Fluorescent cocoon silk fabric prepared by using thiocyanate water solution
A technology using thiocyanate and thiocyanate, which is applied in liquid/gas/steam textile material treatment, animal fiber, textile and papermaking, etc. It can solve the problems of difficult control, reduction of silk fiber skin affinity, and long process and other issues to achieve the effect of reducing damage
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[0012] Example 1
[0013] (1) Preparation of solution: add lithium thiocyanate to water to form a 60% lithium thiocyanate aqueous solution, and then add 1.5% (w / w) long afterglow red luminescent phosphor La2O2S: Eu3+ nanoparticles to it , Obtain a solution with long afterglow red luminescent phosphor La2O2S:Eu3+ nanoparticles dispersed under ultrasonic oscillation;
[0014] (2) Padding the silk fabric in the dissolving solution obtained in step (1) several times, with a rolling margin of 90%;
[0015] (3) Irradiate the padding silk fabric under 100W microwave for 10min;
[0016] (4) Immerse the irradiated silk fabric in an aqueous solution of polyvinylpyrrolidone (10% by mass) to solidify for 10 minutes, then wash and dry.
Example Embodiment
[0017] Example 2
[0018] (1) Preparation of solution: add thiocyanate ammonium salt to water to form a 50% thiocyanate aqueous solution, and then add 0.2% (w / w) long afterglow blue luminescent phosphor (Sr, Ca ,Ba,Mg)10(PO4)6Cl2:Eu2+ nanoparticles, a solution of long afterglow blue luminescent phosphor (Sr,Ca,Ba,Mg)10(PO4)6Cl2:Eu2+ nanoparticles is obtained under ultrasonic oscillation;
[0019] (2) Padding the silk fabric in the dissolving solution obtained in step (1) several times, with a rolling margin of 100%;
[0020] (3) Irradiate the padding silk fabric under 120W microwave for 9min;
[0021] (4) Immerse the irradiated silk fabric in an aqueous solution of polyvinylpyrrolidone (20% by mass) to solidify for 10 minutes, then wash and dry.
Example Embodiment
[0022] Example 3
[0023] (1) Preparation of solution: add sodium thiocyanate to water to form a 50% sodium thiocyanate aqueous solution, and then add 1.0% (w / w) long afterglow green phosphor ZnS:Cu,Al to it Nano particles, a solution containing long afterglow green luminescent phosphor ZnS: Cu, Al nanoparticles dispersed under ultrasonic oscillation;
[0024] (2) Padding the silk fabric in the dissolving solution obtained in step (1) several times, with a rolling margin of 80%;
[0025] (3) Irradiate the padding silk fabric under microwave at 150℃ for 6min;
[0026] (4) Immerse the irradiated silk fabric in an aqueous solution of polyvinylpyrrolidone (30% by mass) to solidify for 10 minutes, then wash and dry.
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