Metal-coated resin particles and electroconductive adhesive in which same are used
A technology of resin particles and metal covering layers, applied in conductive adhesives, conductive connections, adhesives, etc., can solve the problems of reduced adhesion between resin particles and metals, inability to obtain reliable electrical connections, etc., to achieve excellent electrical connection, The effect of improving the reliability of the connection
Active Publication Date: 2016-12-14
TATSUTA ELECTRICWIRE & CABLE
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Problems solved by technology
[0010] However, even with these metal-coated resin particles, as the compression deformation is repeated, the adhesion between the resin particles and the metal decreases, and when used in a conductive adhesive, a highly reliable electrical connection cannot be obtained.
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[0052] Examples of the present invention are shown below, but the present invention is not limited to the following examples. In addition, unless otherwise specified, the following compounding ratio etc. are mass standards.
[0053] 1. Adjustment and evaluation of metal-coated resin particles
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Abstract
Provided are metal-coated resin particles that comprise resin particles and a metal coating layer that covers at least some of the resin particles, wherein it is possible to obtain a high-reliability electrical connection after repeated compression. There are used metal-coated resin particles that have an average grain diameter of 1-100[mu]m and exhibit a recovery of at least 90% after 30% compressive deformation, the metal coating layer comprising a metal having a Vickers hardness of 100 or less and an average thickness of 20-150 nm.
Description
technical field [0001] The present invention relates to metal-coated resin particles and a conductive adhesive using the same. Background technique [0002] As metal-coated resin particles compounded in conductive adhesives used for electrode connection of printed circuit boards, metal-coated resin particles in which resin particles containing acrylic resin are coated with precious metals such as gold via a nickel layer are often used. . [0003] For example, Patent Document 1 discloses that the K value at 10% compression deformation is 50 to 250 kgf / mm for the purpose of providing conductive microspheres having moderate compression deformation and deformation recovery, and excellent connection reliability. 2 The electroconductive microparticles|fine-particles which provided the electroconductive layer which consists of a nickel-gold plating layer on the surface of a microsphere with a recovery rate of 15-100% of high elastic modulus. [0004] In addition, Patent Document ...
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Patent Type & Authority Applications(China)
IPC IPC(8): H01B5/00C09J9/02C09J11/08C09J201/00H01B1/00H01B1/16H01B1/22H01B5/16H01R11/01
CPCC09J9/02C09J11/08C09J201/00H01B1/00H01B1/16H01B1/22H01B5/00H01B5/16H01R11/01
Inventor 十代田优美登峠雅之寺田恒彦堀内伸中尾幸道
Owner TATSUTA ELECTRICWIRE & CABLE
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