Rapid preparation method of monoclinic phase VO2 metal-insulator phase transformation ceramic material

A ceramic material, VO2 technology, applied in the field of rapid preparation of monoclinic VO2 metal-insulator phase change ceramics, can solve the problems of insufficient physical performance, harsh raw material requirements, cumbersome synthesis methods, etc., to shorten the preparation time and reduce the cost of raw materials , The effect of complete hydrothermal reaction

Inactive Publication Date: 2016-11-09
HUAZHONG UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Currently, monoclinic VO 2 The preparation methods of powder materials and the selection of raw materials are different, but the synthesis methods are too cumbersome or the raw material requirements are relatively harsh, and the preparation cycle is too long
In recent years, there are also many methods to efficiently prepare monoclinic VO 2 Ceramics, but there are still defects of high cost or insufficient physical performance

Method used

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  • Rapid preparation method of monoclinic phase VO2 metal-insulator phase transformation ceramic material
  • Rapid preparation method of monoclinic phase VO2 metal-insulator phase transformation ceramic material
  • Rapid preparation method of monoclinic phase VO2 metal-insulator phase transformation ceramic material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] 1. Using Citric Acid-V 2 o 5 Preparation of Monoclinic VO by Hydrothermal Reaction 2 Powder:

[0027] (1) Measure 0.00375mol of citric acid into a 50mL beaker, add 20mL of deionized water, dissolve under magnetic stirring to form a transparent solution, and then weigh 0.0025molV 2 o 5 Add the solid powder to the above citric acid solution, and magnetically stir together for about 30 minutes to form a uniform yellow solution. The concentration of citric acid-vanadium pentoxide in the mixed solution is 0.025±5% g / mL;

[0028] (2) Pour the above yellow solution into a 50mL stainless steel hydrothermal synthesis reaction kettle, and measure 10mL of deionized water several times to rinse the residual drug in step (1), and add it to the reaction kettle together, and the final reaction solution is about 50mL , then put the reactor into an oven, heat to 180°C, and continue the reaction for 5 hours;

[0029] (3) After the above reaction time is over, the solid-liquid separa...

Embodiment 2

[0036] 1. Using Citric Acid-V 2 o 5 Preparation of Monoclinic VO by Hydrothermal Reaction 2 Powder:

[0037] (1) Measure 0.00625mol of citric acid into a 50mL beaker, add 20mL of deionized water, dissolve under magnetic stirring to form a transparent solution, and then weigh 0.0025molV 2 o 5Add the solid powder to the above citric acid solution, and magnetically stir together for about 30 minutes to form a uniform yellow solution. The concentration of citric acid-vanadium pentoxide in the mixed solution is 0.025±5% g / mL;

[0038] (2) Pour the above yellow solution into a 50mL stainless steel hydrothermal synthesis reaction kettle, and measure 10mL of deionized water several times to rinse the residual drug in step (1), and add it to the reaction kettle together, and the final reaction solution is about 50mL , and then put the reactor into an oven, heat it to 170°C, and continue the reaction for 10 hours;

[0039] (3) After the above reaction time is over, the solid-liquid...

Embodiment 3

[0046] 1. Using Citric Acid-V 2 o 5 Preparation of Monoclinic VO by Hydrothermal Reaction 2 Powder:

[0047] (1) Measure 0.00525mol of citric acid into a 50mL beaker, add 20mL of deionized water, dissolve under magnetic stirring to form a transparent solution, and then weigh 0.0025molV 2 o 5 Add the solid powder to the above citric acid solution, and magnetically stir together for about 30 minutes to form a uniform yellow solution. The concentration of citric acid-vanadium pentoxide in the mixed solution is 0.025±5% g / mL;

[0048] (2) Pour the above yellow solution into a 50mL stainless steel hydrothermal synthesis reaction kettle, and measure 10mL of deionized water several times to rinse the residual drug in step (1), and add it to the reaction kettle together, and the final reaction solution is about 50mL , then put the reactor into an oven, heat to 190°C, and continue the reaction for 8 hours;

[0049] (3) After the above reaction time is over, the solid-liquid separa...

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Abstract

The invention relates to a rapid preparation method of a monoclinic phase VO2 metal-insulator phase transformation ceramic material. The method comprises the following steps: reducing V2O5 with citric acid by a hydrothermal method, carrying out centrifugal cleaning to obtain an orthorhombic phase VO2 nanopowder, carrying out high-temperature heat treatment to obtain a monoclinic phase VO2 powder, and finally compressing and sintering to obtain the monoclinic phase VO2 metal-insulator phase transformation ceramic. The process is simple; preparation efficiency is high; sintering temperature is low; energy consumption is low; cost is low; the method is environment friendly, nontoxic and pollution-free; and the prepared ceramic has good phase transformation property and stable and uniform structure.

Description

technical field [0001] The invention relates to the technical field of phase change ceramic materials, in particular to a monoclinic phase VO 2 A rapid preparation method for metal-insulator phase change ceramics. Background technique [0002] The energy band structure of conductors and non-conductors is different. The conductance of conductors is mainly determined by the situation near the Fermi surface. If the energy band structure or Fermi level can be affected by changing the external conditions, it can cause the transition between metal conductors and insulators. , There are several theoretical models for this metal-insulator mutual transformation: Anderson transformation, Mott transformation, Wilson transformation and Peierls transformation. Vanadium, as a typical representative of 3d group transition metal elements, can combine with oxygen to form a variety of oxides. According to the valence state of vanadium from low to high, it is VO, V 2 o 3 、VO 2 , V 2 o 5 ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/495C04B35/632C04B35/64
CPCC04B35/495C04B35/632C04B35/64
Inventor 袁松柳张润尹重阳黄帅
Owner HUAZHONG UNIV OF SCI & TECH
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