Functional electrolyte for preventing overcharge of lithium battery and production method of functional electrolyte
A production method and electrolyte technology, which are applied in the manufacture of secondary batteries, electrochemical generators, and electrolyte batteries, can solve the problems of battery sequential performance and storage life, low lithium ion conductivity, etc., and achieve increased storage performance, Good cycle performance and the effect of improving high temperature cycle performance
Active Publication Date: 2014-09-10
SHIJIAZHUANG SAN TAI CHEM CO LTD
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Problems solved by technology
However, the film's relatively low conductivity to lithium ions can lead to a significant decrease in the battery's sequential performance and storage life.
Method used
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Experimental program
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Effect test
Embodiment 1
[0031] Add 45ml EC, 45ml DME, and 10ml PC to a clean container in turn; after cooling down to room temperature, add 22.79g LiBF to the above mixture 6 The concentration of the substance is 1.5mol / L; after standing clarification, add 13.92g VC (for EC, DME, PC and LiBF) after 3 hours 6 The total weight percentage is 1%); after standing for 6 hours.
Embodiment 2
[0033] After adding 13.92g of VC in Example 1, 7.66g of 2,3,4-trifluorobiphenyl (5% by weight of the base electrolyte) was added, and the rest were the same as in Example 1.
Embodiment 3
[0035] After adding 13.92g VC in embodiment 1, add 7.66g PST (the weight percent with base electrolyte is 5%), and the rest is the same as embodiment 1.
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The invention provides functional electrolyte for preventing the overcharge of a lithium battery and a production method of the functional electrolyte. The functional electrolyte comprises basic electrolyte and a functional additive, wherein the basic electrolyte comprises a carbonic ester type mixed solvent, lithium hexafluorophosphate and vinylene carbonate; the carbonic ester type mixed solvent comprises ethylene carbonate, ethyl methyl carbonate and propylene carbonate; the functional additive comprises 2, 3, 4-trifluorobiphenyl and 1, 3-propene sulfonic acid lactone. The production method comprises the following steps: adding the ethylene carbonate, the ethyl methyl carbonate and the propylene carbonate into a clean container in sequence; reducing the temperature to room temperature, and then adding the lithium hexafluorophosphate; standing for clarification, and then adding the vinylene carbonate, the 1, 3-propene sulfonic acid lactone and the 2, 3, 4-trifluorobiphenyl; and standing for clarification for spare use. The functional electrolyte provided by the invention has the advantages that the occurrence of the safety problems such as ignition and explosion caused by the overcharge of the lithium battery can be effectively prevented, so that the safety of the battery is improved, the high-temperature circulating performance of the lithium battery is improved, and the functional electrolyte is strong in applicability and can be used in multiple electro-chemical systems.
Description
technical field [0001] The invention relates to the technical field of lithium battery electrolytes, in particular to a functional electrolyte for preventing overcharge of lithium batteries and a production method thereof. Background technique [0002] Lithium batteries refer to batteries containing lithium in the electrochemical system. Since the birth of rechargeable lithium metal batteries in the 1990s, due to their superior safety, specific capacity, self-discharge rate and cost performance, they have been widely used in notebook computers, Mobile phones, digital cameras, mp3 players and other small electronic equipment and medical equipment, as a driving power supply. [0003] A lithium battery includes a positive electrode, a negative electrode, an electrolyte, and a separator. Lithium ions undergo oxidation and reduction reactions on the positive and negative electrodes to trigger electron intercalation and extraction to generate electrical energy. If the lithium bat...
Claims
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IPC IPC(8): H01M10/0567
CPCH01M10/0567H01M10/0569H01M10/058Y02E60/10
Inventor 刘鹏梅银平
Owner SHIJIAZHUANG SAN TAI CHEM CO LTD
