Rare-earth doped nickel, cobalt and manganese ternary material wide temperature lithium ion battery and production method thereof
A lithium-ion battery, rare earth doping technology, applied in battery electrodes, secondary batteries, electrochemical generators, etc., can solve problems such as unsatisfactory temperature adaptability, inability to meet power requirements, and achieve good cycle performance , The effect of facilitating high-intensity startup acceleration and high power tolerance
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Embodiment 1
[0027] The first embodiment provides a production method of a rare earth-doped nickel-cobalt-manganese ternary material wide-temperature lithium-ion battery.
[0028] Specifically, Embodiment 1 of the present invention provides a rare earth-doped nickel-cobalt-manganese cylindrical wide-temperature lithium battery. The positive electrode material of the battery is nickel-cobalt-manganese ternary material doped with rare earth element neodymium, and neodymium is doped in L i N i0.5 co 0.3 mn 0.2 o 2 L can be formed in i N i0.5 co 0.3 mn 0.2 N d o 2 compound.
[0029] Concrete preparation method is carried out according to the following steps:
[0030] Step S110, weighing lithium salts, nickel salts, manganese salts, cobalt salts and rare earth nitrates according to preset substance ratios.
[0031] Step S111 , dissolving the weighed lithium salt, nickel salt, manganese salt, cobalt salt and rare earth nitrate in 95%-100% ethanol to obtain a metal salt ethanol soluti...
Embodiment 2
[0040] Embodiment 2 of the present invention also provides a production method of a rare earth-doped nickel-cobalt-manganese ternary material wide-temperature lithium-ion battery.
[0041] Specifically, a 10Ah positive electrode material is a rare earth-doped nickel-cobalt-manganese ternary material aluminum shell square wide temperature lithium battery.
[0042] Its preparation method includes:
[0043] Step S210, weigh LiNO according to the ratio of the amount of substances to 1.56:0.66:0.25:0.11:0.08 3 , Mn(CH 3 COO) 2 4H 2 O, Ni(CH 3 COO) 2 ·6H 2 O, Co(CH 3 COO) 2 4H 2 O and Nd(NO 3 ) 3 ·6H 2 O;
[0044] In step S211, the weighed LiNO 3 , Mn(CH 3 COO) 2 4H 2 O, Ni(CH 3 COO) 2 ·6H 2 O, Co(CH 3 COO) 2 4H 2 O and Nd(NO 3 ) 3 ·6H 2 O was dissolved in absolute ethanol to obtain a transparent metal salt ethanol solution, LiNO 3 , Mn(CH 3 COO) 2 4H 2 O, Ni(CH 3 COO) 2 ·6H 2 O, Co(CH 3 COO) 2 4H 2 O and Nd(NO 3 ) 3 ·6H 2 The total concentrati...
Embodiment 3
[0049] Embodiment 3 of the present invention provides yet another possible implementation of a production method of a rare earth-doped nickel-cobalt-manganese ternary material wide-temperature lithium-ion battery. Specifically, the method includes steps:
[0050] Step S310, weigh LiNO according to the ratio of the amount of substances to 1.56:0.75:0.25:0.11:0.15 3 , Mn(CH 3 COO) 2 4H 2 O, Ni(CH 3 COO) 2 ·6H 2 O, Co(CH 3 COO) 2 4H 2 O and Nd(NO 3 ) 3 ·6H 2 O;
[0051] In step S311, the weighed LiNO 3 , Mn(CH 3 COO) 2 4H 2 O, Ni(CH 3 COO) 2 ·6H 2 O, Co(CH 3 COO) 2 4H 2 O and Nd(NO 3 ) 3 ·6H 2 O was dissolved in absolute ethanol to obtain a transparent metal salt ethanol solution, LiNO 3 , Mn(CH 3 COO) 2 4H 2 O, Ni(CH 3 COO) 2 ·6H 2 O, Co(CH 3 COO) 2 4H 2 O and Nd(NO 3 ) 3 ·6H 2 The total concentration of O in absolute ethanol is 1.8mol / L;
[0052] Step S312, placing the obtained metal salt ethanol solution in a high-temperature furnace at a ...
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