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Visible-light-responded photocatalyst Ba2Ti3Nb4O18 and preparation method thereof

A photocatalyst and visible light technology, used in chemical instruments and methods, physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, etc., can solve the problem of poor stability, low light conversion efficiency, and no visible light response. Photocatalytic performance and other problems, to achieve the effect of low cost, simple preparation method and excellent catalytic performance

Active Publication Date: 2013-09-25
安徽上阡科技信息咨询有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005]Although photocatalytic research has been carried out for several years, the types of photocatalysts with visible light response reported are still very limited, and there are still low photoconversion efficiency and poor stability. Therefore, it is necessary to research and develop new high-efficiency photocatalysts with visible light response.
The existing literature [D. Guo, Z. Ling, X. Hu, Ceram. Int. 34, 1931 (2008)] reported that niobate ceramics Ba 2 Ti 3 Nb 4 o 18 preparation and microwave dielectric properties, but there is no research report on the photocatalytic properties of this type of compound. 2 Ti 3 Nb 4 o 18 、Ba 2 Ti 3 Ta 4 o 18 、Sr 2 Ti 3 Ta 4 o 18 and Sr 2 Ti 3 Ta 4 o 18 Niobium and tantalate carried out photocatalytic performance research, and found that Ba 2 Ti 3 Nb 4 o 18 Has excellent photocatalytic performance in response to visible light, but other components do not have photocatalytic performance in response to visible light

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] (1) 99.9% analytically pure chemical raw material BaCO 3 、TiO 2 and Nb 2 o 5 , press Ba 2 Ti 3 Nb 4 o 18 Chemical formula weighing ingredients.

[0019] (2) Mix the raw materials prepared in step (1), put them into a ball mill jar, add zirconia balls and absolute ethanol, ball mill for 8 hours, mix and grind until fine, take it out and dry it, and pass through a 200-mesh sieve.

[0020] (3) Pre-fire the uniformly mixed powder in step (2) at 1150°C, keep it warm for 6 hours, cool it down to room temperature naturally, and then pulverize it with a ball mill to make the particle diameter smaller than 2 μm, and you can get Ba niobate 2 Ti 3 Nb 4 o 18 powder.

[0021] The prepared photocatalyst can remove 96.5% of methyl orange in 120 minutes under the irradiation of visible light with a wavelength greater than 420nm.

Embodiment 2

[0023] (1) 99.9% analytically pure chemical raw material BaCO 3 、TiO 2 and Nb 2 o 5 , press Ba 2 Ti 3 Nb 4 o 18 Chemical formula weighing ingredients.

[0024] (2) Mix the raw materials prepared in step (1), put them into a ball mill jar, add zirconia balls and absolute ethanol, ball mill for 8 hours, mix and grind until fine, take it out and dry it, and pass through a 200-mesh sieve.

[0025] (3) Pre-fire the uniformly mixed powder in step (2) at 1180°C, keep it warm for 6 hours, cool it down to room temperature naturally, and then use a ball mill to reduce the particle diameter to less than 2 μm to obtain Ba niobate 2 Ti 3 Nb 4 o 18 powder.

[0026] The prepared photocatalyst can remove 98.2% of methyl orange in 120 minutes under the irradiation of visible light with a wavelength greater than 420nm.

Embodiment 3

[0028] (1) 99.9% analytically pure chemical raw material BaCO 3 、TiO 2 and Nb 2 o 5 , press Ba 2 Ti 3 Nb 4 o 18 Chemical formula weighing ingredients.

[0029](2) Mix the raw materials prepared in step (1), put them into a ball mill jar, add zirconia balls and absolute ethanol, ball mill for 8 hours, mix and grind until fine, take it out and dry it, and pass through a 200-mesh sieve.

[0030] (3) Pre-fire the uniformly mixed powder in step (2) at 1200°C, keep it warm for 6 hours, cool it down to room temperature naturally, and then pulverize it with a ball mill to make the particle diameter smaller than 2 μm to obtain Ba niobate 2 Ti 3 Nb 4 o 18 powder.

[0031] The prepared photocatalyst can remove 98.1% of methyl orange in 120 minutes under the irradiation of visible light with a wavelength greater than 420nm.

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Abstract

The invention discloses a visible-light-responded niobate photocatalyst Ba2Ti3Nb4O18 and a preparation method thereof. The chemical composition formula of the niobate photocatalyst is Ba2Ti3Nb4O18. The invention further discloses the preparation method of the photocatalyst. According to the photocatalyst and the preparation method thereof, the preparation method is simple and is low in cost, and the prepared photocatalyst has excellent catalysis performance, plays a role in decomposing harmful chemical substances under the irradiation of visible light and is good in stability, thereby having good application prospects.

Description

technical field [0001] The present invention relates to a kind of photocatalyst Ba of visible light response 2 Ti 3 Nb 4 o 18 The invention and a preparation method thereof belong to the field of inorganic photocatalytic materials. Background technique [0002] With the development of society and economy, people pay more and more attention to energy and ecological environment. Solving the problems of energy shortage and environmental pollution is an urgent need to achieve sustainable development, improve people's quality of life and ensure national security. [0003] Since the late 1970s, people have proposed the use of photocatalysts to decompose organic substances such as pesticides and odorous substances in water and the atmosphere, and self-cleaning of solid surfaces coated with photocatalysts. The principle of photocatalytic reaction is that after the photocatalyst absorbs photons higher than its bandgap energy, holes and electrons are generated, and these holes and...

Claims

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Application Information

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IPC IPC(8): B01J23/20
Inventor 方亮唐莹韦珍海
Owner 安徽上阡科技信息咨询有限公司