Anaerobic adhesive as well as preparation method and application thereof
An anaerobic adhesive and reaction technology, used in adhesives, modified epoxy resin adhesives, adhesive types, etc., can solve the problems of poor compatibility, poor impact toughness, low strength, etc., and achieve good toughness and resistance. Low temperature performance, simple and easy operation, and improved storage stability
An anaerobic adhesive and reaction technology, used in adhesives, modified epoxy resin adhesives, adhesive types, etc., can solve the problems of poor compatibility, poor impact toughness, low strength, etc., and achieve good toughness and resistance. Low temperature performance, simple and easy operation, and improved storage stability
CN104356992AActive Publication Date: 2015-02-18SUZHOU JINQIANG NEW MATERIALS
Examples
Experimental program
Comparison scheme
Effect test
Embodiment 1
[0039] The anaerobic adhesive in this example includes the following components by weight: 50 parts of modified methacrylic acid, 1 part of tert-butyl peroxide, 1 part of triethylamine, and 0.8 part of saccharin.
Embodiment 2
[0041] In this embodiment, the anaerobic adhesive includes the following components by weight: 70 parts of modified methacrylic acid, 3 parts of cumene hydroperoxide, 2.5 parts of N,N-dimethylaniline, and 1.5 parts of saccharin.
Embodiment 3
[0043] In this embodiment, the anaerobic adhesive includes the following components by weight: 100 parts of modified methacrylic acid, 5 parts of methyl ethyl ketone peroxide, 4 parts of triethanolamine, and 2 parts of saccharin.
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Abstract
The invention relates to the field of adhesives, in particular to an anaerobic adhesive and a preparation method of the anaerobic adhesive. The anaerobic adhesive comprises 40-100 parts of modified methacrylic acid, 0.8-5 parts of an initiator, 1-4 parts of an accelerant and 0.5-2 parts of an accelerant aid. According to the anaerobic adhesive, polyurethane modified epoxy resin is adopted to modify methacrylic acid, and the preparation method specifically comprises the following steps: adding the polyurethane modified epoxy resin into a reaction kettle, heating to be 60-65 DEG C, adding hydroquinone, adding methacrylic acid when hydroquinone is completely dissolved, continuously heating to be 70-80 DEG C, adding triethylamine, uniformly mixing, heating to be 80-85 DEG C, reacting for 1-3 hours, further heating to be 98-100 DEG C, and reacting for 2-4 hours, so as to obtain the modified methacrylic acid. The anaerobic adhesive provided by the invention is good in toughness and low-temperature resistance, and is also relatively high in tension strength, shearing resistance and impact resistance.
Description
technical field [0001] The invention relates to the field of adhesives, in particular to an anaerobic adhesive, a preparation method and an application. Background technique [0002] Anaerobic adhesives refer to solid polymers that do not solidify when in contact with oxygen or air, and quickly polymerize to become crosslinked once the air is shut off. The so-called "anaerobic" means that the glue is isolated from oxygen when in use. [0003] Anaerobic adhesives are mainly composed of acrylate monomers, initiators, accelerators, and stabilizers, and other additives such as fillers, dyes and pigments, thickeners, plasticizers, thixotropic agents, and ultraviolet light can also be added as needed. Absorbent etc. [0004] Acrylic monomers are the main components of anaerobic adhesives, accounting for more than 90% of its total proportion. Such monomers include acrylic acid, methacrylic acid diester or some special acrylates (methacrylic acid hydroxy Propyl ester), etc. [0...
Claims
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Patent Timeline
18 Feb 2015
Publication
CN104356992A
- IPC
- C09J163/10; C09J175/14; C09J11/06
- Inventors
- 曹建强