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Petroleum catalytic processing method

A catalytic processing and petroleum technology, which is applied in the petroleum industry, catalytic cracking, cracking, etc., can solve the problems of unsatisfactory product distribution and low yield of target products, so as to improve the distribution of cracked products, increase the yield, and increase the secondary cracking The effect of the reaction

Active Publication Date: 2014-10-01
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The purpose of the present invention is to provide a method for petroleum catalytic cracking processing to improve the problems of unsatisfactory product distribution and low yield of target products in the prior art

Method used

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Effect test

Embodiment 1

[0036] Using oil A (see Table 1 for its properties) as raw oil, the small riser reactor with catalyst inlets on the side wall and bottom is in contact with Y-15 catalytic cracking catalyst to undergo catalytic cracking reaction, and the raw material oil enters from the bottom inlet reactor. Among them, the side wall inlet is at the lower 1 / 4 position of the reactor, the catalyst flow ratio between the bottom inlet and the side wall inlet is 5:5, the carbon content of the catalyst at the bottom inlet is 0.44%, and the carbon content of the catalyst at the side wall inlet is 0.06%. The catalytic cracking process conditions are: the reactor outlet temperature is 498°C, the catalyst oil ratio is 4.5, the half regeneration temperature is 648°C, and the full regeneration temperature is 668°C. The distribution of catalytic cracking products is shown in Table 2.

Embodiment 2

[0041] Using oil B (see Table 1 for its properties) as feedstock oil, in a small riser reactor with catalyst inlets on the side wall and bottom, it contacts with the catalytic cracking catalyst of commercial brand DVR-3 to undergo catalytic cracking reaction. The bottom inlet enters the reactor. Among them, the side wall inlet is located in the lower 1 / 3 of the reactor, the catalyst flow ratio between the bottom inlet and the side wall inlet is 6:4, the carbon content of the catalyst at the bottom inlet is 0.52%, and the carbon content of the catalyst at the side wall inlet is 0.05%. The catalytic cracking process conditions are: the reactor outlet temperature is 498°C, the catalyst oil ratio is 4.5, the half regeneration temperature is 644°C, and the full regeneration temperature is 667°C. The distribution of catalytic cracking products is shown in Table 2. Comparative example 2

Embodiment 3

[0045] Using oil C (see Table 1 for its properties) as feedstock oil, in a small riser reactor with catalyst inlets on the side wall and bottom, it contacts with commercial brand CRC-1 catalytic cracking catalyst to undergo catalytic cracking reaction. The bottom inlet enters the reactor. Among them, the side wall inlet is at the lower 1 / 5 position of the reactor, the catalyst flow ratio between the bottom inlet and the side wall inlet is 4:6, the carbon content of the catalyst at the bottom inlet is 0.52%, and the carbon content of the catalyst at the side wall inlet is 0.05%. The catalytic cracking process conditions are: the reactor outlet temperature is 498°C, the catalyst oil ratio is 4.5, the half regeneration temperature is 698°C, and the full regeneration temperature is 732°C. The distribution of catalytic cracking products is shown in Table 2.

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Abstract

The invention relates to a petroleum catalytic processing method. The method comprises the following steps: contacting petroleum fraction with a catalyst to carry out reactions, separating the obtained product oil gas and the spent catalyst, carrying out fractionation on the product oil gas in a fractionating tower so as to obtain gas, a gasoline fraction, a diesel oil fraction, and a wax oil fraction; subjecting the spent catalyst to steam stripping, dividing the processed spent catalyst into two portions, transporting the two portions into two different regenerators, burning off the cokes on the spent catalyst respectively under a semi-regeneration condition and a complete regeneration condition so as to obtain a semi-regenerated catalyst and a completely-regenerated catalyst; transporting the semi-regenerated catalyst to the bottom of a cracking reactor, and transporting the completely-regenerated catalyst to the middle part of a reactor to carry out reactions with molecules of oil which rises from the bottom of the reactor and is pre-cracked. The petroleum catalytic processing method improves the distribution of cracking products, increases the yields of target products such as gasoline, and enlarges the raw material range of catalytic cracking reactions. Furthermore, the reconstruction investment is small, and the newly-built device will not occupy more ground area.

Description

technical field [0001] The invention relates to a catalytic cracking process of petroleum distillate under the condition of no hydrogen. The invention belongs to the field of petroleum refining. Background technique [0002] Catalytic cracking is a very important heavy oil lightening process in the oil refining industry, that is, the process of converting high-boiling hydrocarbons into more valuable low-boiling hydrocarbons such as gasoline under the action of catalysts and higher temperatures. Catalytic cracking includes processes such as cracking reaction, separation, stripping and regeneration. Conventional catalytic cracking raw oil is distillate oil with a boiling point between 325 and 600°C, usually straight-run wax oil and hydrocracked wax oil. As crude oil becomes heavier, the yield of light oil in the primary processing process of the oil refining industry decreases, and the raw material oil of the catalytic cracking unit is insufficient. deep processing. Moreov...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G11/00
Inventor 任文坡李振宇李雪静杨延翔朱庆云黄格省王红秋曲静波乔明李顶杰任静郑轶丹王春娇卢红朱雅兰
Owner PETROCHINA CO LTD