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Molybdenum-alloy-film and indium-oxide-film etching-solution composition

An oxide film, molybdenum alloy technology, applied in the field of etching solution composition, can solve the problems of low engineering time and durability of etching equipment, poor pixels, and difficult to wet etching, etc., to improve copper corrosion inhibition performance, improve reliability and, The effect of stable etching process

Active Publication Date: 2014-06-25
ENF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] When using the same etchant to etch the above-mentioned molybdenum alloy film and indium oxide film, although the manufacturing process can be simplified, generally speaking, the chemical resistance of the molybdenum alloy film is good, and there is a problem that wet etching is not easy; in addition, in order to etch the indium oxide film The oxalic acid series etchant used in the film cannot etch the molybdenum alloy film
[0004] In the prior art, Korean Patent Publication No. 2008-0045853, Patent Publication No. 2008-0045854, and Patent Publication No. 2008-0107502 disclose a kind of etching solution, but using the etching solution of prior art to molybdenum When the alloy film and the indium oxide film are etched, a chemical reaction occurs between the etchant and the metal film, and precipitates are generated, causing problems such as defective pixels
In addition, there are problems such as reduced etching equipment construction time and durability during continuous use.
In addition, the corrosion suppression performance of the copper film used for the source and drain of the lower TFT is not complete, so that a part of the copper mold is corroded, and the yield of the whole part is low, etc.

Method used

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  • Molybdenum-alloy-film and indium-oxide-film etching-solution composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1 to 20 and comparative example 1 to 4

[0032] Embodiment 1 to 20 and comparative example 1 to 4: the manufacture of etchant composition

[0033] The contents of the components listed in Table 1 below were mixed to prepare the compositions of Examples 1 to 20 and Comparative Examples 1 to 4 of the present invention. The composition content of the following table Table 1 is the value of % by weight.

[0034] Table 1

[0035]

[0036]

[0037] TAZ: Triazole (Triazole)

[0038] IDA: iminodiacetic acid

experiment example

[0039] Experimental example: Etching performance test of etching solution composition

[0040] In order to evaluate the effect of etching solution of the present invention, deposit respectively on the glass substrate as the thickness of molybdenum alloy film: The molybdenum-titanium alloy film, the thickness of the indium oxide film is The indium tin oxide film and the thickness of the copper-molybdenum alloy film are The molybdenum-titanium alloy film and thickness are The copper film is then subjected to photolithography to make a patterned test piece.

[0041] Etching was performed on a sprayable device (Mini-etcher ME-001) using the etching solution compositions of Examples 1 to 20 and the etching solution compositions of Comparative Examples 1 to 3. Table 2 shows the results of observing residues generated on the molybdenum alloy film and indium oxide film, corrosion of the copper film, and the like with a scanning electron microscope (manufactured by Hitachi Group...

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Abstract

The present invention relates to an etching-solution composition for a molybdenum alloy film and an indium oxide film, and relates to an etching-solution composition for a molybdenum alloy film, an indium oxide film or a multilayer film of a molybdenum alloy film and an indium oxide film, wherein the composition comprises, with respect to the total weight of the composition, between 5 and 25 wt.% of hydrogen peroxide, between 0.1 and 2 wt.% of a corrosion inhibitor, between 0.1 and 2 wt.% of a fluorine-containing compound, between 0.1 and 2 wt.% of a chlorine-containing compound, between 0.1 and 5 wt.% of a hydrogen peroxide stabilizer and water to make the total weight of the entire composition up to 100 wt.%. The aim of the present invention is to provide an etching-solution composition which controls the production of precipitates when etching a molybdenum alloy film, an indium oxide film or a multilayer film of a molybdenum alloy film and an indium oxide film used in a TFT-LCD pixel electrode, such that the durability of etching equipment can be improved and the corrosion of copper used as the source and drain of a lower TFT is minimised.

Description

technical field [0001] The invention relates to a molybdenum alloy film and an indium oxide film used for molybdenum alloy film and indium oxide film used on TFT-LCD pixel electrodes. An etchant composition for multiple films of an oxide film or a molybdenum alloy film and an indium oxide film. Background technique [0002] Single films such as molybdenum alloy films and indium oxide films or multiple films of molybdenum alloy films and indium oxide films are used on pixel electrodes of semiconductor devices and liquid crystal displays such as TFT-LCDs. The pixel electrode is generally laminated on the substrate by sputtering and other methods, and photoresist is evenly applied on it, and then imaged after light irradiation through a thin film engraved with a pattern, so that the required pattern photoresist Imaging is completed by a series of photolithography processes such as dry etching or wet etching, after displaying patterns on the metal film under the photoresist, an...

Claims

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Application Information

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IPC IPC(8): C23F1/44C23F1/26C23F1/30
CPCC23F1/44C23F1/26C23F1/30
Inventor 申孝燮金世训李恩庆柳炫圭
Owner ENF TECH