Preparation method of nanometer modified polyurea waterproof coating

A nano-modified polyurea and waterproof coating technology, which is applied in the field of coating preparation, can solve problems such as low adhesion, low strength, and poor substrate wettability, and achieve improved wetting performance, improved compatibility, and enhanced reactivity Effect

Inactive Publication Date: 2018-07-13
陈毅忠
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology relates to improved aqueous polyurethane (PU) waterproof paints made up mainly of Poly(Aspirant)-Polyimino Acrylate), Ammonium Sulfite NH2 salt, Borax hydride soluble compound, Copper Nitrone Solvent Extrudable Spray Paint Exposion Kit or Colored Hydrogel Layer Composites for better durability against corrosive environments such as seawater. Additionally, this innovative process involves adding special chemical substances called stabilizers into the mixture beforehand, resulting in more effective dispersion of nanoparticles throughout the paint film. Overall these improvements enhance its properties over existing products while maintain their benefits compared to previous ones.

Problems solved by technology

In this patented new method called NANOXI (Nearly Nonreactive Water) that combines certain chemical reactions together to create polymers made up mostly of urea molecules without harmful substances like chlorine gas. These chemically crosslinked materials exhibiting excellent performance such as durable hardness, impermeability against environmental factors including rainwater leakage, moisture absorption, heat insulation, flexibility under tension, etc. They allow for easy application onto various surfaces while maintain their effectiveness over long periods due to its unique structure.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0028] Slowly add 16g of diethyl maleate dropwise into 85g of polyetheramine D2000, and stir for 16min at a temperature of 45°C under nitrogen protection. To obtain polyaspartic acid ester, mix MDI-50 and polyether D2000 in a beaker according to an equal mass ratio, stir at room temperature for 10 minutes under nitrogen protection, then heat up to 75°C, keep it warm for 2 hours, and cool it out 24g of scallop shells were weighed and put into a ball mill jar with 4g of zirconia, mixed and ball milled for 2 hours and passed through a 100-mesh sieve to collect ball mill shell powder, and zinc nitrate, Mix and stir the ball-milled shell powder and distilled water for 10 minutes to obtain a suspension, measure 80 mL of the suspension, then add dropwise 5 mL of sodium hydroxide solution with a concentration of 4 mol / L to the suspension and mix and stir for 4 minutes to obtain a mixed solution; then add 3 g of anhydrous Sodium carbonate and 1g of sodium lauryl sulfate were mixed and ...

example 2

[0030] Slowly add 18g of diethyl maleate into 90g of polyetheramine D2000 dropwise, and stir for 18min at a temperature of 55°C under the protection of nitrogen. To obtain polyaspartic acid ester, mix MDI-50 and polyether D2000 in a beaker according to the same mass ratio, stir at room temperature and nitrogen protection for 11min, then heat up to 80°C, keep warm for 3h, cool and discharge , to obtain the prepolymer; weigh 28g of scallop shells and put them into a ball mill tank with 5g of zirconia, mix and mill them for 3 hours, then pass through a 100-mesh sieve, collect the ball-milled shell powder, and mix zinc nitrate and ball mill with a mass ratio of 1:2:5 Shell powder and distilled water were mixed and stirred for 11 minutes to obtain a suspension, and 90 mL of the suspension was measured, and then 6 mL of sodium hydroxide solution with a concentration of 4 mol / L was added dropwise to the suspension, and the mixture was stirred for 5 minutes to obtain a mixed solution; ...

example 3

[0032] Slowly add 20g of diethyl maleate into 95g of polyetheramine D2000 dropwise, and stir for 20min at a temperature of 60°C under the protection of nitrogen. To obtain polyaspartic acid ester, mix MDI-50 and polyether D2000 in a beaker according to an equal mass ratio, stir at room temperature and under nitrogen protection for 12 minutes, then heat up to 85°C, keep warm for 4 hours, and cool and discharge , to obtain the prepolymer; weigh 32g of scallop shells and put them into a ball mill tank with 6g of zirconia, mix and mill them for 4 hours, pass through a 100-mesh sieve, collect the ball-milled shell powder, and mix zinc nitrate and ball mill with a mass ratio of 1:2:5 Shell powder and distilled water were mixed and stirred for 12 minutes to obtain a suspension, and 100 mL of the suspension was measured, and then 7 mL of sodium hydroxide solution with a concentration of 4 mol / L was added dropwise to the suspension, and mixed and stirred for 6 minutes to obtain a mixed ...

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PUM

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Abstract

The invention discloses a preparation method of a nanometer modified polyurea waterproof coating, and belongs to the technical field of preparation of coatings. The preparation method comprises the following steps of mixing diethyl maleate and polyether amine D2000, mixing MDI-50 and polyether D2000, and stirring to react, so as to obtain a pre-polymer, wherein a plant extracting solution containsa plurality of conjugated double bond systems with stronger ability of providing electron pairs. The preparation method has the advantages that the nanometer zinc oxide powder is uniformly dispersedto the surface of a substrate under the polarity adsorption function of the plant extracting solution, and the energy gap width of the nanometer zinc oxide powder is 4.5eV and is equivalent to the energy of most of ultraviolet rays, so as to reduce the strength of ultraviolet rays in the radiation direction; the calcium carbonate crystals in scallop shell powder are crossly and densely stacked, the nanometer zinc oxide is promoted to be filled into the scallop shell powder, and a concentrated solution containing lecithin is continued to add, so that the interface tension of water is reduced; the wetting property of the solid/liquid system is changed, the wetting property of the polyurea waterproof coating is improved, and the application prospect is broad.

Description

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Claims

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Application Information

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Owner 陈毅忠
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