Protease resistant lipidated glp-1 analog
A kind of medicine and composition technology, applied in the field of protease-resistant lipidated GLP-1 analogs
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[0255] Example 1: Chemical Synthesis and Testing of Proteolysis-Resistant Lipidated Peptides
[0256] 1 Introduction
[0257] Exemplary methods for preparing proteolysis resistant peptides as described herein are provided below.
[0258] 2. Abbreviation
[0259] Boc, tert-butoxycarbonyl; DCM, dichloromethane; DIPEA, N,N-diisopropylethylamine; DMF, N,N-dimethylformamide; DMSO, dimethylsulfoxide; EK, enterokinase ; ESI, electrospray ionization; Fmoc, 9-fluorenylmethoxycarbonyl; GIP, gastric inhibitory polypeptide; GLP-1, glucagon-like peptide-1; HCTU, O-(1H-6-chlorobenzotri Azol-1-yl)-1,1,3,3-tetramethyluronium hexafluorophosphate; RP-HPLC, reversed-phase high performance liquid chromatography; EC 50, half maximum (50%) effective concentration; LC / MS, mass spectrometry coupled to liquid chromatography; MeCN, acetonitrile; Mmt, 4-methoxytrityl; NMP, N-methylpyrrolidone; ,2,4,6,7-pentamethyldihydrobenzofuran-5-sulfonyl; PBS, phosphate-buffered saline; t Bu, tert-butyl; TFA, t...
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