Preparation method of organic phase change energy storage material

A technology of energy storage materials and organic phases, applied in the direction of heat exchange materials, chemical instruments and methods, etc., can solve the problems of low melting point, large volume change, and low cost of organic matter, and achieve high heat of solution, simple preparation process, and good Use the effect of value

Inactive Publication Date: 2017-07-04
SHANGHAI BANZAN MACROMOLECULE MATERIAL
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  • Abstract
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  • Application Information

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Problems solved by technology

At the same time, there are the following disadvantages: one is supercooling phenomenon, the other is phase separation
Organic phase change energy storage materials have the advantages of good formability in solid state, generally less prone to supercooling and phase separation, less corrosive materials, relatively stable performance, low toxicity, and low cost; The material has the following disadvantages: low thermal conductivity, low energy storage density, and organic matter generally has a low melting point, which is not suitable for high-temperature applications, and is volatile, flammable, even explosive, or aging due to slow oxidation by oxygen in the air
[0004] US 4708812, CN 1844269A, CN1903971A introduced phase-change microcapsules, which use organic polymers as capsule wall materials to wrap and seal phase-change materials. The phase-change enthalpy is large, but the volume changes during phase-change. Repeated shrinkage and expansion make the material Shorter service life and with physical interaction between the core and shell, leakage and phase separation can still occur

Method used

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  • Preparation method of organic phase change energy storage material
  • Preparation method of organic phase change energy storage material

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Embodiment 1

[0020] The organic phase change energy storage material of the present embodiment, its raw material contains the following components by weight: 48 parts of polyethylene (molecular weight: 400,000); 8 parts by weight of paraffin wax (molecular weight: 600); 3 parts by weight of copper powder; 2 parts by weight of aluminum powder Parts by weight; 2 parts by weight of graphite powder.

[0021] Preparation method: take polyethylene, heat and melt, mix with paraffin wax at 145°C for 2 hours, then add graphite powder, aluminum powder, copper powder, and mix for 1 hour to obtain an organic phase change energy storage material.

Embodiment 2

[0023] The high-density phase-change energy storage material of this embodiment, its raw material contains the following components by weight: 46 parts by weight of polyethylene (molecular weight 500,000) paraffin (molecular weight 800) 5 parts by weight; Copper powder 4 parts by weight; Aluminum powder 4 parts by weight Parts by weight; 4 parts by weight of graphite powder.

[0024] Preparation method: take polyethylene, heat and melt, mix with paraffin wax at 145°C for 2 hours, then add graphite powder, aluminum powder, copper powder, and mix for 1 hour to obtain an organic phase change energy storage material.

Embodiment 3

[0026] The high-density phase change energy storage material of this embodiment, its raw material contains the following components by weight: polyethylene (molecular weight 450,000) 45 parts paraffin (molecular weight 700) 6 weight parts; Copper powder 2 weight parts; Aluminum powder 3 parts by weight; 6 parts by weight of graphite powder.

[0027] Preparation method: take polyethylene, heat and melt, mix with paraffin wax at 145°C for 2 hours, then add graphite powder, aluminum powder, copper powder, and mix for 1 hour to obtain an organic phase change energy storage material.

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Abstract

The invention belongs to the field of research and development of new materials, and particularly relates to an organic phase change energy storage material and a preparation method and an application thereof. The organic phase change energy storage material comprises the following components in parts by weight: 45-48 parts of polyethylene; 5-8 parts of paraffin; 2-4 parts of copper powder; 2-4 parts of aluminum powder and 2-6 parts of graphite powder. The phase change energy storage material realizes energy storage and release through reversible solid-liquid phase change, the phase change temperature is 50-70 DEG C, and the phase change enthalpy can reach 210 J / g, the dissolving heat and the heat conductivity are relatively high, and the preparation process is simple, the organic phase change energy storage material is non-toxic and harmless. The organic phase change energy storage material has a good utilization value in the aspect of phase change energy storage materials.

Description

technical field [0001] The invention belongs to the field of research and development of new materials, and in particular relates to an organic phase change energy storage material and its preparation and application. Background technique [0002] Phase change energy storage is the theoretical understanding of energy storage in modern physics, and a relatively mature theory has been formed, but there is still a lot of room for development of phase change energy storage materials. Due to the rapid growth of energy consumption and the urgent need for efficient energy utilization, the research on phase change energy storage materials is very important, because it is the embodiment of energy saving and energy utilization. According to the way of energy storage, energy storage materials can be roughly divided into three categories: sensible heat energy storage, latent heat energy storage and chemical reaction energy storage. Phase change energy storage is a latent heat energy st...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K5/06
CPCC09K5/063
Inventor 储江顺毕宏海彭艳华毕宏清程启山汪丽陈旭睿毕宏俊欧阳贵薛明跃
Owner SHANGHAI BANZAN MACROMOLECULE MATERIAL
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