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A kind of aluminum-zinc-silicon-zirconium hot-dipping alloy and its dipping process

A hot-dip plating, aluminum-zinc-silicon technology, applied in hot-dip plating process, metal material coating process, coating and other directions, can solve the problem that hot-dip aluminum and hot-dip galvanizing coating process cannot meet the service requirements, and achieve fine Small grains and spangles of electroless plating layer, and the effect of reducing leakage plating

Active Publication Date: 2020-09-08
UNIV OF JINAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the increasing demand for high-performance corrosion-resistant metal materials in society, the corrosion-resistant standards of metal materials have been continuously improved, and the hot-dip aluminum and hot-dip galvanizing coating processes have gradually failed to meet the service requirements under some special conditions.

Method used

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  • A kind of aluminum-zinc-silicon-zirconium hot-dipping alloy and its dipping process
  • A kind of aluminum-zinc-silicon-zirconium hot-dipping alloy and its dipping process
  • A kind of aluminum-zinc-silicon-zirconium hot-dipping alloy and its dipping process

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] An aluminum-zinc-silicon-zirconium hot-dip alloy, consisting of: A1 54.7 Zn 43.3 Si 1.5 Zr 0.5 .

[0028] The preparation method is as follows:

[0029] (1) Raise the temperature of the furnace to 120°C, add the proportioned A155Zn43.5Si1.5 alloy ingots and aluminum-zirconium alloy ingots into the furnace, raise the furnace temperature to 720°C for two hours, and then cool down to 600°C keep warm for two hours;

[0030] (2) Perform ultrasonic cleaning on the steel plate to remove surface impurities; clean the steel plate with a 15% NaOH solution at 70-80°C to remove surface oil stains, and then wash the steel plate with water for 15 seconds to remove surface residues and lye;

[0031] (3) Then wash the steel plate with HCl solution with a volume concentration of 15% until there is no rust on the surface of the steel plate; wash the steel plate with water to remove surface residues and acid;

[0032] (4) Help the cleaned steel plate with a flux solution at a temper...

Embodiment 2

[0052] An aluminum-zinc-silicon-zirconium hot-dip alloy is composed of A154.5Zn43Si1.5Zr1.

[0053] The preparation method is the same as in Example 1.

[0054] The salt spray test method is the same as in Example 1.

[0055] The specific results of the salt spray test are shown in Table 2.

[0056] Table 2

[0057] Mass before salt spray test / g Mass after salt spray test / g Poor quality / g Mass loss percentage / % blank group 55.5694 55.5483 0.0211 0.03797 1.0%Zr 61.3195 61.3092 0.0103 0.01679

[0058] According to the results of salt spray implementation, when 1.0wt% Zr is added, the corrosion weight loss is effectively reduced, indicating that the corrosion resistance of the coating is better improved under the condition of salt spray, and the intergranular corrosion is weakened, indicating that the crystal grains are finer, that is, the structure of the coating get refined.

[0059] It can also be proved by the results observed under ...

Embodiment 3

[0061] An aluminum-zinc-silicon-zirconium hot-dipping alloy is composed of A154.2Zn42.8Si1.5Zr1.5.

[0062] The preparation method is the same as in Example 1.

[0063] The salt spray test method is the same as in Example 1.

[0064] The specific results of the salt spray test are shown in Table 3.

[0065] table 3

[0066] Mass before salt spray test / g Mass after salt spray test / g Poor quality / g Mass loss percentage / % blank group 55.5694 55.5483 0.0211 0.03797 1.5%Zr 36.8383 36.8307 0.00760 0.02063

[0067] It can be seen from the results of salt spray implementation in Table 1 that when 1.5wt% Zr is added, the corrosion weight loss is effectively reduced, indicating that the corrosion resistance of the coating is better improved under the condition of salt spray, and the intergranular corrosion is weakened, indicating that the grains are more Fine, that is, the coating structure is refined.

[0068] At the same time, the inventor foun...

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Abstract

The invention belongs to the technical field of metal material corrosion prevention, and particularly relates to an aluminum zinc silicon zirconium hot dipping coating alloy and a dipping coating process thereof. The hot dipping coating alloy is particularly prepared from, by mass percent, 53.2 wt% to 55.7 wt% of aluminum, 42.8 wt% to 44.3 wt% of zinc, 1.35 wt% to 1.55 wt% of silicon and 0.30 wt%to 2.0 wt% of zirconium. According to the aluminum zinc silicon zirconium hot dipping coating alloy and the dipping coating process thereof, the corrosion resistance of a coating can be effectively improved; and according to experiments, the corrosion resistance can be improved by about 2 times. The grains of the coating can be refined, the surface quality can be improved, the surface is smoother,and spangles are finer. An even and dense coating structure is obtained, coating missing is reduced, and therefore the corrosion resistance and machining performance of the coating are effectively improved.

Description

technical field [0001] The invention belongs to the technical field of anticorrosion of metal materials, and in particular relates to an aluminum-zinc-silicon-zirconium hot-dipping alloy used for anticorrosion on the surface of steel materials and a dipping process thereof. Background technique [0002] With the increasing demand for high-performance corrosion-resistant metal materials in society, the corrosion-resistant standards of metal materials have been continuously improved, and the hot-dip aluminum and hot-dip galvanizing coating processes have gradually failed to meet the service requirements under some special conditions. The A155Zn43.5Si1.5 coating combines the advantages of hot-dip aluminum and hot-dip galvanizing. It has the characteristics of smooth surface, bright luster, regular grain pattern, uniform spangle, good heat resistance and corrosion resistance, and has a large area Promote apps. The coating structure of A155Zn43.5Si1.5 consists of Al-rich dendrit...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C2/12C22C21/10
CPCC22C21/10C23C2/12
Inventor 周国荣韩鹤程吴燕秋滕新营张明明邵辰韩凯洋刘君珂
Owner UNIV OF JINAN