Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Low-temperature environment-friendly dispersed dye

An environmentally friendly disperse dye technology, applied in organic dyes, dyeing methods, textiles and papermaking, etc., can solve the problems of color incompatibility, dark color, incompetence, etc., and achieve ideal compatibility and compatibility, bright color Effect

Inactive Publication Date: 2016-02-10
太湖亚太精化有限公司 +1
View PDF6 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] On the one hand, the low-temperature old ternary colors: Disperse Yellow RGFL (C.I. Disperse Yellow 23), Disperse Red 3B, and Disperse Blue 2BLN have been widely used in printing and dyeing companies for nearly 20 years. Almost no company has not used the above-mentioned ternary colors. It is known to everyone in the industry, but due to research, it has been found that disperse yellow RGFL has its fatal flaw: the main raw material for its synthesis: p-ammonia and its azobenzene is a suspected carcinogenic compound, and the finished disperse yellow RGFL carries p-amino Azobenzene, and stored at a high temperature of 150°C-170°C, when the fabric is set, some azo bonds are broken and decomposed into p-aminoazobenzene. For this reason, many international organizations, including the official organization of the European Union (REACH), will disperse yellow RGFL is listed as a ban on the use of disperse dyes. In this way, one yellow is missing in the three primary colors, and many colors cannot be blended. It is urgent to find a yellow dye to replace disperse yellow RGFL from other dye varieties. The most typical one is Zhejiang Longsheng. Disperse Yellow E-GL
On the other hand, Longsheng's Disperse Yellow E-GL generally solves the ternary color matching problem of printing and dyeing enterprises, but there are still many defects. First, the level dyeing property is not as good as Disperse Yellow RGFL (C.I. Disperse Yellow 23) , the second is that the color is relatively dark, and it cannot be competent when the color requirements are relatively bright.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Low-temperature environment-friendly dispersed dye
  • Low-temperature environment-friendly dispersed dye
  • Low-temperature environment-friendly dispersed dye

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-8

[0026] Embodiment 1-8: According to the data shown in Table 1, the component A finished product (component A content 53%), dyestuff disperse orange E-RL250% (monomer B content 42%), auxiliary agent are fully mixed in a stirring pot Stir well, then commercialize.

[0027] Table 1 Unit weight: grams

[0028]

[0029] In embodiment 1-8, the substituent R corresponding to one or more dye monomers shown in formula (I) constituting component A 1 , and the weight of the dye monomer corresponding to each substituent is listed in Table 2:

[0030] Table 2

[0031]

[0032] Examples 9-16: According to the data shown in Table 3, component A, dye monomer B, additives, water or other wetting agents were mixed, ground and dispersed with a grinder, spray-dried, and then commercialized.

[0033] Table 3 Unit weight: grams

[0034]

[0035] In embodiment 9-16, the corresponding substituent R of one or more dye monomers shown in formula (I) constituting component A 1 , and the wei...

Embodiment 17

[0038] Embodiment 17: respectively get the disperse dye that 0.5 gram embodiment 1-18 makes and disperse in the water of 500ml, draw 20ml in the dyeing cup, add the distilled water of 80ml, with 10% (weight fraction) acetic acid will dye in the cup Adjust the pH value of the dye solution to 4.5-5.0, add 2.0 grams of polyester fiber cloth at room temperature, tighten the cup cover, and weigh 0.5 grams of Disperse Yellow E-GL produced by Longsheng Company, disperse it in 500ml of water, and absorb 20ml is the same as in the dyeing cup, add 80ml of distilled water, adjust the pH value of the dyeing solution in the dyeing cup to 4.5-5.0 with 10% (weight fraction) acetic acid, add 2.0 grams of polyester fiber cloth at room temperature, and tighten the cup cover , put the two staining cups into the dyeing machine at the same time, raise the temperature from room temperature to 130°C, and keep it warm for 30 minutes. Cool to about 60°C, open the cup lid, take out 2.0 grams of polyest...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a low-temperature environment-friendly dispersed dye which is composed of following components: 3-47% by weight of a component A, which is composed of one or more dye monomers and is represented as the general formula (I), wherein R1 is a methyl group, an ethyl group, a propyl group, an isopropyl group, a n-butyl group, a sec-butyl group, a tert-butyl group or (CH2)3OCH(CH3)2; 1-17% by weight of a dye monomer B which is represented as the general formula (II); and the balanced being an additive. When the dispersed dye in the invention is matched with a low-temperature dispersed dye, both cooperation and compatibility are excellent. Compared with dispersed yellow E-GL, the dispersed dye is bright and full in color.

Description

technical field [0001] The invention relates to a low-temperature environment-friendly disperse dye, which is especially suitable for dyeing and printing polyester fiber and acetate fiber materials. Background technique [0002] On the one hand, the low-temperature old ternary colors: Disperse Yellow RGFL (C.I. Disperse Yellow 23), Disperse Red 3B, and Disperse Blue 2BLN have been widely used in printing and dyeing companies for nearly 20 years. Almost no company has not used the above-mentioned ternary colors. It is known to everyone in the industry, but due to research, it has been found that disperse yellow RGFL has its fatal flaw: the main raw material for its synthesis: p-ammonia and its azobenzene is a suspected carcinogenic compound, and the finished disperse yellow RGFL carries p-amino Azobenzene, and stored at a high temperature of 150°C-170°C, when the fabric is set, some azo bonds are broken and decomposed into p-aminoazobenzene. For this reason, many internationa...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C09B67/38D06P1/16D06P3/54
Inventor 阮华森计刘华
Owner 太湖亚太精化有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products