Electrolyte capable of improving security property of lithium ion battery

A lithium-ion battery, safety performance technology, applied in the field of lithium-ion batteries, can solve problems such as combustion and explosion, battery thermal breakdown, safety hazards, etc., to ensure cycle performance, meet high safety requirements, and avoid combustion and explosion Effect

Inactive Publication Date: 2014-05-07
TECHN CENT FOR SAFETY OF INDAL PRODS TIANJIN ENTRY EXIT INSPECTION QUARANTINE BUREAU
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Organic electrolyte is the carrier of ion movement in lithium-ion batteries, mainly for lithium-ion secondary batteries, which release a lot of heat under the conditions of high-temperature heating, over-charging and discharging, short-circuit and high-current working for a long time, and these heat become flammable The safety hazard of the electrolyte may cause catastrophic thermal breakdown (thermal collapse) and combustion of the battery, and even cause the battery to explode
At present, lithium-ion batteries usually use an electrolyte mixed with an electrolyte lithium salt LiPF6 (lithium hexafluorophosphate) and an organic solvent. The application of this electrolyte may cause the above-mentioned potential safety hazards. Thermal stability, to avoid the burning and explosion of batteries under overheating conditions, effectively improve the safety performance of batteries, and improve the use of safe electrolytes for batteries

Method used

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  • Electrolyte capable of improving security property of lithium ion battery
  • Electrolyte capable of improving security property of lithium ion battery
  • Electrolyte capable of improving security property of lithium ion battery

Examples

Experimental program
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Embodiment 1

[0012] Embodiment 1: See Table 1, the percentages by weight of the components of the electrolyte solution of the present invention are: solid solute LiBOB: 12.0%, ethylene carbonate EC: 29.9%, propylene carbonate PC: 5.5%, ethyl methyl carbonate EMC : 44%, vinylene carbonate VC: 1.1%, ethylene ethylene carbonate VEC: 0.5%, propylene sulfite PS: 3%, tributyl phosphate TBP: 4%.

Embodiment 2

[0013] Embodiment 2: Referring to Table 1, the weight percentages of the components of the electrolyte of the present invention are: solid solute LiBOB: 12.5%, ethylene carbonate EC: 24.4%, propylene carbonate PC: 9.5%, ethyl methyl carbonate EMC : 45%, vinylene carbonate VC: 1.1%, ethylene ethylene carbonate VEC: 0.5%, propylene sulfite PS: 3%, tributyl phosphate TBP: 4%.

Embodiment 3

[0014] Embodiment 3: Referring to Table 1, the percentage by weight of each component of the electrolyte solution of the present invention is: solid solute LiBOB: 13.0%, ethylene carbonate EC: 26%, propylene carbonate PC: 9.5%, ethyl methyl carbonate EMC : 42.5%, vinylene carbonate VC: 1.1%, ethylene ethylene carbonate VEC: 0.5%, propylene sulfite PS: 3%, tributyl phosphate TBP: 4%.

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Abstract

The invention discloses an electrolyte capable of improving the security property of a lithium ion battery. The electrolyte is prepared by mixing of electrolyte salt, organic solvents and additives, wherein the electrolyte salt is solid solvent LiBOB; the organic solvents are ethylene carbonate EC, propylene carbonate PC and ethyl methyl carbonate EMC; the additives are vinylene carbonate VC, vinyl ethylene carbonate VEC, trimethylene sulfite PS and tributyl phosphate TBP. By using the novel electrolyte salt and the functional additives, the thermal stability of the lithium ion battery is improved, on premise of ensuring the battery circulation property, the security property of the battery is effectively improved, and the problems that the battery is combusted and exploded under an overheating condition are avoided. By applying the electrolyte, the reliability and the security of the lithium ion battery are improved, the quality of the lithium ion battery is greatly improved, and the market application prospect of products of battery production factories is improved, so that the successful development of the novel electrolyte has great production practice significance.

Description

technical field [0001] The invention relates to lithium-ion battery technology, in particular to an electrolyte capable of improving the safety performance of the lithium-ion battery. Background technique [0002] At present, lithium-ion batteries have the advantages of high specific energy, high voltage, many cycle times, and long storage time. They are not only widely used in portable electronic devices, such as mobile phones, digital cameras and laptop computers, but also widely used in electric Large and medium-sized electric equipment such as automobiles, energy storage, electric bicycles, and electric tools. [0003] With the continuous expansion of the lithium-ion battery market, safety issues are an important prerequisite for innovation in the lithium-ion battery market. Organic electrolyte is the carrier of ion movement in lithium-ion batteries, mainly for lithium-ion secondary batteries, which release a lot of heat under the conditions of high-temperature heat...

Claims

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Application Information

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IPC IPC(8): H01M10/0567
CPCH01M10/0525H01M10/0567H01M10/4235H01M2300/0025Y02E60/10
Inventor 贾晓川李晶于智睿孙俐丁宇张彬王娜
Owner TECHN CENT FOR SAFETY OF INDAL PRODS TIANJIN ENTRY EXIT INSPECTION QUARANTINE BUREAU
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