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Environmentally-friendly low-transparency type absolute black alumina silicate glass

A silicate glass, low-transparency technology, applied in the field of pure black high-alkali aluminosilicate glass system, can solve problems such as restricting product yield, ink scratching and falling off, and affecting appearance effects.

Inactive Publication Date: 2013-05-15
BEIJING UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The black frame is for shading and decoration. It is necessary to print black glass ink on the back of the glass multiple times, and then bake or bake the ink to make it solidify on the glass surface, but the mechanical strength is not very strong. It needs to be handled with care, otherwise it will easily cause the ink to scratch and fall off, which will affect the appearance effect. In addition, the printing process of black ink is very complicated, and the printing process is polluting. In addition, the yield rate of the product is greatly restricted. Therefore, it is necessary to A product that combines decorative and mechanical strength with black glass instead of ink on the surface of transparent glass
[0005] If the environmental protection requirements of glass are not considered, the black color of ordinary soda-lime-silica glass is easy to achieve. Usually, iron oxide, chromium oxide, copper oxide, and nickel oxide are used together to form a black colorant for glass, but based on RoHS regulations are harmful to electronic products Cr 6+ Therefore, the black colorant of traditional soda lime silica glass cannot be popularized and applied
[0006] In addition, the application of V in the lithium aluminum silicon glass-ceramic system 2 o 5 The method of showing black after glass crystallization has been widely used on induction cooker panels, but V 2 o 5 It is also listed as a toxic and harmful oxide, so the black coloring principle cannot be applied and promoted

Method used

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  • Environmentally-friendly low-transparency type absolute black alumina silicate glass

Examples

Experimental program
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Effect test

Embodiment 1

[0026] The glass composition of the present invention is composed of basic glass and coloring agent, the total amount is 100%; wherein, the chemical composition of basic glass is (wt%): SiO 2 50.00, Al 2 o 3 7.00, Na 2 O 15.00, K 2 O 1.00, CaO 2.80, MgO 4.00, TiO 2 12.00, CeO 2 0.20; black colorant chemical composition (wt%): MnO 6.50, Fe 2 o 3 0.45, CoO 0.25, NiO 0.00, CuO 0.80. After annealing treatment, after cutting 1mm slices and grinding and polishing, the average visible light transmittance is 1.8%, after crystallization treatment, the visible light transmittance is 1.4%, and the CIE Lab values ​​are 18.23, -0.33, -1.08 respectively. From the results of Implementation 1, compared with the traditional non-environmentally friendly black glass of Comparative Example 1, the visible light transmittance after annealing decreased by 21.6% (23.4% in Comparative Example 1), and the visible light transmittance after crystallization treatment Reduced by 17.2% (Comparat...

Embodiment 2- Embodiment 6

[0028] The chemical composition of the glass of the present invention is as shown in Table 1, and the test results of Example 2-Example 6 are also shown in Table 1, and their color and spectral index are all better than Comparative Example 1, and have chemically enhanced material conditions, Therefore, I will not repeat them one by one.

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Abstract

The invention relates to lining plates of electronic display products and frame side protection and decorative glass materials, and in particular to environmentally-friendly low-transparency type absolute black alumina silicate glass. The environmentally-friendly low-transparency type absolute black alumina silicate glass is characterized by consisting of basic glass and a coloring agent; according to the 100 percent of weight percentage, the coloring agent is prepared from the following components in percentage by weight: 1-8 percent of MnO, 0-3.5 percent of Fe2O3, 0.2-0.8 percent of C0O, 0-3 percent of NiO and 0.2-2.5 percent of CuO; the basic glass is prepared from the components in percent by weight: 50-75 percent of SiO2, 5-16 percent of Al2O3, 5-15 percent of Na2O, 0-5 percent of K2O, 0.5-4 percent of MgO, 0.5-8 percent of CaO, 4-12 percent of TiO2 and 0.2-0.5 percent of CeO. The alumina silicate glass is high in decoration property, has basic chemical compositions which can be chemically intensified and processed, and can be used for promoting the chemical compositions to realize high mechanical strength, including compressive strength, bending strength, impact resistance, abrasion resistance and scratch resistance.

Description

technical field [0001] The invention relates to a glass material for protecting and decorating substrate plates and frame edges of electronic display products, which is a pure black high-alkali aluminosilicate glass system with environmental protection and low transmittance. The glass material has excellent mechanical properties and decorative properties, and can be used to replace engineering plastics in electronic display products or ordinary glass coated with black ink, in which electronic display products include plasma TVs, LCD TVs, LCD monitors, laptop LCD monitors, tablet computers , smartphones, PDAs, etc. Background technique [0002] With the development of modern electronic display technology, a large number of flat-panel electronic display products have emerged, including plasma TVs, LCD TVs, LCD monitors, LCD monitors for notebook computers, tablet computers, smart phones, PDA, PSP, information inquiry machines, media advertisements player etc. Generally, the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C3/095
Inventor 田英良吴德龙孙诗兵姚晓丹
Owner BEIJING UNIV OF TECH
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