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Lead storage battery

A technology for lead-acid batteries and unit cells, which is applied in the direction of lead-acid batteries, electrodes of lead-acid batteries, construction of lead-acid batteries, etc. It can solve problems such as increased distance between the masking plate and the pole plate, reduced battery life, and difficulty in continuously increasing the capacity. , to reduce the possibility of short circuit, improve cycle life, and improve charging efficiency

Active Publication Date: 2015-04-15
松下蓄电池(沈阳)有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Chinese utility model patent CN201820837U discloses a kind of equal deflection plaster board for double-sided coating. The technical problem to be solved is: the working surface at the lower end of the existing plaster board is flat. The pressure makes the plate concave, the distance between the masking plate and the plate increases, and the amount of paste in the middle increases relatively. The raw plate after double-sided coating is often thicker in the middle and thinner on both sides, and the plate is seriously bent after curing. , affecting the quality of the plate
The technical problem to be solved by this method is: increase the porosity of the positive plate by reducing the paste density of the positive plate, thereby improving the rapid discharge characteristics of the sealed lead-acid battery, but in order to suppress the reduction of the life due to the reduction of the paste density , an aqueous dispersion of polytetrafluoroethylene added to the lead paste
Moreover, in the prior art, the design of the pole plate has also been considered and some methods have been found, for example, as mentioned above, by reducing the density of the lead paste of the positive plate to improve the porosity of the positive plate, thereby improving the performance of the sealed lead-acid battery. Rapid discharge characteristics, but reducing the density of the lead paste will lead to a decrease in battery life; or the thickness of the two ends of the plate is thinner than the middle part, so as to overcome the weak retention of the active material at the ends and the active material is easy to fall off. shortcoming
[0013] However, when the surface of the pole plate is flat and the thickness of the pole plate is the same, because more sulfuric acid cannot be stored to make the chemical reaction proceed more, the capacity is difficult to continue to increase, and it may not be able to reach the designed initial capacity
Moreover, when the surface of the electrode plate is flat and the thickness of the electrode plate is uniform, the distance between the positive electrode plate and the negative electrode plate is too small, there is a hidden danger of short circuit, which affects the cycle life
In addition, because the plate is too flat and the contact between the separator and the plate is too close, the oxygen generated by the positive plate at the end of charging cannot diffuse to the negative electrode in time, which affects the recombination of oxygen and reduces the charging efficiency.

Method used

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Examples

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Embodiment C)

[0075] (1) Manufacture of positive plate

[0076] The raw material lead powder (a mixture of lead and lead oxide), water, and dilute sulfuric acid were kneaded in a weight ratio of about 100:12:14 to obtain a positive electrode paste as a positive electrode active material.

[0077] On the other hand, a lead strip comprising a Pb alloy containing about 0.07% by mass Ca and about 1.3% by mass Sn obtained by casting was extruded to a thickness of 1.3 mm. like Figure 5 (a) and Figure 5Shown in (b), at first, carry out cutting and drawing process, use reciprocating stamping die to repeatedly carry out stamping to lead band 27, while forming a plurality of slits along the length direction of lead band, this slit is along with lead band surface The vertical direction is developed to form a mesh sheet having a grid 25 formed by interlacing a plurality of ruled lines. Then, the above-mentioned mesh sheet is shaped by a pair of rollers of a shaping mold to obtain an expanded mesh....

Embodiment D~I)

[0100] In Examples D to I, except that the thickness ratio H1 / H2 of the above-mentioned protrusions is set to a certain value in the range of 4% to 9%, the others are prepared according to the same setting conditions as in Example C. Plate groups and lead storage batteries.

Embodiment L

[0108] (Example L~O)

[0109] In Examples L~O, except that the density of the above-mentioned AGM separator is 117~129g / dm 3 Except that there are changes between them, the others are prepared according to the same setting conditions as in Example F to prepare the plate group and the lead storage battery.

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Abstract

This lead acid storage battery comprises a plurality of cells, each of which comprises an electrode plate group, an electrolyte solution and a cell chamber. The electrode plate group and the electrolyte solution are contained in the cell chamber. The electrode plate group is obtained by alternately arranging a plurality of positive electrode plates and a plurality of negative electrode plates with separators being interposed therebetween. The separators are AGM separators, and each separator has a density within the range of 117-129 g / dm3. The collectors of the positive electrode plates and / or the negative electrode plates are expanded grids, and each electrode plate is composed of projected end portions each having a projection and a flat intermediate portion between the end portions. The thickness of the end portions is larger than the thickness of the intermediate portion.

Description

technical field [0001] The present invention relates to a lead-acid storage battery, and specifically relates to a lead-acid storage battery excellent in all of life characteristics, charging efficiency characteristics, and high-rate discharge characteristics. Background technique [0002] Lead-acid batteries are not only used for starting vehicle power supply, lighting power supply and backup power supply, but also widely used for main power supply, that is, as a power supply for independent charging and discharging equipment such as electric vehicles, electric forklifts, electric forklifts, electric buses, electric bicycles, Power sources for electric motorcycles, electric scooters, small electric mopeds, golf carts, electric locomotives, etc., and electric energy storage devices such as solar batteries. In these applications, the working characteristics of lead-acid batteries are: large current when starting, small discharge current when driving, and long discharge time. ...

Claims

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Application Information

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IPC IPC(8): H01M4/14H01M2/14H01M50/437H01M50/489
CPCH01M4/14H01M4/73H01M10/12H01M50/44H01M50/437Y02E60/10Y02P70/50
Inventor 孙勤超吴昊阿部阳隆佐佐木健浩
Owner 松下蓄电池(沈阳)有限公司