Encapsulating composition, barrier layer including same, and encapsulated apparatus including same
一种封装装置、组合物的技术,应用在涂层、图纹面的照相制版工艺、半导体/固态器件零部件等方向,能够解决粘附力劣化、防水性能退化等问题
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preparation Embodiment 1
[0113] Preparation Example 1: Preparation of monomer represented by formula 2
[0114] In a 1000 ml flask provided with a cooling tube and a stirrer, 30 mg of hydroquinone, 50 g of DL-lactic acid (TCI Chemicals), and 86.98 g of 2-isocyanatoethyl methacrylate were stirred at 0°C , while slowly adding 100 mg of dibutyltin dilaurate thereto. The flask was heated to 50°C, followed by stirring for 4 hours. 127 g of the monomer represented by Formula 2 was obtained. The obtained compound has a HPLC purity of 97%.
[0115] [Formula 2]
[0116]
preparation Embodiment 2 to 4
[0117] Preparation Examples 2 to 4: Preparation of Monomers Represented by Formulas 3 to 5
preparation Embodiment 2
[0118] Monomers represented by formulas 3 to 5 were prepared in the same manner as in Preparation Example 1, except that 4-hydroxycyclohexanecarboxylic acid (Preparation Example 2), 2-hydroxybenzoic acid (Preparation Example Example 3), and 4-hydroxy-3-nitrobenzoic acid (Preparation Example 4) instead of DL-lactic acid.
[0119] [Formula 3]
[0120]
[0121] [Formula 4]
[0122]
[0123] [Formula 5]
[0124]
[0125] Details of components used in Examples and Comparative Examples are as follows.
[0126] (A) Photocurable monomers: (A1) tetraethylene glycol diacrylate, (A2) decanediol diacrylate, (A3) pentaerythritol tetraacrylate (Aldrich Chemical)
[0127] (B) Photocurable monomers containing carboxylic acid groups: (B1) the monomer represented by Formula 2 in Preparation Example 1, (B2) the monomer represented by Formula 3 in Preparation Example 2, ( B3) the monomer represented by Formula 4 in Preparation Example 3, (B4) the monomer represented by Formula 5 in P...
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