Structures with Thinned Dielectric Materials
A dielectric material and thinning technology, applied in the field of semiconductor structures, can solve problems such as difficulties
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[0016] The present invention relates to semiconductor structures, and more particularly to structures having thinned dielectric materials and methods of fabrication. More specifically, the present invention is directed to, for example, HfO 2 Atomic (selective) etching of high-k dielectric materials (HfO2) using high temperature TiCl 4 TiN, used to shrink the size of nFET and pFET devices. Helpfully, in specific embodiments, the methods described herein improve the reliability of sized devices by, in one implementation, using thicker HfO 2 Improved pFET negative bias temperature instability (nBTI) and thinner HfO 2 Improve nFET positive bias temperature instability (pBTI).
[0017] In a specific embodiment, atomic layer deposition (ALD) of TiN is performed at high temperature using TiCl 4 (Titanium tetrachloride) precursor for preparation. As an example, HCl (hydrochloric acid) is the precursor of TiCl during the deposition of TiN (titanium nitride). 4 with precursor NH ...
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