Water-soluble pentapolymer molecular brush dye capture and sedimentation agent and its preparation method and application
A polymer and sedimentation agent technology, applied in water pollutants, chemical instruments and methods, water/sewage treatment, etc., can solve complex heavy metal ions, single chemical structure of polyacrylamide, and poor capture ability of dye molecules and other problems, to achieve the effect of solving the problem of complexed heavy metal ions, efficient capture, and rapid sedimentation
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Embodiment 1
[0021] It is a water-soluble five-membered polymer molecular brush dye catching sedimentation agent, which is prepared by the following steps:
[0022] Step 1 Synthesis of PHEMAA polymer backbone
[0023] Take 1 part of azobisisobutyronitrile initiator, 100 parts of hydroxyethyl acrylamide (HEMAA) and 400 parts of methanol, carry out polymerization reaction at 80°C for 1 hour under nitrogen protection, and obtain a degree of polymerization (DP) of 30 Polyhydroxyethyl acrylamide (PHEMAA);
[0024] Step 2 Synthesis of cationic polymer side chain PDMC-COOH, anionic polymer side chain precursor polymer PtBMA-COOH and functional polymer side chain precursor polymer PNVF-COOH
[0025] Synthesis of cationic polymer side chain PDMC-COOH: take 1 part of azodicyanovaleric acid initiator, 100 parts of methacryloyloxyethyltrimethylammonium chloride (DMC) and 300 parts of water , carried out radical polymerization at 60 °C for 2 hours under nitrogen protection to obtain PDMC-COOH with a ...
Embodiment 2
[0035] It is a water-soluble five-membered polymer molecular brush dye catching sedimentation agent, which is prepared by the following steps:
[0036] Step 1 Synthesis of PHEMAA polymer backbone
[0037] Take 1 part of ethyl 2-bromoisobutyrate initiator, 1 part of CuBr, 1 part of 4,4-bipyridine (BPy), 100 parts of hydroxyethyl acrylamide (HEMAA), 100 parts of methanol, Under nitrogen protection, the polymerization was carried out at 60 °C for 5 hours to obtain polyhydroxyethyl acrylamide (PHEMAA) with a degree of polymerization (DP) of 200;
[0038] Step 2 Synthesis of cationic polymer side chain PDMC-COOH, anionic polymer side chain precursor polymer PtBMA-COOH and functional polymer side chain precursor polymer PNVF-COOH
[0039] Synthesis of cationic polymer side chain PDMC-COOH: take 1 part of azodicyanovaleric acid initiator, 200 parts of methacryloyloxyethyltrimethylammonium chloride (DMC) and 100 parts of water , carry out radical polymerization at 60 °C for 10 hours...
Embodiment 3
[0049] It is a water-soluble five-membered polymer molecular brush dye catching sedimentation agent, which is prepared by the following steps:
[0050] Step 1 Synthesis of PHEMAA polymer backbone
[0051] Take 1 part of ethyl 2-bromoisobutyrate initiator, 1 part of CuBr, 1 part of 4,4-bipyridine (BPy), 400 parts of hydroxyethyl acrylamide (HEMAA), 100 parts of methanol, Under nitrogen protection, the polymerization was carried out at 70°C for 10 hours to obtain polyhydroxyethyl acrylamide (PHEMAA) with a degree of polymerization (DP) of 300;
[0052] Step 2 Synthesis of cationic polymer side chain PDMC-COOH, anionic polymer side chain precursor polymer PtBMA-COOH and functional polymer side chain precursor polymer PNVF-COOH
[0053] Synthesis of cationic polymer side chain PDMC-COOH: take 1 part of azodicyanovaleric acid initiator, 300 parts of methacryloyloxyethyltrimethylammonium chloride (DMC) and 100 parts of water , carried out radical polymerization at 60 °C for 12 hou...
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