A kind of preparation method of zero-valent iron ball
A technology of nano-zero-valent iron and iron balls, which is applied in the direction of nanotechnology, can solve the problems that nano-zero-valent iron cannot guarantee effective contact reaction, the processing efficiency of the treatment system is reduced, and nano-iron powder is difficult to separate, so as to achieve rapid decontamination Physical performance, high efficiency removal efficiency, and low cost of ball making
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Embodiment 1
[0066] A method for preparing zero-valent iron balls, comprising:
[0067] Ⅰ. Preparation of air-stable guar gum nanometer zero-valent iron powder:
[0068] A, prepare guar gum solution
[0069] Add food-grade guar gum solid powder into ultrapure water, then heat and stir to dissolve, and obtain a mass percentage of 0.05%.
[0070] of guar gum solution.
[0071] B. Deoxygenation
[0072] In a three-necked flask, 0.2780g FeSO 4 ·7H 2 O was mixed with 30ml of the above-mentioned guar gum solution, then passed into nitrogen deoxygenation for 20-40min, and mechanically stirred for 5-10min so as to mix uniformly to obtain a mixed solution;
[0073] C. Preparation of nano-iron solution
[0074] Weigh 0.2160g of KBH 4Add dropwise 1ml of NaOH solution with a concentration of 0.5mol / L, then add 20ml of the above-mentioned guar gum solution, and react for 30min under mechanical stirring to obtain a black nano-zero-valent iron solution;
[0075] D. Preparation of nano-sized zero-...
Embodiment 21
[0083] A method for preparing zero-valent iron balls. The difference from Example 1 is that the prepared iron balls are soaked in a deoxygenated absolute ethanol solution and stabilized for 12 hours after forming the balls.
Embodiment 22
[0085] A method for preparing zero-valent iron balls. The difference from Example 1 is that the prepared iron balls are immediately soaked in a deoxygenated absolute ethanol solution and stabilized for 18 hours after forming the balls.
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