Experimental facility and method for remediating saturated water-bearing layer chlorinated hydrocarbon DNAPL pollution source based on zero-valent iron-PRB reduction

An experimental device and technology of zero-valent iron, which is applied in the field of soil and groundwater pollution restoration, can solve the problems of difficult mixing evenly, large difference in specific gravity between powdered zero-valent iron and quartz sand, etc., so as to reduce the occupied space, avoid rapid oxidation, The effect of improving single-player operability

Pending Publication Date: 2017-11-24
INST OF SOIL SCI CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

But currently about Fe 0 The research on the removal of DNAPL pollution sources mainly focuses on nano-ZVI and its binary loading system, and does not turn the perspective to the ZVI-PRB system with high engineering application value. The smaller the particle size of ZVI, it can participate in the degradation of pollutants. The larger the effective specific surface area of ​​the reaction is, but in actual engineering applications and laboratory simulation experiments, the specific gravity difference between powdered zero-valent iron and quartz sand is very difficult to mix evenly, so the application of powdered zero-valent iron is less

Method used

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  • Experimental facility and method for remediating saturated water-bearing layer chlorinated hydrocarbon DNAPL pollution source based on zero-valent iron-PRB reduction
  • Experimental facility and method for remediating saturated water-bearing layer chlorinated hydrocarbon DNAPL pollution source based on zero-valent iron-PRB reduction
  • Experimental facility and method for remediating saturated water-bearing layer chlorinated hydrocarbon DNAPL pollution source based on zero-valent iron-PRB reduction

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Experimental program
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Embodiment 1

[0022] An experimental device for repairing chlorinated hydrocarbon DNAPL pollution sources in saturated aquifers based on zero-valent iron-PRB reduction, including: a water supply device 1, a column simulation device 2 and a waste liquid collection device 4 connected by pipelines in sequence, and the column simulation device 2 A group of sampling devices 3 are arranged on it; the cylinder simulation device 2 includes a cylinder, and the two ends of the cylinder are provided with a cylinder cover 5 at the water inlet end and a cylinder cover 6 at the water outlet end, and the two cylinder covers are respectively A water inlet 10 and a water outlet 11 are provided, the water inlet 10 and the water outlet 11 are respectively provided with pneumatic tubes, a screen is provided between the cylinder cover and the cylinder, and the first filter layer is arranged in the cylinder in turn 14. DNAPL contaminated area 7, PRB area 8, PRB downstream area 9 and second filter layer 15, the co...

Embodiment 2

[0024] As shown in the figure, an experimental device and method for the reduction of zero-valent iron-PRB to repair saturated aquifer chlorinated hydrocarbon DNAPL pollution sources, including a water supply device 1, a column simulation device 2, a sampling device 3 and a waste liquid collection device 4.

[0025] The column simulation device 2 has a length of 50 cm, an inner diameter of 5 cm, and an outer diameter of 6 cm, including a saturated aquifer simulation area and filter layers at both ends. The saturated aquifer simulation area includes DNAPL pollution area 7, PRB area 8 and PRB downstream area 9. The length of the DNAPL contaminated area 7 is 5 cm, the PRB area 8 is installed at a position 2 cm downstream from the DNAPL injection hole 16, and the length is 20 cm, and the length of the PRB downstream area 9 is 15 cm. The filter layers at both ends include a first filter layer 14 and a second filter layer 15 with lengths of 3 cm and 1.5 cm respectively. The inner d...

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Abstract

The invention relates to an experimental facility and method for remediating a saturated water-bearing layer chlorinated hydrocarbon DNAPL pollution source based on zero-valent iron-PRB reduction. The experimental facility comprises a water supply device, a cylinder simulator, a sampling device and a waste liquid collecting device which are sequentially connected. According to the method, specific to pollution caused by the saturated water-bearing layer chlorinated hydrocarbon DNAPL pollution source, a zero-valent iron-PRB is mounted near the pollution source, reductive degradation is carried out on a dissolved-state DNAPL ingredient flowing through a wall body, and the saturated water-bearing layer chlorinated hydrocarbon DNAPL pollution source is remediated. Simulation experiments show that dissolution rate of the DNAPL pollution source can be increased by mounting the zero-valent iron-PRB near the pollution source, existence time of the saturated water-bearing layer chlorinated hydrocarbon DNAPL pollution source in an underground environment is shortened, and a design thought and key technical parameters are provided for study of in situ chemical reduction remediation.

Description

technical field [0001] The invention relates to the field of soil and groundwater pollution remediation, in particular to an experimental device and method for remediating saturated aquifer chlorinated hydrocarbon DNAPL pollution sources based on zero-valent iron-PRB reduction. Background technique [0002] As an important industrial raw material, Dense non-aqueous phase liquid (DNAPL) is widely used in the fields of agriculture, fuel, and medicine, and it is easy to leak and discharge during production, transportation, storage, and use, resulting in a large amount of DNAPL. Enter the underground environment. This part of the DNAPL entering the underground environment can continuously migrate to the soil and groundwater under the action of gravity, and accumulate in the impermeable or impermeable layer to form a DNAPL pool, thereby slowly and continuously releasing pollutants to the underground environment, forming a persistent Sources of contamination, the remediation of w...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N33/00
CPCG01N33/00
Inventor 宋昕徐坷坷唐伟王新博
Owner INST OF SOIL SCI CHINESE ACAD OF SCI
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