Insulated and flame-retardant nylon composite material with high thermal conductivity and preparation method thereof

A flame-retardant nylon and composite material technology, applied in the field of intelligent polymer materials, can solve the problems of poor flame-retardant effect, limited application, non-insulation, etc., and achieve the effects of simple and easy preparation process, excellent mechanical properties, and good insulation

Active Publication Date: 2014-05-14
ZHONGSHAN DIANSHI PLASTIC
View PDF3 Cites 20 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004]2) The processing efficiency of metal parts is low. Generally, it needs to be cut or machined from bulk materials into the required complex shapes, requiring special machining equipment, and the unit cost Relatively high;
[0005]3) The density of metal materials is relatively high, usually greater than 2.4g/cm3, resulting in relatively bulky products;
[0006]4) Metals are more susceptible to corrosion than plastic materials;
[0007]5) Metal processing requires relatively high temperature and relatively large energy consumption
Nylon, the first of engineering plastics, is widely used for its excellent performance. Conventional engineering plastics, including thermoplastic and thermosetting plastics, have the advantages of good mechanical properties, chemical stability, electrical insulation, etc., and are widely used in daily electrical appliances and other shells, etc. field, but because of its low thermal

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Insulated and flame-retardant nylon composite material with high thermal conductivity and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0045] A preparation method of high thermal conductivity insulating flame retardant nylon composite material, comprising the following steps:

[0046] 1) Soak magnesium nitride in an ethanol solution with a mass percentage of 1-3% silane coupling agent KH560 for 3-8 minutes, and volatilize to remove ethanol;

[0047] 2) Melt extrusion and granulation of nylon 6 and magnesium nitride treated in step 1) through a twin-screw extruder to obtain thermally conductive master batches;

[0048] 3) Melt extrusion and granulation of nylon 66 and glass fiber through a twin-screw extruder to obtain a reinforced masterbatch;

[0049] 4) Mix ultra-fine light magnesium carbonate, light magnesium oxide, magnesium hydroxide and 1-3% KH560 ethanol solution in a high-speed mixer for 3-8 minutes at a temperature of 50-70°C;

[0050] 5) Add the thermally conductive masterbatch and the reinforced masterbatch into the high-speed mixer in step 4), and mix for 25-30 minutes at a temperature of 50-70°C...

Example Embodiment

[0055] Example 1

[0056] 1) Soak the magnesium nitride in an ethanol solution with a mass percentage of 2% KH560 for 5 minutes, and volatilize to remove the ethanol;

[0057] 2) Melt extrusion and granulation of nylon 6 and magnesium nitride treated in step 1) through a twin-screw extruder to obtain thermally conductive master batches;

[0058] 3) Melt extrusion and granulation of nylon 66 and glass fiber through a twin-screw extruder to obtain a reinforced masterbatch;

[0059] 4) Mix ultrafine light magnesium carbonate, light magnesium oxide, magnesium hydroxide and 2% KH560 ethanol solution in a high-speed mixer for 5 minutes at a temperature of 60°C;

[0060] 5) Add the thermally conductive masterbatch and the reinforced masterbatch to the high-speed mixer in step 4), mix for 25 minutes, and the temperature is 60°C;

[0061] 6) Place the raw material, elastomer and antioxidant mixed in step 5) in a twin-screw extruder, melt extrusion and granulation to obtain a high th...

Example Embodiment

[0065] Example 2

[0066] 1) Soak the magnesium nitride in an ethanol solution with a mass percentage of 2% KH560 for 5 minutes, and volatilize to remove the ethanol;

[0067] 2) Melt extrusion and granulation of nylon 6 and magnesium nitride treated in step 1) through a twin-screw extruder to obtain thermally conductive master batches;

[0068] 3) Melt extrusion and granulation of nylon 66 and glass fiber through a twin-screw extruder to obtain a reinforced masterbatch;

[0069] 4) Mix ultrafine light magnesium carbonate, light magnesium oxide, magnesium hydroxide and 2% KH560 ethanol solution in a high-speed mixer for 8 minutes at a temperature of 60°C;

[0070] 5) Add the thermally conductive masterbatch and the reinforced masterbatch to the high-speed mixer in step 4), mix for 25 minutes, and the temperature is 60°C;

[0071] 6) Place the raw material, elastomer and antioxidant mixed in step 5) in a twin-screw extruder, melt extrusion and granulation to obtain a high t...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
The average particle sizeaaaaaaaaaa
The average particle sizeaaaaaaaaaa
The average particle sizeaaaaaaaaaa
Login to view more

Abstract

The invention discloses an insulated and flame-retardant nylon composite material with high thermal conductivity. The insulated and flame-retardant nylon composite material comprises the following components in parts by weight: 10-20 parts of nylon 6, 10-25 parts of nylon 66, 10-25 parts of magnesium nitride, 5-10 parts of super fine light magnesium carbonate, 5-15 parts of light magnesium oxide, 5-30 parts of magnesium hydroxide, 5-8 parts of fiberglass, 1-5 parts of elastomers, 0.1-0.5 part of coupling agents, and 0.1-0.5 part of antioxidants. The preparation method comprises the following steps: respectively preparing heat-conducting masterbatch and enhanced masterbatch from the nylon 6, the magnesium nitride, the nylon 66 and the fiberglass; adding to a mixture of the magnesium carbonate, the magnesium oxide, the magnesium hydroxide and the coupling agent; and evenly mixing, and adding the elastomers and the antioxidants to pelletize, so as to obtain the composite material. The material has the thermal conductivity of 25W/mk, the fire resistance of UL-94V-0 grade, good insulativity, and excellent mechanical property, and the requirements of the market on the materials with high thermal conductivity and high flame retardancy can be met.

Description

technical field [0001] The invention relates to the technical field of intelligent polymer materials, in particular to a high thermal conductivity insulating flame-retardant nylon composite material and a preparation method thereof. Background technique [0002] With the high-speed and high-power operation of various electronic components, relatively high temperatures will be generated during the use and operation of the equipment, which may cause overheating of electronic components and damage their performance, resulting in reduced reliability, or even a substantial reduction lifetime of the entire system. As we all know, metal materials have very good thermal conductivity, and the products are not easy to burn. They have been used in heat dissipation components of semiconductor device components. However, metals have the following potential disadvantages: [0003] 1) Metal is a good conductor of electricity. In many applications, based on safety considerations, it is des...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08L77/06C08L77/02C08K13/06C08K9/06C08K3/28C08K3/26C08K3/22C08K7/14C08J3/22B29C47/92B29C48/92
CPCB29C48/92B29C2948/92552B29C2948/9258B29C2948/92704C08K2201/003C08K2201/011C08L77/02C08L77/06C08L2201/02C08L2201/22C08L2203/20C08L2205/03C08L23/0815C08K13/06C08K9/06C08K3/28C08K2003/267C08K2003/222C08K2003/2224C08K7/14C08L53/02B29C48/04B29C48/40B29C48/625B29C2948/9259B29C2948/92885B29C2948/92895
Inventor 王可王毅侯筱华
Owner ZHONGSHAN DIANSHI PLASTIC
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products