All-solid-state photoelectric conversion device and preparation method thereof
A photoelectric conversion, all-solid-state technology, applied in photovoltaic power generation, electrical components, semiconductor devices, etc., can solve the problems of low conversion efficiency, high cost, and difficult preparation of the intermediate layer, so as to reduce preparation cost, improve contact performance, and simplify preparation The effect of craft
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[0066] This embodiment is a photoelectric conversion device with a metal-semiconductor-metal structure. The photoelectric conversion device has a Zn-ZnO-Ag structure, specifically: the lower layer of the photoelectric conversion device is a Zn sheet, the middle layer is a ZnO thin film, and the upper layer is an Ag thin film deposited on the ZnO thin film. The ZnO thin film is hole-shaped and is formed by anodic oxidation on the lower Zn sheet.
[0067] The Zn sheet is a current-collecting layer of a photoelectric conversion device with an all-solid Zn-ZnO-Ag structure, the ZnO thin film is a heterogeneous layer, and the Ag thin film is a photoresponsive layer.
[0068] The ZnO thin film presents blue-black holes with a diameter of 30-100 nm and a thickness of 2.6 μm.
[0069] The present invention also proposes a method for preparing a photoelectric conversion device with a Zn-ZnO-Ag structure, and the specific preparation process is as follows:
[0070] Step 1: Zn sheet pr...
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