Lithium ion battery negative electrode sheet and battery comprising electrode sheet
A technology for lithium-ion batteries and negative pole pieces, applied in non-aqueous electrolyte battery electrodes, secondary batteries, circuits, etc., can solve problems such as reducing battery costs, achieve the effect of improving rate performance and improving charge and discharge rate performance
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Embodiment 1
[0022] Example 1, Such as figure 1 As shown, a negative pole piece of a lithium ion battery, the negative pole piece 1 is provided with a crack structure, the opening of the crack structure is arranged on the surface layer of the pole piece, and the surface density of the crack 3 of the crack structure is 100m / mm 2 , the width of the crack 3 is 5um, the length of the crack 3 is 5um, the cross-sectional shape of the crack 3 is triangular, and the thickness of the pole piece is completely penetrated by the crack 3. The used negative pole piece 1 is to adopt graphite as the active material, and the distribution ratio of each component in the negative pole piece 1 is, graphite: superconducting carbon: sodium carboxymethyl cellulose: styrene-butadiene rubber=96%:1.0%:1.0%: 2.0%. The negative electrode sheet 1 is cold-pressed (compaction density 1.70g / cc), and assembled with the positive electrode sheet, separator, electrolyte and packaging bag to form a finished battery cell. I...
Embodiment 2
[0023] Example 2, Such as figure 2 As shown, the difference from Example 1 is: the surface density of the crack 3 of this example is 1000m / mm 2 , the width of the crack 3 is 12um, the length of the crack 3 is 8um, the cross-sectional shape of the crack 3 is trapezoidal, and the thickness of the pole piece is completely penetrated by the crack 3. The negative electrode sheet 1 used uses silicon as the active material, and is prepared by stirring according to the negative electrode formula (silicon: superconducting carbon: sodium carboxymethyl cellulose: styrene-butadiene rubber = 96%: 1.0%: 1.0%: 2.0%) to obtain the negative electrode slurry, and then the negative electrode slurry is coated on the copper foil current collector to prepare the negative electrode sheet, and then the negative electrode sheet is cold-pressed (the compaction density is 1.70g / cc), and the positive electrode sheet, separator, electrolyte and The packaging bag is assembled into a finished cell.
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Embodiment 3
[0025] Example 3, Such as image 3 Shown, and embodiment 2 is different: the surface density of the crackle 3 of this embodiment is 10m / mm 2 , the width of the crack 3 is 1um, the length of the crack 3 is 9um, the cross-sectional shape of the crack 3 is rectangular, and the thickness of the pole piece is not completely penetrated by the crack. The negative pole piece 1 used is to adopt silicon-carbon alloy as the active material, and the distribution ratio of each component in the negative pole piece 1 is, silicon-carbon alloy: superconducting carbon: sodium carboxymethyl cellulose: styrene-butadiene rubber=96%:1.0% :1.0%:2.0%. After the negative pole piece 1 is cold-pressed (compaction density 1.70g / cc), it is assembled with the positive pole piece, separator, electrolyte and packaging bag to form a finished battery cell.
[0026] Others are the same as in Embodiment 2 and will not be repeated here.
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