PPR (polypropylene-random) water supply pipe material with high environmental stress cracking resistance and preparation method thereof

A technology for environmental stress resistance and water supply pipes, used in rigid pipes, pipes, mechanical equipment, etc., can solve the problems of low impact strength, poor resistance to environmental stress cracking, brittleness and easy cracking, etc. Effects of Environmental Stress Cracking

Active Publication Date: 2015-07-29
HENAN LIANSU IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the structure of the PP base material itself, at low temperatures, the pipes prepared from the PP base material have defects such as brittleness and cracking, poor environmental stress cracking resistance, and low impact strength, which seriously restrict The development of PPR pipes in the north, therefore, seeking a PPR water supply pipe with ultra-low temperature resistance and high environmental stress cracking resistance is still a technical problem that needs to be solved urgently.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A PPR water supply pipe with high resistance to environmental stress cracking performance, the PPR water supply pipe is composed of the following raw materials in parts by weight:

[0033] 15 parts of block copolymerized polypropylene PPB;

[0034] 65 copies of random copolymerized PPR;

[0035] 6 parts of low-cis polybutadiene rubber;

[0036] 6 parts of polyisobutylene;

[0037] 2 parts paraffin oil;

[0038] 0.3 parts of tert-butyl peroxy 2-ethylhexyl carbonate;

[0039] Antioxidant 0.3 parts.

[0040] The preparation method of the above-mentioned high environmental stress cracking resistance PPR water supply pipe specifically includes the following steps:

[0041] S1: Weigh each raw material according to the above formula;

[0042] S2: Add the low-cis polybutadiene rubber, polyisobutylene and antioxidant weighed in step S1 to the polymerization kettle for dissolution, then add block copolymerized polypropylene PPB, random copolymerized PPR, paraffin oil and in...

Embodiment 2

[0046] A PPR water supply pipe with high resistance to environmental stress cracking performance, the PPR water supply pipe is composed of the following raw materials in parts by weight:

[0047] 18 parts of block copolymerized polypropylene PPB;

[0048] 68 copies of random copolymerized PPR;

[0049] 7 parts of low-cis polybutadiene rubber;

[0050] 7 parts of polyisobutylene;

[0051] 3 parts paraffin oil;

[0052] 0.4 parts of tert-butyl peroxy 2-ethylhexyl carbonate;

[0053] Antioxidant 0.4 parts.

[0054] The preparation method of this embodiment is the same as that of Example 1.

Embodiment 3

[0056] A PPR water supply pipe with high resistance to environmental stress cracking performance, the PPR water supply pipe is composed of the following raw materials in parts by weight:

[0057] 19 parts of block copolymerized polypropylene PPB;

[0058] 70 copies of random copolymerized PPR;

[0059] 9 parts of low-cis polybutadiene rubber;

[0060] 9 parts of polyisobutylene;

[0061] 3 parts paraffin oil;

[0062] 0.4 parts of tert-butyl peroxy 2-ethylhexyl carbonate;

[0063] Antioxidant 0.4 part.

[0064] The preparation method of this embodiment is the same as that of Example 1.

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Abstract

The invention relates to a PPR (polypropylene-random) water supply pipe material with high environmental stress cracking resistance. The PPR water supply pipe material comprises raw materials in parts by weight as follows: 15-20 parts of PPB (polypropylene block copolymer), 65-75 parts of PPR, 6-10 parts of low-cis polybutadiene rubber, 6-10 parts of polyisobutene, 2-4 parts of paraffin oil, 0.3-0.5 parts of an initiator and 0.3-0.5 parts of an antioxidant. The invention further provides an application of the PPR water supply pipe material in preparation of PPR water supply pipes. The PPR water supply pipes prepared from the PPR water supply pipe material have excellent environmental stress cracking resistance, cold resistance and low-temperature toughness and can be used in an ultra-low-temperature environment, so that the use range of the PPR pipes is enlarged.

Description

technical field [0001] The invention relates to the technical field of plastic pipes, in particular to a PPR water supply pipe with high resistance to environmental stress cracking. Background technique [0002] The PPR pipe extruded from random copolymerized polypropylene (PPR) has good impact resistance, temperature resistance, creep resistance and good hot-melt welding performance, so it can be used as an environmentally friendly transportation pipe. Water pipes are widely used in building cold and hot water, pure water supply, heating and general industrial fluid pipes. However, due to the structure of the PP base material itself, at low temperatures, the pipes prepared from the PP base material have defects such as brittleness and cracking, poor environmental stress cracking resistance, and low impact strength, which seriously restrict With the development of PPR pipes in the north, it is still an urgent technical problem to seek a PPR water supply pipe with ultra-low ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/14C08L9/00C08L53/00C08L91/06F16L9/12
CPCC08L23/14C08L2201/08C08L2203/18C08L2205/035F16L9/12C08L53/00C08L9/00C08L23/22C08L91/06C08K5/14
Inventor 代营伟李锦松秦立臣王焱阮艳灵秦亚辉秦賀霞徐汝冰赵宏强
Owner HENAN LIANSU IND
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