The application belongs to the field of
petroleum refining
catalysis technology, and discloses a ZSM-5 additive for increasing propylene production and a preparation and use method thereof. In the method, waste filtrate prepared by using SAPO-34
molecular sieve is used to improve the stability of the
molecular sieve under a high-temperature water-containing
atmosphere, prevent the
molecular sieve channels from being blocked by excessive
phosphorus elements, reduce environmental
pollution caused by the waste filtrate, improve the specific surface area of the ZSM-5 additive and the stability of the product, realize the dual effects of the stabilization of the molecular
sieve by the
phosphorus elements and the protection of the organic
ammonium channels, complement the low-molecular-weight
ammonium polyacrylate, white
carbon black and
phosphorus aluminum binder, construct a hierarchical pore structure (micropore-mesopore-
macropore hierarchical pore), and then obtain the additive with a specific surface area of 150-170 m 2 / g, an addition amount of only 10 wt% can achieve a propylene
production effect better than that of 20 wt% of a commercially available additive, the catalyst procurement cost of a
refinery is greatly reduced, and the
slurry oil yield is reduced and the heavy oil
cracking capacity is improved.