Environment-friendly nanometer emulsion fracturing fluid and preparation method thereof

An environmentally friendly, nanoemulsion technology, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of water system and environmental pollution, difficult molecular weight control, low solid content of aqueous solution, etc., and achieve low reservoir damage. , Excellent effect of reducing surface activity and good sand suspension ability

Active Publication Date: 2016-06-01
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example: the solid content of the aqueous solution is generally low, and the molecular weight is not easy to control, and the transportation cost is high; the powder needs to be dried by a large amount of heat and requires special drying equipment, and it needs high-speed stirring and heating during use, which is time-consuming and labor-intensive; water-in-oil Emulsion is to disperse water-soluble polyacrylamide in oil (hydrocarbons). When in use, these hydrocarbons will enter the water system, which not only wastes precious hydrocarbon resources, but also causes pollution to the water system and the environment

Method used

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  • Environment-friendly nanometer emulsion fracturing fluid and preparation method thereof
  • Environment-friendly nanometer emulsion fracturing fluid and preparation method thereof
  • Environment-friendly nanometer emulsion fracturing fluid and preparation method thereof

Examples

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Effect test

Embodiment 1

[0040] This embodiment provides a method for preparing an environmentally friendly nanoemulsion fracturing fluid, comprising the following steps:

[0041](1) 15 parts by weight of acrylamide, 1 part by weight of methacryloxyethyltrimethylammonium chloride, 2 parts by weight of octylphenol polyoxyethylene ether (OP-10) maleic acid monoester , 20 parts by weight of ammonium sulfate, 3 parts by weight of polymethacryloyloxyethyltrimethylammonium chloride are added to the reactor and mixed with 70 parts by weight of deionized water to form a mixed solution, and the mixed solution is adjusted The pH value is 6.5;

[0042] (2) Introduce nitrogen gas into the mixed liquid to remove oxygen, and raise the temperature of the mixed liquid to 55° C., under the protection of nitrogen, add 0.5 parts by weight of azobisisobutyronitrile to react for 5 hours, and use high-speed dispersion with a rotation speed of 15000 rpm. The operation time is 3 minutes; the pressure of high-pressure homoge...

Embodiment 2

[0047] This embodiment provides a method for preparing an environmentally friendly nanoemulsion fracturing fluid, comprising the following steps:

[0048] (1) 20 parts by weight of acrylamide, 3 parts by weight of diallyl dimethyl ammonium chloride, 2 parts by weight of nonylphenol polyoxyethylene ether (NP-10) diester of maleate, 25 parts by weight of Parts of magnesium sulfate and 5 parts by weight of polyacryloyloxyethyltrimethylammonium chloride are added to the reactor and mixed with 80 parts by weight of deionized water to form a mixed solution, and the pH value of the mixed solution is adjusted to 7.2;

[0049] (2) Introduce nitrogen gas into the mixed solution to remove oxygen, and raise the temperature of the mixed solution to 60°C. Under the protection of nitrogen, add 1 part by weight of azobisisobutylamidine hydrochloride to react for 6 hours, and use high-speed dispersion to The rotation speed is 10000rpm, and the operation time is 5min; the pressure of high-press...

Embodiment 3

[0054] This embodiment provides a method for preparing an environmentally friendly nanoemulsion fracturing fluid, comprising the following steps:

[0055] (1) 2-methacrylamide of 25 parts by weight, trimethylallyl ammonium chloride of 5 parts by weight, fatty alcohol polyoxyethylene ether (Pingping plus O-20) maleic acid monosodium ether of 2 parts by weight The potassium sulfate of ester, 25 parts by weight, the polydiallyl dimethyl ammonium chloride of 8 parts by weight are added in the reactor and the deionized water of 100 parts by weight is mixed and stirred evenly to form a mixed solution, and the pH value of the mixed solution is adjusted 7.4;

[0056] (2) feed nitrogen into the mixed solution to remove oxygen, and the temperature of the mixed solution is raised to 60° C., under the protection of nitrogen, add the mixed solution of 1 weight part of hydrogen peroxide and ferrous sulfate (wherein: hydrogen peroxide and The weight ratio of ferrous sulfate is 1:1) to react...

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Abstract

The invention provides a preparation method for environment-friendly nanometer emulsion fracturing fluid. The method comprises the following steps of dissolving monomers A, monomers B, monomers C, inorganic salts and dispersing agents into deionized water to form a mixed solution; performing heating and nitrogen gas introduction; adding initiators to initiate the polymerization under the nitrogen gas protection; meanwhile, dispersing the mixed solution by using high-speed dispersion combining high-pressure homogenizing or high-pressure microjet to form dispersing liquid; diluting the dispersing liquid so as to obtain the environment-friendly nanometer emulsion fracturing fluid through preparation. The monomers A are water-soluble monomers with carbon-carbon double bonds; the monomers B are cationoid water-soluble monomers with carbon-carbon double bonds; the monomers C are polyether type monomers with carbon-carbon double bonds. The preparation method for the fracturing fluid is simple; the environment-friendly effect and no pollution are realized; the energy consumption is low; the application range is wide; meanwhile, the excellent functions of resistance reduction, clay stability, discharge assistance, sand suspending, surface activity reduction and the like are realized; high stability is realized; layering flocculation, accumulation and sedimentation cannot easily occur.

Description

technical field [0001] The invention belongs to the field of oil field exploitation, and in particular relates to an environment-friendly nanoemulsion fracturing fluid and a preparation method thereof. Background technique [0002] Tight unconventional reservoirs are characterized by low porosity and low permeability, making exploration and development difficult. Most tight oil and gas wells require reservoir reconstruction to obtain ideal production. At present, the most important production stimulation measure for the development of tight unconventional reservoirs at home and abroad is drag reduction fracturing. Traditional gel fracturing fluid systems use higher concentrations of gels, and the residues of these gels, along with the filter cake produced during the fracturing process, can plug the formation and reduce fracture conductivity. The slick water fracturing fluid system is a new fracturing fluid system developed on the basis of traditional fracturing fluids for t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/56C08F220/54C08F220/34C08F226/02C08F222/20C08F283/06
CPCC08F220/56C08F283/06C09K8/604C09K8/68C09K8/882C09K2208/28C08F220/54C08F226/02C08F220/34C08F222/205
Inventor 金旭丁彬贺丽鹏刘合
Owner PETROCHINA CO LTD
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