Dry/wet wipable whiteboard pen ink and preparation method thereof

A pen-ink and whiteboard technology, applied in ink, household utensils, applications, etc., can solve the problems of affecting secondary writing, ink is not easy to dry, difficult to erase, etc., and achieves the effect of convenient dry erasing, easy wiping, and low surface tension

Inactive Publication Date: 2018-08-28
赵顺全
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is to provide a dry / wet erasable whiteboard pen ink and its preparation method for the ink that uses water as a solvent is not easy to dry, difficult to erase, and affects secondary writing.

Method used

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  • Dry/wet wipable whiteboard pen ink and preparation method thereof

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Embodiment Construction

[0021] Take 10~12g carbon black into 100~120mL deionized water, stir and mix at 300~400r / min for 20~30min, and adjust the pH to 13~14 with a mass fraction of 20% sodium hydroxide solution, then transfer it to the rotary evaporator Evaporate to dryness to obtain pretreated carbon black. Take 10~12g of pretreated carbon black and put it into the autoclave, continue to inject ozone until the pressure in the autoclave is 10~12MPa, keep the pressure and react for 3~5h, then turn on the high pressure Reactor valve, quickly release the pressure to normal pressure and then take it out to obtain the reactant. Soak the reactant in 300-360mL deionized water for 20-30 minutes, and adjust the pH to 3 to 4 with 10% hydrochloric acid, and then transfer to centrifugation. Centrifugal separation in the machine at 5000~6000r / min, collect the precipitate, wash the precipitate with deionized water 2~3 times, place it in a vacuum drying oven, and dry it to constant weight at 105~110℃ to obtain oxidi...

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Abstract

The invention relates to dry/wet wipable whiteboard pen ink and a preparation method thereof, and belongs to the technical field of fine chemical engineering. The preparation method is characterized by comprising the following steps: fully infiltrating carbon black by using high-pressure liquefied ozone and carrying out surface oxidation modification on the carbon black by utilizing the strong oxidizing action of ozone; introducing hydrophilic oxygen-containing groups such as carboxyl and hydroxyl to the surface of the carbon black, thereby improving the wettability of the carbon black and improving the dispersion stability of the carbon black in an aqueous solution; opening a high-pressure reactor valve to generate instantaneous gasification expansion and high pressure; enabling the pressure generated by ozone expansion to act on a part between carbon black layers to produce cracks; expanding original cracks and breaking into fine fragments; meanwhile, expanding interlamellar spacingfor enabling additives and water molecules to be easily infiltrated into an interlayer, and further improving the dispersion performance in the water and the wiping effect. The dry/wet wipable whiteboard pen ink disclosed by the preparation method disclosed by the invention has the advantages of stable properties of writing fluid, fluent writing, convenience in dry wiping, better wet wiping effect, no peculiar odor and suitability for writing of commercially-available whiteboards.

Description

Technical field [0001] The invention relates to a dry / wet erasable whiteboard pen ink and a preparation method thereof, belonging to the technical field of fine chemicals. Background technique [0002] The research and development of whiteboard pen ink began in the 1950s. Currently, alcohol and water are used as the main solvents, in line with the theme of the era of environmental protection, dust-free, and erasable. Some ink brands such as South Korea’s Aisilian and German Wendu are world leaders in the manufacturing of high-end inks. The whiteboard pen inks they produce are not only smooth in writing, bright in color, but also uniform in ink, and the handwriting can last for a long time. Up to several months. The research and development of domestic whiteboard pen inks started late, and the current production is still relatively backward, the preparation process is complicated, and the technical content is low. The recent invention patent uses water as the solvent, which is e...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/17C09D11/16
CPCC09D11/16C09D11/17
Inventor 赵顺全王文新史玉玲
Owner 赵顺全
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