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Preparation method of glass ceramic

A technology of glass ceramics and glass powder, which is applied in the field of glass ceramics preparation to achieve excellent optical properties and high insulation reliability

Inactive Publication Date: 2015-02-18
华文蔚
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] At present, the research on the luminescent properties of borosilicate glass by single rare earth ions is more common, however, there are few literature reports that can use the combination of multiple rare earth ions to study its influence on the luminescent properties of borosilicate glass; in addition, For the preparation method of glass ceramics, the smelting process is also mostly used, and there are few literature reports that the preparation of glass ceramics can be carried out by multiple heat treatments.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] (1) preparation comprises the first glass of following composition (mass %, by oxide):

[0032] 30% by mass of magnesium borosilicate glass powder, 30% of alumina filler powder, 30% by mass of Y 2 o 3 and 10% by mass of rare earth ion Ce / Eu, the magnesium borosilicate glass powder contains 68% by mass of SiO in terms of oxide 2 , 10 mass% B 2 o 3 , 10 mass% Al 2 o 3 , 22% by mass MgO. Wherein, the mole fractions of Ce and Eu are both 0.5%.

[0033] (2) The first heat treatment time at 650°C is 20h, and the second heat treatment time at 700°C is 68h.

[0034] According to tests, the crystallization rate of the glass phase in the ceramic sintered body obtained by sintering reaches 55% by volume ratio, and the high-refractive-index filler powder is a ceramic whose refractive index exceeds 1.95.

Embodiment 2

[0036] (1) preparation comprises the first glass of following composition (mass %, by oxide):

[0037] 32% by mass of magnesium borosilicate glass powder, 35% of alumina filler powder, 20% by mass of Y 2 o 3and 13% by mass of rare earth ion Ce / Eu mixture, the magnesium borosilicate glass powder contains 68% by mass of SiO in terms of oxide 2 , 10 mass% B 2 o 3 , 10 mass% Al 2 o 3 , 22% by mass MgO. Wherein, the molar fractions of Ce and Eu are both 1.0%.

[0038] (2) The first heat treatment time at 660°C is 22h, and the second heat treatment time at 750°C is 60h.

[0039] According to tests, the crystallization rate of the glass phase in the ceramic sintered body obtained by sintering reaches 52% by volume ratio, and the high-refractive-index filler powder is a ceramic whose refractive index exceeds 1.95.

Embodiment 3

[0041] (1) preparation comprises the first glass of following composition (mass %, by oxide):

[0042] 34% by mass of magnesium borosilicate glass powder, 38% of alumina filler powder, 16% by mass of Y 2 o 3 and 12% by mass of rare earth ions Ho / Tm / Yb, the magnesium borosilicate glass powder containing 60% by mass of SiO in terms of oxides 2 , 10 mass% B 2 o 3 , 10 mass% Al 2 o 3 , 20% by mass MgO. Wherein, the mole fractions of Ho, Tm and Yb are all 1.0%.

[0043] (2) The first heat treatment time at 680°C is 25h, and the second heat treatment time at 750°C is 70h.

[0044] According to the test, the crystallization ratio of the glass phase in the ceramic sintered body obtained by sintering reaches 53% by volume ratio, and the high-refractive-index filler powder is a ceramic whose refractive index exceeds 1.97.

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Abstract

The invention relates to a preparation method of glass ceramic. The method comprises the following steps: (1) preparing the following raw materials by mass percent: 30%-40% of magnesia borosilicate glass powder, 30%-50% of aluminum oxide filler powder, 10%-30% of Y2O3 and 10%-15% of rare earth ions, wherein the magnesia borosilicate glass powder contains 40%-70% of SiO2, 8%-25% of B2O3, 5%-30% of Al2O3 and 20%-30% of MgO; (2) performing heat treatment for the first time at 650-750 DEG C and performing heat treatment for the second time at 700-750 DEG C. A glass ceramic substrate prepared by the method is high in reflection rate, low in glass phase crystallization rate and excellent in luminous performance.

Description

technical field [0001] The invention relates to a method for preparing glass ceramics, in particular to a method for preparing glass ceramics applicable to optical glass. Background technique [0002] With the rapid development of information technology and optoelectronic technology, people pay more and more attention to the special properties of phosphors, which exist in the form of crystalline powder, single crystal, film, ceramics, glass, etc. Because glass has the advantages of being uniform, transparent, easy to process into various shapes, and can be doped at a higher concentration, it has gradually become a good matrix material for inorganic luminescence, and its use is becoming more and more extensive. [0003] Light sources are generally divided into discharge lamps and solid-state lamps, where heat radiators dominate in general lighting and automotive applications, such as halogen lamps. Additionally, solid state light sources in the form of luminescent radiators,...

Claims

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Application Information

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IPC IPC(8): C03C10/00
CPCC03C10/0045
Inventor 华文蔚
Owner 华文蔚
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