Closed-cell two-step foamed material prepared from styrene butadiene rubber, natural rubber, butadiene rubber and high styrene resin, and preparation method of closed-cell two-step foamed material

A high-styrene resin and natural rubber technology, applied in the field of foaming materials, can solve chemical weather resistance, poor embossing and shaping, low tensile and tear strength, embossing, poor plasticity, etc. problems, to achieve the effect of wide cold resistance, outstanding performance and low cost

Active Publication Date: 2015-12-23
YIBAO FUJIAN POLYMER MATERIALS
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  • Claims
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AI Technical Summary

Problems solved by technology

[0002] With the maturity of domestic production technology, styrene-butadiene rubber has been widely used in various industries. It has good elasticity, wear resistance, crack resistance, wet skid resistance and price advantages and has become the mainstream rubber type. Low strength, chemical and weather resistance, poor embossing and shaping; natural rubber has good resilience, elongation, tensile strength, and tear strength, but in terms of shortcomings, embossing and plasticity are not good. Good, basically similar to styrene-butadiene rubber; butadiene rubber has very excellent cold resistance (-100°C) elasticity and wear resistance, but poor processability alone, and has a tendency to cold flow; high styrene resin has excellent mechanical stiffness in recent years , wear resistance, et

Method used

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  • Closed-cell two-step foamed material prepared from styrene butadiene rubber, natural rubber, butadiene rubber and high styrene resin, and preparation method of closed-cell two-step foamed material
  • Closed-cell two-step foamed material prepared from styrene butadiene rubber, natural rubber, butadiene rubber and high styrene resin, and preparation method of closed-cell two-step foamed material
  • Closed-cell two-step foamed material prepared from styrene butadiene rubber, natural rubber, butadiene rubber and high styrene resin, and preparation method of closed-cell two-step foamed material

Examples

Experimental program
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Example Embodiment

[0044] The material source specifications used in Example 1 and Example 2 are shown in Table 1 below:

[0045]

[0046] Table 1. Specifications of each raw material source

[0047] Example 1

[0048] The preparation method of the closed-cell secondary foaming material of styrene butadiene rubber, natural rubber, butadiene rubber and high styrene resin includes the following steps:

[0049] (1) Mixing rubber G mastication: Put 100PHR of high styrene resin, 100PHR of natural rubber, and 0.2PHR of stearic acid into a 75L diamond-shaped shaft W type heavy hammer internal mixer, pressurize to 7 kg, and knead Mix for 8 minutes, and continue to fill with cold water to cool down during the kneading process. When the temperature reaches 110℃, the material is discharged to obtain compound G; put compound G into an 18-inch automatic turning mill, the temperature is controlled at 80℃, 2mm turning Material for 180 seconds, the thickness of 2mm is fluttered and cut into the corresponding weight, r...

Example Embodiment

[0058] Example 2

[0059] The preparation method of the closed-cell secondary foaming material of styrene butadiene rubber, natural rubber, butadiene rubber and high styrene resin includes the following steps:

[0060] (1) Mixing rubber G mastication: Put 100PHR of high styrene resin, 100PHR of natural rubber, and 0.1PHR of stearic acid into a 75L diamond-shaped shaft W type heavy hammer internal mixer, pressurize to 7 kg, and knead Mix for 8 minutes, and continue to fill with cold water to cool down during the kneading process. When the temperature reaches 115℃, the material is discharged to obtain compound G; put compound G into an 18-inch automatic turning mill, the temperature is controlled at 85℃, 2mm turning Material for 180 seconds, the thickness of 2mm is fluttered and cut into the corresponding weight, respectively, stand for treatment;

[0061] (2) Natural rubber mastication: Put 100PHR of natural rubber and 0.1PHR of stearic acid into a 75L diamond-shaped shaft W-type hea...

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Abstract

The invention relates to the technical field of foam materials and provides a closed-cell two-step foamed material prepared from styrene butadiene rubber, natural rubber, butadiene rubber and high styrene resin, and a preparation method of the closed-cell two-step foamed material. The closed-cell two-step foamed material retains the relatively good elasticity, wear resistance, fracturing resistance and slippery resistance of the styrene butadiene rubber; the addition of the natural rubber improves the rebound resilience, elongation, tensile strength and tear strength of the material; the cold resistance, wear resistance and elasticity of the material are particularly excellent and heat generated under live load is less due to the addition of butadiene rubber; the use of the high styrene resin improves the mechanical rigidity, hardness and stiffness of products, and makes up the cold flow property of the butadiene rubber at normal temperature. The produced product is remarkable in properties such as cold resistance (the lowest temperature reaches -100 DEG C), embossing and the like, and is free of toxicity, odorless and pollution. During the preparation, firstly, the natural rubber is masticated separately, and the high styrene resin and the natural rubber are blended in a ratio of 1:1; and then the two premixed rubbers are blended with styrene butadiene rubber and butadiene rubber, and the process of rolling and standing is carried out, so that the difficulty that the three types of rubber resins are poor in compatibility is overcome.

Description

technical field [0001] The invention relates to the technical field of foaming materials, in particular to a closed-cell secondary foaming material combined with styrene-butadiene rubber, natural rubber, butadiene rubber and high-styrene resin and a preparation method thereof. Background technique [0002] With the maturity of domestic production technology, styrene-butadiene rubber has been widely used in various industries. It has good elasticity, wear resistance, crack resistance, wet skid resistance and price advantages and has become the mainstream rubber type. Low strength, chemical and weather resistance, poor embossing and shaping; natural rubber has good resilience, elongation, tensile strength, and tear strength, but in terms of shortcomings, embossing and plasticity are not good. Good, basically similar to styrene-butadiene rubber; butadiene rubber has very excellent cold resistance (-100°C) elasticity and wear resistance, but poor processability alone, and has a ...

Claims

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Application Information

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IPC IPC(8): C08L9/06C08L7/00C08L9/00C08K13/02C08K3/22C08K5/09C08K3/04C08K3/34C08K3/06C08J9/04B29C35/02
Inventor 侯汝红陈奕汲
Owner YIBAO FUJIAN POLYMER MATERIALS
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