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Processing auxiliary and preparing method and application thereof

A technology of processing aids and extrusion equipment, which is applied in the field of polyolefin processing, can solve problems affecting the mechanical properties and performance of materials, and achieve the effects of maintaining molecular weight and mechanical properties, reducing costs, and simplifying the preparation process

Inactive Publication Date: 2018-04-10
BEIJING HUAFU ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, during its granulation and processing, it is easily degraded due to the action of heat and shear force, thus affecting the mechanical properties and performance of the material.

Method used

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  • Processing auxiliary and preparing method and application thereof
  • Processing auxiliary and preparing method and application thereof
  • Processing auxiliary and preparing method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0027] Such as figure 1 As shown, the preparation method according to the processing aid of the present invention mainly comprises the following steps:

[0028] 1a) Prepare each component according to the formula ratio, mix α-tocopherol, phosphite, dilauryl thiodipropionate, polyethylene glycol 2000 evenly and heat to 80°C-120°C to melt.

[0029] 1b) Add polybasic acid and polyamine to the mixture obtained in 1a), and stir for 30min-60min until the mixture is uniform.

[0030] 1c) The mixture obtained in 1b) was allowed to stand for 2h-4h to fully react.

[0031] 1d) Cool the reaction product obtained in 1c) and grind it to 40-60 mesh to obtain a processing aid.

[0032] Such as figure 2 Shown, utilize the processing aid prepared by above-mentioned method to prepare high-quality polyolefin, generally comprise the following steps:

[0033] 2a) Mix the polyolefin powder and the processing aid at a weight ratio of 1000:1-5 to prepare a blended material.

[0034] In this ste...

Embodiment 1

[0037] The processing aid of the embodiment of the present invention 1 comprises each component of following percentage by weight:

[0038]

[0039]

[0040] The preparation method of the processing aid of the embodiment of the present invention 1 comprises the following steps:

[0041] 1a) 6 grams of α-tocopherol, 25 grams of phosphite, 28 grams of dilauryl thiodipropionate, and 5 grams of polyethylene glycol 2000 were mixed uniformly and heated to 80°C to melt;

[0042] 1b) Add 15 grams of phosphoric acid and 5 grams of polyethylene polyamine to the mixture obtained in 1a), and stir for 30 minutes to make it evenly mixed;

[0043] 1c) 1b) the resulting mixture was allowed to stand for 3h to fully react;

[0044] 1d) The reaction product obtained in 1c) was cooled and ground to 40 mesh to obtain a processing aid.

[0045] Using the processing aid prepared by the above method to prepare high-quality polyolefin generally includes the following steps:

[0046] 2a) unifo...

Embodiment 2

[0049] The processing aid of the embodiment of the present invention 2 comprises each component of following percentage by weight:

[0050]

[0051]

[0052] The preparation method of the processing aid of the embodiment of the present invention 2 comprises the following steps:

[0053] 1a) 6 grams of α-tocopherol, 25 grams of phosphite, 28 grams of dilauryl thiodipropionate, and 5 grams of polyethylene glycol 2000 were mixed uniformly and heated to 80°C to melt;

[0054] 1b) Add 15 grams of boric acid and 5 grams of polyethylene polyamine to the mixture obtained in 1a), and stir for 30 minutes to make it evenly mixed;

[0055] 1c) 1b) the resulting mixture was allowed to stand for 3h to fully react;

[0056]1d) The reaction product obtained in 1c) was cooled and ground to 50 mesh to obtain a processing aid.

[0057] Using the processing aid prepared by the above method to prepare high-quality polyolefin generally includes the following steps:

[0058] 2a) uniformly m...

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Abstract

The invention discloses a processing auxiliary. The processing auxiliary is composed of alpha-tocopherol, phosphite, dilauryl thiodipropionate, polyethylene glycol 2000, polyatomic acid and polyamine.The processing auxiliary can make processing performance of a polyolefin product improved in the forming process. The invention further discloses a preparing method of the processing auxiliary and amethod for utilizing the processing auxiliary to prepare high-quality polyolefin.

Description

technical field [0001] The invention relates to the field of polyolefin processing, in particular to a processing aid used in the polyolefin granulation process and a preparation method thereof, and also to a method for preparing high-quality polyolefin using the processing aid. Background technique [0002] Polyolefin has become the most widely used plastic material because of its excellent performance and low price. However, during its granulation and processing, it is easily degraded due to the action of heat and shear force, thus affecting the mechanical properties and performance of the material. Especially polyolefins with a low melt index, because of their high viscosity, high shear force and high shear temperature during the granulation process, are more prone to degradation, which directly affects the processing performance of polyolefins. [0003] Therefore, how to reduce the shear viscosity and keep the degradation of polyolefin has become an urgent technical pro...

Claims

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Application Information

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IPC IPC(8): C08L71/02C08K13/02C08K5/1545C08K5/524C08K5/372C08K3/32C08K5/17C08K3/38C08K5/092
CPCC08K13/02C08K3/32C08K3/38C08K5/092C08K5/1545C08K5/17C08K5/175C08K5/372C08K5/524C08K2003/329C08K2003/387C08L71/02
Inventor 黄伟史雪君何杉史东军杜波明瑞光吴道洪
Owner BEIJING HUAFU ENG