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A kind of tungsten-based heavy alloy rod with hardness gradient change and preparation method thereof

A tungsten-based heavy alloy, hardness gradient technology, applied in the direction of metal material coating process, coating, solid diffusion coating, etc., can solve the problems of reducing the overall elongation and increasing the risk of breaking the core material of armor-piercing bullets, etc. Effect of Dynamic Yield Strength

Inactive Publication Date: 2018-04-03
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, a large amount of deformation usually leads to a sharp decrease in the overall elongation (ie, toughness) of the tungsten-based heavy alloy rod, which increases the risk of the core material of the armor-piercing projectile breaking when it is launched and hits the target.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Example 1: Preparation of Tungsten-based Heavy Alloy Rod with Molybdenum Gradient Structure

[0028] First, 50% (volume fraction) of 2.5 micron molybdenum powder and calcined alumina powder were ball milled and mixed for 3 hours. Embed the sintered 92W-5.6Ni-2.4Fe alloy rod with a diameter of 12mm in a molybdenum boat or corundum boat filled with Mo powder + alumina powder, and put it into a vacuum furnace with molybdenum or tungsten sheets as heating elements. Draw out the air in the furnace to below 5Pa, raise the temperature to 1350°C at a rate of 10°C / min, keep the temperature for 2 hours, and cool down to room temperature with the furnace. From the surface of the alloy rod to 2.5mm below the surface layer, the microhardness of the alloy rod decreases continuously from 380HV to 220HV.

Embodiment 2

[0029] Embodiment 2: the preparation of the graded structure tungsten-based heavy alloy bar of infiltration Ti

[0030] First, 50% (volume fraction) of 25-micron titanium powder and calcined alumina powder were ball milled and mixed for 3 hours. Embed the sintered 92W-5.6Ni-2.4Fe alloy rod with a diameter of 12mm in a molybdenum boat or corundum boat filled with Ti powder + alumina powder, and put it into a vacuum furnace with a molybdenum or tungsten sheet as a heating element. Draw out the air in the furnace to below 5Pa, raise the temperature to 1300°C at a rate of 10°C / min, keep it warm for 2 hours, and cool down to room temperature with the furnace. From the surface of the alloy rod to 2.5mm below the surface layer, the microhardness of the alloy rod decreases continuously from 395HV to 320HV.

Embodiment 3

[0031] Embodiment 3: Preparation of gradient structure tungsten-based heavy alloy cladding Cr

[0032] First, 50% (volume fraction) of 16-micron Cr powder was ball-milled and mixed with calcined alumina powder for 3 hours. Embed the sintered 92W-5.6Ni-2.4Fe alloy rod with a diameter of 12mm in a molybdenum boat or corundum boat filled with Cr powder + alumina powder, and put it into a vacuum furnace with molybdenum or tungsten sheets as heating elements. Draw out the air in the furnace to below 5Pa, raise the temperature to 1300°C at a rate of 10°C / min, keep it warm for 2 hours, and cool down to room temperature with the furnace. From the surface of the alloy rod to 2.5mm below the surface layer, the microhardness of the alloy rod decreases continuously from 373HV to 335HV.

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Abstract

The invention relates to a tungsten-based heavy alloy bar with the gradient-changing hardness and a producing method thereof and belongs to the technical field of powder metallurgy. Gradient distribution areas with the continuously-changing hardness are formed in the radial direction of the tungsten-based heavy alloy bar, and the area, with the largest hardness, in the gradient distribution areas with the continuously-changing hardness in the tungsten-based heavy alloy bar is the surface of the tungsten-based heavy alloy bar. The producing method of the tungsten-based heavy alloy bar includes the steps that a W-Ni-Fe alloy bar is used as a pack cementation object, a solid solution element is packed into the W-Ni-Fe alloy bar in a cementation manner through pack cementation treatment on the vacuum condition, and the tungsten-based heavy alloy bar with the gradient-changing hardness is obtained. The structural design of the bar is reasonable, the producing method is simple and controllable, and the performance of obtained finished products is excellent and stable. According to the tungsten-based heavy alloy bar and the producing method, industrial production and application are facilitated.

Description

technical field [0001] The invention relates to a tungsten-based heavy alloy rod with gradient hardness changes and a preparation method thereof, belonging to the technical field of powder metallurgy. Background technique [0002] The development of self-sharpening heavy alloys is the development direction of armor-piercing projectile core materials. Due to its excellent self-sharpening properties, the depleted uranium composite material is currently the most excellent armor-piercing bullet core material. In the early 1990s, based on international public opinion and environmental pressure caused by the toxicity of depleted uranium materials, the United States began to develop alternative depleted uranium armor-piercing core materials. Based on the W-Ni-Fe series heavy alloy, the researchers changed the microstructure of the alloy, such as increasing the tungsten grain size, improving the design of the phase interface structure, the design of the geometric shape of the bulle...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C10/34C22C27/04
CPCC22C27/04C23C10/34
Inventor 曹顺华易辉伟马新星肖彬李世康徐欢
Owner CENT SOUTH UNIV