Photocurable composition and methods for optical component by using the same
一种光固化性、组合物的技术,应用在半导体/固态器件制造、光学、电气元件等方向
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Embodiment 1
[0221] [Preparation of Photocurable Composition 1]
[0222] A (meth)acrylate monomer (component (A)), a photopolymerization initiator (component (B)), and a release agent (component (C)) described below were mixed to obtain a mixed solution.
[0223] Component (A) (total: 100 parts by weight)
[0224] (A-1) Isobornyl acrylate (manufactured by Kyoeisha Chemical Co., Ltd., trade name: IB-XA): 75 parts by weight
[0225] (A-2) 1,10-Decanediol diacrylate (manufactured by Shin-Nakamura Chemical Co., Ltd., trade name: A-DOD-N): 25 parts by weight
[0226] Component (B)
[0227] (B-1) IRGACURE369 (manufactured by BASF): 3 parts by weight
[0228] Note that (B-1) IRGACURE369 is a compound represented by the following formula (1), which is (2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)-butanone-1 ).
[0229] [chemical formula 12]
[0230]
[0231] Component (C)
[0232] (C-1) Megaface EXP.TF-2067 (manufactured by DIC Corporation, nonionic fluorine-based surfactant): 1.1 parts...
Embodiment 2
[0238] [Preparation of Photocurable Composition 2]
[0239] Except using 2.0 parts by weight of (C-2) BLAUNONSA-30 / 702000R (manufactured by Aoki Oil Industrial Co., Ltd., non-ionic alkyl-based surfactant) as a release agent (component (C)), as in Example 1 Prepare photocurable composition 2.
[0240] (Measurement of release force)
[0241] The average release force was measured as in Example 1 except by using Photocurable Composition 2. The average release force is 13N. This value was lower than when the photocurable composition of the comparative example described below was used.
Embodiment 3
[0243] [Preparation of Photocurable Composition 3]
[0244] A photocurable composition 3 was prepared as in Example 1 except that 0.8 parts by weight of (C-3) Pluriol A760E (manufactured by BASF, methyl polyethylene glycol) was used as a release agent (component (C)).
[0245] (Measurement of release force)
[0246] The average release force was measured as in Example 1 except by using Photocurable Composition 3. The average release force is 17N. This value was lower than when the photocurable composition of the comparative example described below was used.
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