Energy storage molecular material, crystal dielectric layer and capacitor
A technology of molecular materials and molecular structures, applied in fixed capacitor electrodes, fixed capacitor dielectrics, fixed capacitor parts, etc., can solve problems such as unsuitable capacitors
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[0110] This example describes porphyrin-(phenyl-perylenediimides) represented by general structure I comprising fragments represented by structures 6 and 35 (Tables 1 and 5) 4 - compound (TPP-PD I 4 ) synthesis method,
[0111]
[0112] The method includes several steps.
[0113] In the first step, the synthesis of 1,7-dibromobi-3,4:9,10-tetracarboxylic dianhydride represented by the general structure 81 is carried out:
[0114]
[0115]
[0116] To this end, 3,4:9,10-perylenetetracarboxylic dianhydride (28.52 g, 72.7 mmol) was added to 420 ml of concentrated sulfuric acid and stirred at 55° C. for 24 hours. Iodine (0.685 g, 2.70 mmol) was added to the reaction mixture and stirred at 55°C for an additional 5 hours. Bromine (8.3ml, 162mmol) was added dropwise to the reaction flask over 1 hour and stirred at 85°C for 24 hours. Then with nitrogen N 2 Replace excess bromine. Water (66ml) was added dropwise to the cooled mixture and the precipitate was filtered off. ...
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