Recovery of styrene from pyrolysis gasoline by extractive distillation

A technology of styrene and distillation column, applied in azeotropic/extractive distillation, distillation separation, extraction purification/separation, etc., can solve problems such as difficult component separation
CN1077560CInactive Publication Date: 2002-01-09苏尔寿际特(北京)技术有限公司

Patent Information

Authority / Receiving Office
CN · China
Current Assignee / Owner
苏尔寿际特(北京)技术有限公司
Publication Date
2002-01-09
Estimated Expiration
Not applicable · inactive patent

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Abstract

An extractive distillation process for separating at least one substituted unsaturated aromatic from a pyrolysis gasoline mixture, containing said aromatic and at least one close-boiling aromatic or non-aromatic hydrocarbon, employing a two part extractive solvent: (a) sulfolane (tetramethylene sulfone), and (b) portion consisting of water.
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Description

Background of the invention

[0001] In one aspect, the invention relates to the separation of selected compounds in a pyrolysis gasoline stream primarily containing substituted unsaturated aromatics. Extractive distillation is used to separate selected compounds from aromatic and non-aromatic hydrocarbons with similar boiling points. In another aspect, the present invention relates to the use of mixtures of sulfolane (tetrahydrothiol sulfone) alone or with water as solvent (also called extractant or entrainer) in the aforementioned extractive distillation.

[0002] Extractive distillation is a well-known technique for separating mixture components with relative volatilities close to 1 (i.e., almost equal in volatility and boiling point). It is difficult to separate the components of this mixture by ordinary fractional distillation. In extractive distillation, a solvent is fed into the distillation column above the feed point of the separated feed mixture. The solvent present...

Claims

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