Fluorescent cocoon silk fabric prepared by using thiocyanate water solution

A technology using thiocyanate and thiocyanate, which is applied in liquid/gas/steam textile material treatment, animal fiber, textile and papermaking, etc. It can solve the problems of difficult control, reduction of silk fiber skin affinity, and long process and other issues to achieve the effect of reducing damage

Inactive Publication Date: 2017-11-24
SOUTHWEST UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the adsorption method mainly uses the intermolecular van der Waals force and ionic bond force to make the nanoparticles adsorb to the surface of the silk fiber, and the washing fastness is low; the process of the sol-gel method and the layer-by-layer assembly method is long and difficult to control;

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0012] Example 1

[0013] (1) Preparation of solution: add lithium thiocyanate to water to form a 60% lithium thiocyanate aqueous solution, and then add 1.5% (w / w) long afterglow red luminescent phosphor La2O2S: Eu3+ nanoparticles to it , Obtain a solution with long afterglow red luminescent phosphor La2O2S:Eu3+ nanoparticles dispersed under ultrasonic oscillation;

[0014] (2) Padding the silk fabric in the dissolving solution obtained in step (1) several times, with a rolling margin of 90%;

[0015] (3) Irradiate the padding silk fabric under 100W microwave for 10min;

[0016] (4) Immerse the irradiated silk fabric in an aqueous solution of polyvinylpyrrolidone (10% by mass) to solidify for 10 minutes, then wash and dry.

Example Embodiment

[0017] Example 2

[0018] (1) Preparation of solution: add thiocyanate ammonium salt to water to form a 50% thiocyanate aqueous solution, and then add 0.2% (w / w) long afterglow blue luminescent phosphor (Sr, Ca ,Ba,Mg)10(PO4)6Cl2:Eu2+ nanoparticles, a solution of long afterglow blue luminescent phosphor (Sr,Ca,Ba,Mg)10(PO4)6Cl2:Eu2+ nanoparticles is obtained under ultrasonic oscillation;

[0019] (2) Padding the silk fabric in the dissolving solution obtained in step (1) several times, with a rolling margin of 100%;

[0020] (3) Irradiate the padding silk fabric under 120W microwave for 9min;

[0021] (4) Immerse the irradiated silk fabric in an aqueous solution of polyvinylpyrrolidone (20% by mass) to solidify for 10 minutes, then wash and dry.

Example Embodiment

[0022] Example 3

[0023] (1) Preparation of solution: add sodium thiocyanate to water to form a 50% sodium thiocyanate aqueous solution, and then add 1.0% (w / w) long afterglow green phosphor ZnS:Cu,Al to it Nano particles, a solution containing long afterglow green luminescent phosphor ZnS: Cu, Al nanoparticles dispersed under ultrasonic oscillation;

[0024] (2) Padding the silk fabric in the dissolving solution obtained in step (1) several times, with a rolling margin of 80%;

[0025] (3) Irradiate the padding silk fabric under microwave at 150℃ for 6min;

[0026] (4) Immerse the irradiated silk fabric in an aqueous solution of polyvinylpyrrolidone (30% by mass) to solidify for 10 minutes, then wash and dry.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention provides a method for preparing fluorescent silk fabrics using a thiocyanate aqueous solution, the method comprising the following steps: (1) Preparation of a solution: adding thiocyanate to water to form a thiocyanate aqueous solution, and then Phosphor powder nanoparticles are added therein, and a solution in which phosphor powder nanoparticles are dispersed is obtained under ultrasonic oscillation; (2) the silk fabric is repeatedly padded in the solution obtained in step (1); (3) after padding, The silk fabric is irradiated under microwave; (4) The irradiated silk fabric is soaked in polyvinylpyrrolidone aqueous solution to solidify, then washed and dried. The preparation technology is simple and easy, the cost is low, the strength damage to the silk fabric is small, the surface properties of the silk fiber are not changed, and the fluorescent powder nanoparticles have good fastness on the silk fabric; no adhesive is used in the preparation process, toxic free and safe.

Description

technical field [0001] The invention relates to a method for preparing functional fabrics, in particular to a method for preparing fluorescent silk fabrics by using a thiocyanate aqueous solution. Background technique [0002] Functional fiber materials can be prepared by introducing nanoparticles into textile fibers. At present, there are many preparation methods for introducing nanoparticles into silk fibers, such as: adsorption method, sol-gel method, layer-by-layer assembly method, coating method, feeding method and so on. However, the adsorption method mainly uses the intermolecular van der Waals force and ionic bond force to make the nanoparticles adsorb to the surface of the silk fiber, and the washing fastness is low; the process of the sol-gel method and the layer-by-layer assembly method is long and difficult to control; The coating method is to use adhesives to bond nanoparticles to the surface of silk fibers, which reduces the skin affinity of silk fibers to the...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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IPC IPC(8): D06M13/325D06M10/02D06M15/356D06B3/18D06M101/12
CPCD06M13/325D06B3/18D06M10/02D06M15/3562D06M2101/12
Inventor 卢明刘一萍
Owner SOUTHWEST UNIVERSITY
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