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Tea saponin modified red mud and composite floor tile made from red mud and waste plastics

A technology of waste plastics and tea saponin, which is applied in the field of building materials, can solve the problems of white pollution, poor compatibility of two phases, and land occupation, etc., and achieve the effects of increasing the number of filling parts, good dispersion performance, and improved combination

Inactive Publication Date: 2017-09-22
GUIZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, the industrial waste residue red mud discharged by my country's chemical industry is increasing year by year. In addition to the production of red mud bricks and cement, there are many ash storage yards stacked in red mud, which not only invades the land, but also cause serious environmental pollution
In addition, with the increasing production capacity and consumption of polyphenylene ether plastics in my country, the output of plastic waste formed by discarded polyphenylene ether plastics is increasing, causing serious "white pollution"
In addition, most of the floor tiles currently used for laying on the ground in public places and family houses are made of clay, porcelain clay, and stone. The production process is complicated and the price is high. There are still some defects in the degree of improvement, and a new material that uses waste, reduces pollution, and saves resources is urgently needed to solve the problem.
On the other hand, in the blending process of waste polyphenylene ether plastic and red mud, red mud is a polar inorganic substance and hydrophilic, while waste polyphenylene ether plastic is a non-polar organic substance and lipophilic. The chemical structure is very different, so that there is a lack of chemical bonding between the two, resulting in uneven dispersion of inorganic fillers in the above-mentioned organic matter during two-phase blending, and poor compatibility between the two phases, thus affecting the performance of composite floor tiles

Method used

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  • Tea saponin modified red mud and composite floor tile made from red mud and waste plastics
  • Tea saponin modified red mud and composite floor tile made from red mud and waste plastics
  • Tea saponin modified red mud and composite floor tile made from red mud and waste plastics

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] Make tea saponin modified red mud according to the following steps:

[0049] Add 93Kg of red mud and 7Kg of tea saponin into a high-speed mixer at 50°C, and stir for 7 to 9 minutes to obtain tea saponin-modified red mud.

[0050] Follow the steps below to make composite floor tiles:

[0051] a. After cleaning 140Kg of waste polyphenylene ether plastics, dry them at 120°C for 1.4 hours, and then crush them to less than 7mm to obtain product A;

[0052] b. After mixing product A and 860Kg tea saponin modified red mud with a high-speed mixer, product B is obtained;

[0053]c. Put product B on a three-roller mill to form a sheet at a temperature of 260-290°C and a sheet thickness of 0.5-0.8mm, and then send it to a hot press for molding at a temperature of 120°C-150°C and a pressure of 7.0 MPa, the time is 3 to 5 minutes, and the product C is obtained;

[0054] d. Cut product C into pieces according to the standard size of 300mm in length, 300mm in width and 1.5mm in thi...

Embodiment 2

[0078] Make tea saponin modified red mud according to the following steps:

[0079] Add 90Kg of red mud and 10Kg of tea saponin into a high-speed mixer at 50°C, and stir for 7 to 9 minutes to obtain tea saponin-modified red mud.

[0080] Follow the steps below to make composite floor tiles:

[0081] a. After cleaning 200Kg of waste polyphenylene ether plastics, dry them at 120°C for 1.4 hours, and then crush them to less than 7mm to obtain product A;

[0082] b. After mixing product A and 800Kg tea saponin modified red mud with a high-speed mixer, product B is obtained;

[0083] c. Put product B on a three-roller mill to form a sheet at a temperature of 260-290°C and a sheet thickness of 0.5-0.8mm, and then send it to a hot press for molding at a temperature of 120°C-150°C and a pressure of 7.0 MPa, the time is 3 to 5 minutes, and the product C is obtained;

[0084] d. Cut product C into pieces according to the standard size of 300mm in length, 300mm in width and 1.5mm in t...

Embodiment 3

[0107] Make tea saponin modified red mud according to the following steps:

[0108] Add 87Kg of red mud and 13Kg of tea saponin into a high-speed mixer at 50°C, and stir for 7 to 9 minutes to obtain tea saponin-modified red mud.

[0109] Follow the steps below to make composite floor tiles:

[0110] a. After cleaning 250Kg of waste polyphenylene ether plastics, dry them at 120°C for 1.4 hours, and then crush them to less than 7mm to obtain product A;

[0111] b. After mixing product A and 750Kg tea saponin modified red mud with a high-speed mixer, product B is obtained;

[0112] c. Put product B on a three-roller mill to form a sheet at a temperature of 260-290°C and a sheet thickness of 0.5-0.8mm, and then send it to a hot press for molding at a temperature of 120°C-150°C and a pressure of 7.0 MPa, the time is 3 to 5 minutes, and the product C is obtained;

[0113] d. Cut product C into pieces according to the standard size of 300mm in length, 300mm in width and 1.5mm in t...

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Abstract

The invention discloses tea saponin modified red mud which comprises 7-13wt% of tea saponin and 87-93wt% of red mud. The tea saponin modified red mud is made by the following steps: adding red mud and tea saponin into a high-speed mixer at the temperature of 50 DEG C, stirring for 7-9 minutes, thereby obtaining the tea saponin modified red mud. The composite floor tile made from the tea saponin modified red mud and waste polydiphenyl ether plastics is made from the following raw materials in parts by weight: 14-25 parts of waste polydiphenyl ether plastics and 75-86 parts of tea saponin modified red mud. The making method of the composite floor tile comprises the following steps: drying, stirring by a stirrer, plastifying into sheets, performing mold pressing, cutting, thereby obtaining the composite floor tile. The surface property of the red mud is changed from hydrophilic to oleophilic by utilizing the tea saponin, so that the blending compatibility between the red mud and waste polydiphenyl ether and the binding property are greatly improved, and the performance of the composite floor tile is greatly improved. Meanwhile, the filling fraction of the red mud in the composite floor tile is increased, and the cost of the product is effectively reduced.

Description

technical field [0001] The invention belongs to the field of building materials, and in particular relates to tea saponin modified red mud used as waste polyphenylene ether plastic filler and a composite floor tile made of waste polyphenylene ether plastic. Background technique [0002] At present, the industrial waste residue red mud discharged by my country's chemical industry is increasing year by year. In addition to the production of red mud bricks and cement, there are many ash storage yards stacked in red mud, which not only invades the land, but also cause serious environmental pollution. In addition, with the increasing production capacity and consumption of polyphenylene ether plastics in my country, the output of plastic waste formed by discarded polyphenylene ether plastics is increasing, causing serious "white pollution". In addition, the floor tiles currently used for laying the ground in public places and family houses are mostly made of clay, porcelain clay, ...

Claims

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Application Information

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IPC IPC(8): C08L71/12C08K9/04C08K3/34E04F15/10
CPCC08K9/04C08K3/34C08L2207/20E04F15/105C08L71/123
Inventor 张龙刘彤
Owner GUIZHOU UNIV
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