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A kind of glass fiber separator for battery and preparation method thereof

A technology of glass fiber separator and glass fiber, which is applied in battery pack components, separators/films/diaphragms/spacers, circuits, etc. It can solve the problems of insufficient rigidity of separators and achieve excellent alkali resistance and rigidity High, life-prolonging effect

Active Publication Date: 2019-03-26
CHONGQING WEIYE POWER MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Lead-acid battery separators are usually equipped with ribs to strengthen the separator, but the stiffness provided by the ribs to the separator is often insufficient

Method used

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  • A kind of glass fiber separator for battery and preparation method thereof
  • A kind of glass fiber separator for battery and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Such as figure 1 As shown, a glass fiber separator for batteries includes a substrate, the upper surface of the substrate is provided with an arched bridge deck, and a layer of glass fiber wool is arranged above the arched deck, and the base The lower surface of the sheet is evenly provided with a curved support surface, the cross-sectional shape of the arched bridge deck is arc-shaped, and the cross-sectional shape of the curved support surface is wave-like; the width of the bottom edge of the arched bridge deck is larger than that of one of the curved support surfaces. The width of the bottom edge corresponding to the wave crest; the height of the arched bridge deck is greater than the height of the curved support surface; the wavy shape of the section of the curved support surface is a symmetrical S shape.

[0018] According to the present invention, a method for preparing a glass fiber separator for a battery, the glass fiber separator for a battery includes an arch...

Embodiment 2

[0021] Such as figure 1 Shown, a kind of preparation method for the glass fiber separator of battery, wherein glass fiber wool is made up of the raw material of following parts by weight: SiO 2 75 parts, Al 2 o 3 10 parts, MgO 12 parts, CaO 12 parts, ZnO 0.5 parts, K 2 O 0.1 parts, Li 2 O 0.1 part, TiO 2 0.1 parts, ZrO 2 0.1 part; the arched bridge deck and the curved support surface are made up of the raw materials of the following parts by weight: SiO 2 65 parts, Al 2 o 3 20 copies, K 2 O 1.5 parts, ZnO 0.1 parts, Fe 2 o 3 0.1 part, 5 parts of CaO, 9 parts of MgO; the base sheet includes intertwined glass fiber aggregates, and cellulose slurry dispersed in the glass fiber aggregates, and the parts by weight of the cellulose slurry are the weight of the glass fiber aggregates 10% of the number of parts, the diameter of the glass fiber aggregates is 8 μm, and the rest are the same as in Example 1.

Embodiment 3

[0023] Such as figure 1 Shown, a kind of preparation method for the glass fiber separator of battery, wherein glass fiber wool is made up of the raw material of following parts by weight: SiO 2 70 parts, Al 2 o 3 9 parts, MgO 11 parts, CaO 10 parts, ZnO 0.3 parts, K 2 O 0.3 parts, Li 2 O0.3 parts, TiO 2 0.3 parts, ZrO 2 0.3 part; The arched deck and the curved support surface are made up of the raw materials of the following parts by weight: SiO 2 62 copies, Al 2 o 3 18 parts, K2O 0.8 parts, ZnO 0.5 parts, Fe 2 o 3 0.3 parts, 6 parts of CaO, 10 parts of MgO; the substrate includes intertwined glass fiber aggregates, and cellulose slurry dispersed in the glass fiber aggregates, and the parts by weight of the cellulose slurry are the weight of the glass fiber aggregates 0.2% of the parts by weight, the diameter of the glass fiber aggregates of 5% by weight is 1 μm, and the diameter of the glass fiber aggregates of 95% by weight is 10-18 μm.

[0024] Table 1 Phy...

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Abstract

The invention discloses a glass fiber separator for batteries and a preparation method thereof. The separator of the present invention comprises a substrate, wherein the upper surface of the substrate is provided with an arched deck, a layer of glass fiber wool is provided above the arched deck, and the lower surface of the substrate is evenly arranged There is a curved support surface, the cross-section shape of the arched bridge deck is arc-shaped, and the cross-section shape of the curved support surface is wave-like. The glass fiber separator in the separator of the present invention includes intertwined glass fiber aggregates, and the separator has a large pore volume and specific surface area, and the glass fiber separator used in batteries prepared by the separator With high porosity, the rigidity of the glass fiber separator is high, and it has excellent alkali resistance, acid resistance and water resistance due to the content of TiO2; the battery made of this separator has a significantly longer service life.

Description

technical field [0001] The invention belongs to the field of corrosion-resistant materials, and relates to a method for manufacturing battery separators, in particular to a glass fiber separator for batteries and a preparation method thereof. Background technique [0002] The separator is an important component of the battery, and its material is an electronic insulator, and its porosity makes it ionically conductive. The resistance of the separator is an important performance of the separator, which is determined by the thickness, porosity, and tortuousness of the pores, and has an important impact on the high-rate discharge capacity and terminal voltage level of the battery; the stability of the separator in sulfuric acid It directly affects the life of the battery; the elasticity of the separator can delay the shedding of the positive active material; the aperture size of the separator affects the degree of short circuit of the lead dendrite. [0003] Separators have var...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M2/14H01M2/16H01M2/18H01M50/403H01M50/44H01M50/463H01M50/491
CPCH01M50/431H01M50/44H01M50/40H01M50/409H01M50/403H01M50/463Y02E60/10
Inventor 滕波
Owner CHONGQING WEIYE POWER MATERIALS CO LTD