Preparation method for anode device of microbial fuel cell
An anode device and fuel cell technology, applied in biochemical fuel cells, battery electrodes, circuits, etc., can solve the problems of the survival and proliferation of secondary pollution microorganisms, lack of effective control methods, and large space limitations, to ensure long-term stable output. , Improve the survival rate, the effect of high space utilization
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Embodiment 1
[0025] A preparation method of an anode device of a microbial fuel cell, the steps of the method are as follows:
[0026] (1) Preparation of monomer Y: Dissolve 10mmol methacrylic acid in dichloromethane containing 0.1mmol / L polymerization inhibitor, then add 0.1mol dicyclohexylcarbodiimide, stir for 30min, then add Aminoalkylosmium bipyridyl chloride salt, reacted for 2h, washed with water, collected the organic phase and dried in vacuum to obtain monomer Y;
[0027] (2) Preparation of copolymer PMBVY: 2-methacryloyloxyethylphosphorylcholine, 2-methacrylbutyl, 4-vinylphenylboronic acid and monomer Y according to the ratio of 5:2:1:2 The molar ratio was dissolved in absolute ethanol to make a solution with a concentration of 1mol / L, and then 10mmol of azobisisobutyronitrile was added, and the solution was heated to 60°C under the protection of argon and reacted for 48h, and the reaction product was dissolved in 0.1 : Precipitate in the chloroform / ether mixed solvent of 0.9 an...
Embodiment 2
[0031] A preparation method of an anode device of a microbial fuel cell, the steps of the method are as follows:
[0032] (1) Preparation of monomer Y: by dissolving 10mmol of methacryloyl chloride in methylene chloride containing a polymerization inhibitor at a concentration of 0.1mmol / L, adding 10mmol of triethylamine at 0°C and adding 10mmol of Hydroxyalkyl ferrocene, reacted for 4 hours, filtered and washed with deionized water, then collected the organic phase and dried in vacuum, washed with water and dried to obtain monomer Y;
[0033] (2) Preparation of copolymer PMBVY: 2-methacryloyloxyethylphosphorylcholine, 2-methacrylbutyl, 4-vinylphenylboronic acid and monomer Y according to the ratio of 5:2:1:2 The molar ratio was dissolved in absolute ethanol to make a solution with a concentration of 1mol / L, and then 10mmol of azobisisobutyronitrile was added, and the solution was heated to 60°C under the protection of argon and reacted for 48h, and the reaction product was dis...
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