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Starch-base degradable plastic and preparation method

A technology for degrading plastics and starch-based plastics, applied in the field of starch-based degradable plastics and its preparation, can solve the problems of complicated operations, poor practical performance of degradable plastics, and high cost, and achieve improved mechanical properties, low production costs, and improved processing performance. The effect of toughness

Inactive Publication Date: 2017-12-22
王治民
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method is complicated to operate and the cost is extremely high; 3) Using starch as the main material, the development of whole starch degradable plastics
In this regard, a single starch is usually selected as the main material. Due to the limitation of the structure of the raw material, the practical performance of the prepared degradable plastic is poor.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A starch-based degradable plastic in this embodiment is made of the following raw materials in parts by weight: 40 parts of pregelatinized corn starch, 20 parts of pregelatinized potato starch, 1 part of adipic acid, 8 parts of glycerin and carbonic acid Calcium 1 part.

[0021] A method for preparing the described starch-based degradable plastics, comprising the following steps:

[0022] 1) Add 40 parts of pregelatinized cornstarch and 20 parts of pregelatinized potato starch into a mixer and mix evenly;

[0023] 2) Add 1 part of adipic acid and 8 parts of glycerin to the mixed starch, and heat to 150°C for 6 hours while stirring;

[0024] 3) After the reaction is completed, cool down to below 60°C, add 1 part of calcium carbonate, and knead evenly to obtain a starch-based degradable plastic.

Embodiment 2

[0026] A starch-based degradable plastic in this embodiment is made of the following raw materials in parts by weight: 60 parts of pregelatinized cornstarch, 30 parts of pregelatinized potato starch, 5 parts of adipic acid, 20 parts of glycerin and carbonic acid Calcium 5 parts.

[0027] A method for preparing the described starch-based degradable plastics, comprising the following steps:

[0028] 1) Add 60 parts of pregelatinized cornstarch and 30 parts of pregelatinized potato starch into a mixer and mix evenly;

[0029] 2) Add 5 parts of adipic acid and 20 parts of glycerin to the mixed starch, and heat to 180°C for 4 hours while stirring;

[0030] 3) After the reaction is finished, cool down to below 60°C, add 5 parts of calcium carbonate, and knead evenly to obtain a starch-based degradable plastic.

Embodiment 3

[0032] A starch-based degradable plastic in this embodiment is made of the following raw materials in parts by weight: 48 parts of pregelatinized cornstarch, 24 parts of pregelatinized potato starch, 3 parts of adipic acid, 15 parts of glycerin and carbonic acid Calcium 3 parts.

[0033] A method for preparing the described starch-based degradable plastics, comprising the following steps:

[0034] 1) Add 48 parts of pregelatinized cornstarch and 24 parts of pregelatinized potato starch into a mixer and mix evenly;

[0035] 2) Add 3 parts of adipic acid and 15 parts of glycerin to the mixed starch, and heat to 170°C for 5 hours while stirring;

[0036] 3) After the reaction is finished, cool down to below 60°C, add 3 parts of calcium carbonate, and knead evenly to obtain a starch-based degradable plastic.

[0037] Adipic acid in the above-mentioned embodiment can also be replaced with any one in malic acid or epichlorohydrin;

[0038] The glycerin in the above-mentioned embo...

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PUM

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Abstract

The invention particularly relates to a starch-base degradable plastic and a preparation method, solving the technical problems of incomplete degradation, complex preparation method, ultrahigh cost, poor practical property of degradable plastic, and the like, of the present starch-base degradable plastic. The starch-base degradable plastic is prepared by mixing and reacting 60-90 parts of base starch, 1-5 parts of a cross-linking agent, 8-20 parts of a plasticizer and 1-5 parts of a degradable accelerant. According to the starch-base degradable plastic, different starches are compounded for realizing the adjustable and controllable structure; under the synergic effect of cross-linking reaction, the mechanical properties of the products are promoted; the plasticizer can be used for promoting the processing properties and toughness of the products; the degradable accelerant can be used for realizing the synergic degradation of optical degradation and biodegradability of the products and promoting the degradation property; according to the invention, the product cost is low; the raw materials are easily available; a conventional processing mode is adopted for preparing various common disposable plastic products.

Description

technical field [0001] The invention belongs to degradable plastics and a preparation method, in particular to a starch-based degradable plastic and a preparation method. Background technique [0002] Plastic has the characteristics of light weight, good performance, easy processing, and low price, and has been widely used. While plastic brings convenience to human beings, it also causes serious harm to the ecological environment because it is not easy to recycle. The development of degradable plastics is considered to be one of the effective ways to solve plastic pollution, and has attracted the attention of relevant researchers at home and abroad in recent years. Starch is a renewable resource with good hydrolytic degradation and biodegradation characteristics, and is finally converted into clean carbon dioxide and water. It has broad application prospects in the field of degradable plastics. At present, there are three main directions for developing degradable plastics ...

Claims

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Application Information

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IPC IPC(8): C08L3/02C08K5/092C08K5/053C08K3/26
CPCC08L3/02C08K2003/265C08L2201/06C08L2205/025C08K5/092C08K5/053C08K3/26
Inventor 王治民
Owner 王治民
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