyl ketone, add 0.05 parts by weight of polydimethylsiloxane Skeleton structure leveling agent Levaslip432 [manufactured by Deqian (Shanghai) Chemical Co., Ltd.],...

Embodiment 3

[0076] 1. Preparation of zinc sulfide dispersion:

[0077] 20 parts by weight of nano-zinc sulfide and 80 parts by weight of butanone were mixed together, dispersed on a high-speed mixer for 40 minutes, then ball milled for 1.5 hours with a ball mill, and filtered to obtain a solid content of 20% and an average particle size of 0.4 μm. Zinc sulfide dispersion.

[0078] 2. Preparation of coating material for transparent hardened layer

[0079] EM-24118.4 parts by weight,

[0080] 1840.4 parts by weight,

[0081] 18.0 parts by weight of zinc sulfide dispersion,

[0082] BYK-3770.05 parts by weight,

[0083] Butanone 23.13 parts by weight,

[0084]Dissolve 8.4 parts by weight of ethoxylated pentaerythritol tetraacrylate monomer EM-2411 [Changxing Chemical, functionality 4] into 23.13 parts by weight of methyl ethyl ketone solvent, add 0.05 parts by weight of polyether modified polydimethylsiloxane flow Leveling agent BYK-377 [Bick Chemical], and add 0.40 parts by weight of ...

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Abstract

The invention discloses an anti-static transparent hardening membrane which comprises a base material, a transparent hardening layer and an anti-static layer; a transparent hardening layer containing resin A and micro particles with the particle size of 0.01-1 micro meter as well as formed by solidified film forming of coating liquid is coated on the surface of the base material; an anti-static layer containing resin B and conducting particles as well as formed by solidified film forming of coating liquid is coated on the surface of the transparent hardening layer, and the thickness of the anti-static layer is 0.03-1 micro meter; and the difference between the refractive index of the transparent hardening layer and the refractive index of the anti-static layer is controlled within the range of -0.05-0.05. The anti-static transparent hardening membrane provided by the invention has the characteristics of high full-light-ray light transmissivity, shallow interference lines, superior damage resistance and the like, can effectively prevent static electricity generated by ultrahigh surface resistance of the hardening membrane, and can be widely applied to the field of screen protection.

Description

technical field [0001] The invention relates to an antistatic transparent hardened film used on a display screen. Background technique [0002] With the popularity of tablet computers and large-screen smart phones, touch screens are widely used in various fields. However, in the process of using the touch screen, since the touch screen is often operated with hands, it is easy to stain or scratch the touch screen. Therefore, a hardened film is generally attached to the surface of the screen. However, due to the surface resistance of the hardened film itself is generally 1 × 10 14 More than Ω, it is easy to accumulate charge and generate static electricity. Static electricity has a great impact on the touch screen, which affects the operation accuracy of the touch screen, and even damages the touch screen in serious cases. Therefore, anti-static treatment is generally performed on the hardened film. [0003] In the prior art, in order to prevent static electricity on the s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B27/08B32B27/18B32B33/00
Inventor 刘玉磊王志坚于佩强宋朝辉侯峰
Owner HEFEI LUCKY SCI & TECH IND
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