Manufacturing method and device for transparent conductive film, sputtering target and transparent conductive film
A technology of a transparent conductive film and a manufacturing method, which can be used in cable/conductor manufacturing, sputtering coating, conductive layer on an insulating carrier, etc., can solve problems such as low solubility, difficulty in high etching selectivity, etc.
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Embodiment 1
[0102] A sputtering target in which 1.5 atomic % of dysprosium oxide was added to indium tin oxide (hereinafter also referred to as "Dy-added ITO target") was manufactured. Using this Dy-added ITO target, given by figure 1 The sputtering setup shown forms a film on a substrate with a thickness of ITO film (hereinafter also referred to as "Dy-added ITO film"). The film forming condition is set to DC power of 600W (1.16W / cm 2 ), the distance between the target and the substrate (T / S distance) is 100mm, the magnetic field of the magnet unit is 300G, and the film formation rate (dynamic rate) is m / min. A mixed gas of argon and oxygen was used as the sputtering gas, and a plurality of ITO film samples were formed by varying the oxygen partial pressure. Among them, the partial pressure of argon is set to 0.67Pa (200sccm), the partial pressure of oxygen is set to 0Pa, 1.33×10 -3 Pa, 2.66×10 -3 Pa, 5.32×10 -3 Pa, 7.98×10 -3 Pa, 1.06×10 -2 Pa.
[0103] For an oxygen partial...
Embodiment 2
[0105] A sputtering target in which 1 atomic % of boron oxide was added to indium tin oxide (hereinafter also referred to as "B-added ITO target") was manufactured. Using this B-added ITO target, an ITO film (hereinafter also referred to as "B-added ITO film") was formed under the same conditions as in Example 1. For the formed B-added ITO film, the etching rate, resistivity, light transmittance, and X-ray diffraction intensity before and after annealing were measured under the same conditions as in Example 1.
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