Heat dispersion resin composition for LED (Light-emitting Diode) base plate and preparation method thereof
A technology of resin composition and LED substrate, which is applied in the field of heat-dissipating resin composition, can solve the problems such as the increase of the working temperature of the LED chip, and achieve the effect of improving the service life and suppressing the increase of temperature
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Embodiment 1
[0044] A preparation method for a heat-dissipating resin composition for an LED substrate, comprising:
[0045] Step 1) prepare epoxy resin A,
[0046] Step 1.1) prepare the epoxy compound B of formula (II) structure,
[0047] Dissolve 4-hydroxybiphenyl in excess epichlorohydrin, add potassium hydroxide, the molar ratio of 4-hydroxybiphenyl to potassium hydroxide is 1.2, react at 100°C for 4 hours, and distill the unreacted ring under reduced pressure Oxychloropropane, the product of vacuum distillation is washed with distilled water, and dried to obtain epoxy compound A;
[0048]
[0049] Step 1.2), mix epoxy compound B, R-N(H)-R', R and R' connected to N are C2 alkyl and C4 linear alkyl respectively, react at 110°C for 2min, add epoxy resin CYD -128, stirred and mixed evenly, reacted for 10min, cooled to room temperature, extracted with toluene and dried in vacuum to obtain epoxy resin A;
[0050] Step 2), disperse 60% by mass of epoxy resin A in water, add 30% by mass...
Embodiment 2
[0052] A preparation method for a heat-dissipating resin composition for an LED substrate, comprising:
[0053] Step 1) prepare epoxy resin A,
[0054] Step 1.1) prepare the epoxy compound B of formula (II) structure,
[0055] Dissolve 4-hydroxybiphenyl in excess epichlorohydrin, add potassium hydroxide, the molar ratio of 4-hydroxybiphenyl to potassium hydroxide is 1.2, react at 100°C for 4 hours, and distill the unreacted ring under reduced pressure Oxychloropropane, the product of vacuum distillation is washed with distilled water, and dried to obtain epoxy compound A;
[0056]
[0057] Step 1.2), mix epoxy compound B, R-N(H)-R', R and R' connected to N are C3 straight-chain alkyl and C6 straight-chain alkyl respectively, react at 110°C for 3 minutes, add epoxy Resin CYD-128, stirred and mixed evenly, reacted for 13 minutes, cooled to room temperature, extracted with toluene and dried in vacuum to obtain epoxy resin A;
[0058] Step 2), disperse 70% by mass of epoxy r...
Embodiment 3
[0060] A preparation method for a heat-dissipating resin composition for an LED substrate, comprising:
[0061] Step 1) prepare epoxy resin A,
[0062] Step 1.1) prepare the epoxy compound B of formula (II) structure,
[0063] Dissolve 4-hydroxybiphenyl in excess epichlorohydrin, add potassium hydroxide, the molar ratio of 4-hydroxybiphenyl to potassium hydroxide is 1.1, react at 100°C for 4 hours, and distill the unreacted ring under reduced pressure Oxychloropropane, the product of vacuum distillation is washed with distilled water, and dried to obtain epoxy compound A;
[0064]
[0065] Step 1.2), mix epoxy compound B, R-N(H)-R', R and R' connected to N are C4 straight-chain alkyl and C6 straight-chain alkyl respectively, react at 110°C for 3 minutes, add epoxy Resin CYD-128, stirred and mixed evenly, reacted for 15 minutes, cooled to room temperature, extracted with toluene and dried in vacuum to obtain epoxy resin A;
[0066] Step 2), disperse 60% by mass of epoxy r...
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