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Soil stabilizer for heavy metal contamination, method for preparing soil stabilizer and application thereof

A soil stabilizer and heavy metal technology, applied in the field of soil treatment, can solve the problems of unfavorable disposal and utilization, large landfill storage capacity, large capacity increase ratio, etc., and achieve the effects of high-efficiency product stability, large processing capacity, and total reduction

Inactive Publication Date: 2018-04-24
ZHENGZHOU YUANRAN BIOLOGY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, from the perspective of existing applications, cement-based reagents are mainly used as stabilizers for restoration. Stabilization with such reagents has the problems of large volume increase ratio and large landfill storage capacity, and it also causes soil or other solid waste to harden and increase. Capacity and other issues are not conducive to subsequent disposal and utilization

Method used

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  • Soil stabilizer for heavy metal contamination, method for preparing soil stabilizer and application thereof
  • Soil stabilizer for heavy metal contamination, method for preparing soil stabilizer and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0021] In the embodiment of the present invention, a soil stabilizer contaminated by heavy metals comprises the following raw materials: 30 kg of red jade soil, 11 kg of caffeic acid, 3 kg of cobalt naphthenate, 15 kg of jade powder, 11 kg of sodium lactate, and 5 kg of dimethyl carbonate.

[0022] Mix cobalt naphthenate with 18 times its mass of ethanol to obtain a cobalt naphthenate solution; mix sodium lactate with 10 times its mass of deionized water to obtain a sodium lactate solution; mix caffeic acid with 4 times its mass of deionized water , to obtain a caffeic acid solution. Grind red jade soil and pass through a 120-mesh sieve, then add cobalt naphthenate solution, heat up to 72°C and seal and stir at this temperature for 1 hour, then heat up to 88°C and add dimethyl carbonate, continue stirring at this temperature After 45 minutes, centrifuge and wash to obtain mixture A; the stirring speed is 200r / min, the centrifuge speed is 3000r / min, centrifuge for 10min, and de...

Embodiment 2

[0024] In the embodiment of the present invention, a soil stabilizer contaminated by heavy metals comprises the following raw materials: 40 kg of red jade soil, 19 kg of caffeic acid, 7 kg of cobalt naphthenate, 25 kg of jade powder, 19 kg of sodium lactate, and 9 kg of dimethyl carbonate.

[0025] Mix cobalt naphthenate with 20 times its mass of ethanol to obtain a cobalt naphthenate solution; mix sodium lactate with 12 times its mass of deionized water to obtain a sodium lactate solution; mix caffeic acid with 5 times its mass of deionized water , to obtain a caffeic acid solution. Grind red jade soil and pass through a 150-mesh sieve, then add cobalt naphthenate solution, raise the temperature to 75°C and seal and stir at this temperature for 1.2h, then raise the temperature to 90°C and add dimethyl carbonate, continue at this temperature Stir for 50 min, centrifuge and wash to obtain mixture A; the stirring speed is 250 r / min. Grind the jade powder, pass through a 150-mes...

Embodiment 3

[0027] In the embodiment of the present invention, a soil stabilizer contaminated by heavy metals comprises the following raw materials: 32kg of red jade soil, 13kg of caffeic acid, 4kg of cobalt naphthenate, 18kg of jade powder, 13kg of sodium lactate, and 6kg of dimethyl carbonate.

[0028] Mix cobalt naphthenate with 19 times its mass of ethanol to obtain a cobalt naphthenate solution; mix sodium lactate with 11 times its mass of deionized water to obtain a sodium lactate solution; mix caffeic acid with 5 times its mass of deionized water , to obtain a caffeic acid solution. Grind red jade soil and pass through a 150-mesh sieve, then add cobalt naphthenate solution, heat up to 75°C and seal and stir at this temperature for 1.2h, then heat up to 89°C and add dimethyl carbonate, continue at this temperature Stir for 50 min, centrifuge and wash to obtain mixture A; the stirring speed is 250 r / min. Grind the jade powder, pass through a 150-mesh sieve, add the caffeic acid solu...

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PUM

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Abstract

The invention discloses a soil stabilizer for heavy metal contamination, a method for preparing the soil stabilizer and application thereof. The soil stabilizer comprises, by weight, 30-40 parts of akadama, 11-19 parts of caffeic acid, 3-7 parts of cobalt naphthenate, 15-25 parts of jade powder, 11-19 parts of sodium lactate and 5-9 parts of dimethyl carbonate. The method includes smashing the akadama, adding the akadama into cobalt naphthenate solution to obtain first solution, heating and hermetically stirring the first solution, adding the dimethyl carbonate into the first solution to obtain second solution and centrifugally separating and washing the second solution to obtain mixtures A; grinding the jade powder, adding the jade powder into caffeic acid solution to obtain first solution, heating and hermetically stirring the first solution, adding sodium lactate solution and the mixtures A into the first solution to obtain second solution, carrying out ultrasonic treatment on the second solution, stirring the second solution until the second solution is dried and carrying out calcination to obtain the soil stabilizer. The soil stabilizer, the method and the application have theadvantages that excellent effects of stabilizing heavy metal or organic contaminants in soil can be realized by the soil stabilizer; effects of degrading halogenated or brominated organic matters canbe realized as the time goes by, and accordingly the total quantity of organic matters can be reduced; the soil stabilizer is high in stabilization speed and low in dosage, and good stabilization effects can be realized by the soil stabilizer.

Description

technical field [0001] The invention relates to the technical field of soil treatment, in particular to a soil stabilizer polluted by heavy metals, a preparation method and application thereof. Background technique [0002] In recent years, heavy metal pollution incidents have occurred from time to time, especially the problem of heavy metal soil pollution is becoming more and more apparent. The area of ​​soil pollution in my country is increasing year by year, and it has not been effectively controlled. It has become one of the important environmental problems. For the remediation and treatment of heavy metal soil, stabilization technology is a relatively mature and economically feasible method, and there are currently specific implementation cases at home and abroad. However, from the perspective of existing applications, cement-based reagents are mainly used as stabilizers for restoration. Stabilization with such reagents has the problems of large volume increase ratio an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K17/40B09C1/08
CPCC09K17/40B09C1/08
Inventor 张力
Owner ZHENGZHOU YUANRAN BIOLOGY TECH CO LTD
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