Glass ceramic and preparation method thereof

A glass-ceramic and micro-crystal technology, applied in the field of glass-ceramic and its preparation, can solve the problems of affecting the decorative effect and service life, cannot be used at high temperature, scratched or worn, etc., so as to overcome the problem of scratches and prolong the The effect of long service life and low cost

Active Publication Date: 2016-02-24
CDGM GLASS LLC
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  • Abstract
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Problems solved by technology

[0003] Traditional amber glass is colored by adding selenium and cadmium to the glass. Because cadmium is toxic, it is not suitable for use in the existing environment. The Mohs hardness of ordinary amber glass is 5H, while the Mohs hardness of commonly used knives is 5H. 5.5-6H, the grit or dust contains silica Mohs hardness 7H, which can cause scratches or wear on the surface of the existing amber decorative glass, affecting its decorative effect and service life, and ordinary amber glass does not High temperature resistance, it starts to soften at 700-800°C, and cannot be used at high temperatures

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  • Glass ceramic and preparation method thereof
  • Glass ceramic and preparation method thereof
  • Glass ceramic and preparation method thereof

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Embodiment Construction

[0027] The present invention uses ZnO(MgO)-Al 2 o 3 -SiO 2 -TiO 2 -CuO is the system, the precursor glass is prepared through the melting process, and the precursor glass is annealed and heat-treated to prepare the amber glass-ceramics. The content in weight percent and its effect will be described below.

[0028] SiO 2 、Al 2 o 3 , MgO or ZnO are the main components constituting glass-ceramic of the present invention, according to MgO (or ZnO)-Al 2 o 3 -SiO 2 phase diagram, in the present invention, SiO 2 The content of Al is 50-70%; Al 2 o 3 The content of MgO is 10-25%; the content of MgO is 0-22%, and the content of ZnO is 0-20%. In the present invention, at least one of the components in MgO and ZnO is contained, further, MgO and ZnO The total content is 5-22%, preferably 8-15%. When the contents of MgO and ZnO exceed the above range, other crystals will appear in the glass, which cannot meet the requirements of the present invention. SiO 2 and Al 2 o 3 Th...

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Abstract

The invention provides an amber glass ceramic which is relatively high in hardness and resistant to high temperature. The amber glass ceramic comprises the following ingredients by weight percent: 50-70 percent of SiO2, 10.0-25 percent of Al2O3, 3-10 percent of TiO2, 0.2-0.7 percent of CuO, 0-22 percent of MgO and 0-20 percent of ZnO, and comprises at least one of MgO and ZnO. The glass ceramic has the Moh's hardness of 7.5-8 H, can be applied to decorative materials and ornaments, can solve the problem of scratching of ordinary amber glass, is not softened at the high temperature of 1150 DEG C, therefore, is high-temperature resistant and can be further processed under the high-temperature condition. The glass ceramic is high in mechanical strength, hardness and thermal stability, and excellent in chemical stability, wearing resistance and electric insulativity, and can be used for decorative materials, building inner and outer walls, grounds, gallery-column and other high-grade decoration projects.

Description

technical field [0001] The invention relates to a glass-ceramic and a preparation method thereof, in particular to an amber glass-ceramic and a preparation method thereof. technical background [0002] Glass-ceramics has the advantages of glass, ceramics and natural stone, and has excellent thermodynamic properties, good chemical stability, high strength, high wear resistance, uniform and crystal-clear surface gloss, and easy cleaning. These characteristics determine the characteristics of glass-ceramics Occupying an important position in the field of materials, it can be used in high-end decoration projects such as building interior and exterior walls, floors, and corridor columns. [0003] Traditional amber glass is colored by adding selenium and cadmium to the glass. Because cadmium is toxic, it is not suitable for use in the existing environment. The Mohs hardness of ordinary amber glass is 5H, while the Mohs hardness of commonly used knives is 5H. 5.5-6H, the grit or d...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C10/02C03C3/085C03C4/02C03B32/02
Inventor 原保平苏学剑于天来
Owner CDGM GLASS LLC
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