The invention discloses a preparation method of a modified mesoporous
silicon-aluminum material. The modified mesoporous
silicon-aluminum material has a pseudo-
boehmite physical structure. The
anhydrous chemical formula of the material by the weight of oxides is (0-8)P2O5(0-0.1)Na2O*(20-30)SiO2*(70-80)Al2O3(0-1.0)RE2O3. The specific area is 200 to 500 m2 / g, and the pore volume is 0.5 to 1.5 mL / g. The preparation method comprises the following steps: step one, adding a low-concentration aluminum source into a
silicon source solution, controlling the pH in a range of 10.3 to 10.8, and carrying out stationary aging for 0.5 to 3 hours; step two, adding
phosphor-aluminum gel and a high-concentration aluminum source into the previous solution according to a certain ratio, and controlling the pH in a range of 3.4 to 3.8; step three, adding a
rare earth solution according to a certain ratio; step four, adjusting the pH of the previous
slurry to 8.0-9.0 by an alkaline solution; step five, filtering the
slurry, and washing the solids by deionized water and
ammonium salt. The provided modified mesoporous silicon-aluminum material can be used as the carrier of FCC catalyst, has a proper pore volume and acidic property, and is capable of performing pre-
cracking on macromolecular raw oil. RE2O3 exists in a deposited state of oxides and can prevent the
metal pollution, so the provided material can improve the heavy oil
cracking performance of FCC catalyst, moreover, the hydrothermal stability of FCC catalyst is good, and the
coke selectivity is excellent.