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A kind of preparation method of lead-acid storage battery lead paste mixed with graphene

A lead-acid battery and graphene technology, applied in the direction of lead-acid battery electrodes, battery electrodes, circuits, etc., can solve problems such as difficulty in dispersion, failure to achieve charging and receiving capabilities, high-current charging and discharging performance, and graphene's inability to play, and achieve The effects of prolonging the service life, preventing the sulfation of the negative electrode, improving the charge receiving ability and high current charge and discharge performance

Active Publication Date: 2017-04-12
SINO INNOV SEMICON (PKU) CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the effective dispersion of carbon additives such as graphene in the active materials of lead-acid batteries has been a key factor that has plagued the development of lead-carbon batteries. Since the specific gravity of graphene is quite different from that of lead oxide powder in the active materials of lead-acid batteries, the powder Shaped graphene is very easy to agglomerate and difficult to disperse during the preparation of active materials; and graphene is a nano-material, it is difficult to achieve nano-scale dispersion in the ordinary lead-acid battery active material mixing method so that graphene can be fully dispersed in the active material. As a result, graphene cannot play its advantageous role, and the resulting lead-acid battery cannot achieve the above-mentioned purpose of greatly improving the charging receiving capacity and high-current charging and discharging performance, and prolonging the life of the lead-acid battery.

Method used

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  • A kind of preparation method of lead-acid storage battery lead paste mixed with graphene

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Experimental program
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Effect test

Embodiment 1

[0016] Embodiment 1, a kind of preparation method of the lead-acid storage battery lead paste that is mixed with graphene, it may further comprise the steps:

[0017] (1) Weigh 130 grams (1.65 parts) of polyvinylpyrrolidone PVP, sodium carboxymethylcellulose CMC, sodium lignosulfonate SLS or sodium dodecylbenzenesulfonate SDBS and add 8 kg (100 parts) of deionized In water and stir evenly in the high-speed stirring disperser 21, slowly add graphene powder containing 100 grams (1.25 parts) of pure graphene under stirring, the graphene average sheet thickness of the graphene powder is 3nm, and the content is 80%. The solution obtained after stirring for 5 minutes is the graphene aqueous dispersion. 3 is the feeding device of deionized water, 4 is the feeding device of aqueous dispersant, and 5 is the feeding device of graphene.

[0018] (2) Weigh 4 kg (40 parts) of sulfuric acid with a concentration of 98% and slowly add 10 kg (100 parts) of deionized water along the container ...

Embodiment 2

[0025] Embodiment 2, a kind of preparation method of the lead-acid storage battery lead paste that is mixed with graphene, it may further comprise the steps:

[0026] (1) Weigh 15 grams (0.1 part) of two of polyvinylpyrrolidone PVP, sodium carboxymethylcellulose CMC, sodium lignosulfonate SLS and sodium dodecylbenzenesulfonate SDBS and add 15 kilograms (100 part) deionized water and stir evenly in the high-speed stirring disperser 21, slowly add graphene powder containing 60 grams (0.5 parts) of pure graphene under stirring, the graphene average sheet thickness of the graphene powder is 1nm, The content is 99%, and the solution obtained after stirring for 5 minutes is the graphene aqueous dispersion. 3 is the feeding device of deionized water, 4 is the feeding device of aqueous dispersant, and 5 is the feeding device of graphene.

[0027](2) Weigh 3 kg (130 parts) of sulfuric acid with a concentration of 98% and slowly add 2.3 kg (100 parts) of deionized water along the conta...

Embodiment 3

[0033] Embodiment 3, a kind of preparation method of the lead-acid storage battery lead paste that incorporates graphene, it may further comprise the steps:

[0034] (1) Weigh 330 grams (3 parts) of three kinds of polyvinylpyrrolidone PVP, sodium carboxymethylcellulose CMC, sodium lignosulfonate SLS and sodium dodecylbenzenesulfonate SDBS and add 11 kilograms (100 part) in deionized water and stir evenly in the high-speed stirring disperser 21, slowly add graphene microflake powder containing 550 grams (5 parts) of pure graphene under stirring, the graphene microflake powder of this graphene microchip powder The average sheet thickness is 20nm, the content is 99.5%, and the solution obtained after stirring for 5 minutes is the graphene aqueous dispersion. 3 is the feeding device of deionized water, 4 is the feeding device of aqueous dispersant, and 5 is the feeding device of graphene.

[0035] (2) Weigh 4 kg (51 parts) of sulfuric acid with a concentration of 98% and slowly a...

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Abstract

The invention discloses a preparation method of a graphene-doped lead acid battery lead paste. The method comprises the following steps: adding 0.1-5 parts of aqueous disperser in 100 parts of deionized water, stirring at high speed and mixing, slowly adding 0.5-5 parts of graphene to prepare a graphene aqueous dispersion liquid; slowly adding 39-130 parts of sulfuric acid with concentration being 98% in 100 parts of deionized water to obtain dilute sulfuric acid; adding 0.1-5 parts of aqueous disperser in the dilute sulfuric acid for stirring at high speed and mixing, slowly adding 0.5-5 parts of graphene to prepare the graphene dilute sulfuric acid dispersion liquid; slowly adding 8-15 parts of the graphene aqueous dispersion liquid in 100 parts of leadoxide mixing material flow for stirring and mixing; adding 5.3-20 parts of graphene dilute sulfuric acid dispersion liquid in the material flow, and stirring and mixing during a conveying process to form a lead paste. The method can fully disperse graphene in a lead acid battery active substance, charge acceptance as well as heavy current charge and discharge performance of the lead acid battery can be greatly increased, and usage life of the storage battery can be prolonged.

Description

technical field [0001] The invention belongs to the field of lead-acid battery manufacturing, and relates to a preparation method of lead-acid battery lead paste mixed with graphene. Background technique [0002] While industry and technology have brought civilization to mankind, resources and the environment are also suffering unprecedented damage. The environment and resources have increasingly become two major challenges facing mankind. The development of electric vehicles has become one of the effective solutions. The core of electric vehicles is the power source. At present, lead-carbon batteries, lithium-ion batteries and flow batteries are the three major development directions of electric vehicle batteries. Among them, the cost of lithium batteries is relatively high, and consistency problems still exist; the cost of flow batteries is also high; and lead-carbon batteries have gradually become a relatively practical and feasible energy storage technology route in the ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/16H01M4/56
CPCH01M4/16H01M4/57Y02E60/10
Inventor 张戌有陈恒胡勇郭强冯占生冉顺治孙保虎
Owner SINO INNOV SEMICON (PKU) CO LTD
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