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Method for increasing content of asphaltene in low-asphaltene raw materials

A technology of asphaltene content and asphaltene, which is applied in the direction of processing tar pitch/petroleum pitch/natural pitch by distillation, processing tar pitch/petroleum pitch/natural pitch by chemical methods, and only multi-stage series refining and cracking process treatment, etc. , which can solve the problems of difficult production of SBS modified asphalt and reduction of colloid content

Active Publication Date: 2014-08-06
PETROCHINA CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0015] The object of the present invention is to provide a method for increasing the asphaltene content in low-asphaltene raw materials, which can increase the asphaltene content in low-asphaltene raw materials, reduce the colloid content, optimize the composition, and solve the problem of using low-asphaltene raw materials to produce SBS Difficult problems of modified asphalt

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The deoiled asphalt with an asphaltene content of less than 0.5% is used as the raw material, heated to 390 ℃ by a heating furnace, and then enters a thermal cracking fractionation tower, where it stays for 60 minutes, and the thermally cracked oil is subjected to vacuum fractionation to obtain an atmospheric boiling point greater than 440 ℃. The residue at the bottom of the tower is used as a blending component with high asphaltene content. Its asphaltene content is 6.37%, the gum content is 35.07%, the softening point is 45.8°C, and the penetration is 85 (1 / 10mm), which will account for 74% of the total weight of the base asphalt raw material. % of the blending component is mixed with road asphalt that accounts for 26% of the total weight of the base asphalt raw material to prepare a base asphalt, the base asphalt penetration is 93 (1 / 10mm), and the ductility (15°C, 5cm / min) It is greater than 150cm and the softening point is 48.5℃. The base asphalt meets the technical...

Embodiment 2

[0027] The deoiled asphalt with an asphaltene content of less than 0.5% is used as the raw material, heated to 390 ℃ by a heating furnace, and then enters a thermal cracking fractionation tower, where it stays for 50 minutes, and the thermally cracked oil is subjected to vacuum fractionation to obtain a normal pressure boiling point greater than 450 ℃. The residue at the bottom of the tower is used as a blending component with high asphaltene content. Its asphaltene content is 5.05%, the gum content is 35.85%, the softening point is 45.0°C, and the penetration is 90 (1 / 10mm), which will account for 84% of the total weight of the base asphalt raw material. % of the blended component is mixed with road asphalt that accounts for 16% of the total weight of the base asphalt raw material to form a base asphalt, the penetration of which is 98 (1 / 10mm), and the ductility (15°C, 5cm / min) is greater than 150cm, softening point of 47.2 ℃, the base asphalt meets the technical requirements ...

Embodiment 3

[0029] The deoiled asphalt with an asphaltene content of less than 0.5% is used as the raw material, heated to 400 ℃ in a heating furnace, and then enters the thermal cracking fractionation tower, where it stays for 50 minutes. The bottom residue is used as a high asphaltene content blending component, and its asphaltene content is 8.92%, colloid content is 34.11%, softening point is 51.2°C, and penetration is 71 (1 / 10mm), which will account for 94% of the total weight of matrix asphalt raw materials. % of the blending component and 6% of the total weight of the raw material are mixed with a high aromatic hydrocarbon solvent to prepare a matrix pitch, the penetration is 95 (1 / 10mm), and the ductility (15°C, 5cm / min) is greater than 150cm , the softening point is 48.6 ℃, the base asphalt meets the technical requirements of JTG F40-2004 road petroleum asphalt in the "Technical Specification for Highway Asphalt Pavement Construction" of the Ministry of Communications, so as to mee...

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Abstract

The invention relates to a method for increasing the content of asphaltene in low-asphaltene raw materials. The method comprises the following steps of: heating residual oil or deoiled asphalt, and then enabling the heated residual oil or deoiled asphalt to enter a thermal cracking factional distillation column to obtain thermal cracking produced oil, wherein the heating temperature ranges from 390 DEG C to 450 DEG C; and carrying out reduced-pressure factional distillation on the thermal cracking produced oil to obtain column bottom residues for blending matrix asphalt used for producing modified asphalt, wherein the residual oil is reduced-pressure residual oil with the atmospheric boiling point being higher than 350 DEG C, the reduced-pressure residual oil is obtained after gasoline, coal diesel and lubricating oil components are separated from thick crude oil through atmospheric and reduced-pressure distillation, and the residual oil contains 0.1-0.5% of asphaltene and 45-55% of colloid; or the residual oil is deoiled asphalt obtained after a heavy lubricating oil component is removed through solvent deasphalting, and the deoiled asphalt contains 0.1-0.5% of asphaltene and 50-60% of colloid. By using the method, the content of the asphaltene in the low-asphaltene raw materials is increased from 0.1-0.5% to 5-20%.

Description

technical field [0001] The present invention relates to a method for increasing the asphaltene content in low (0.1-0.5%) asphaltene raw materials, and more particularly, relates to a method for increasing the asphaltene content in matrix asphalt produced from low asphaltene raw materials. Background technique [0002] Asphalt is a hydrocarbon mixture composed of various hydrocarbons. The family structure of asphalt determines the physical and chemical properties of asphalt products and their performance. Usually people use silica gel-alumina adsorption chromatography to separate the chemical composition of asphalt into four components: saturate, aromatic, colloid and asphaltene, commonly known as the four-component method. As the core of asphalt colloid solution, asphaltene is dispersed in other components of asphalt and forms a stable colloid system, which is an important component of asphalt. Many properties of asphalt are related to the content of asphaltenes. According...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10C3/02C10C3/06C10G55/04
Inventor 杨克红熊良铨汪军平蔺习雄毛三鹏甄新平秦本记王华
Owner PETROCHINA CO LTD