Anode materials for lithium battery of improved temperature performance
A technology for lithium-ion batteries and composite anodes, applied in battery electrodes, active material electrodes, negative electrodes, etc., can solve problems such as low energy density, low conductivity, and high processing costs
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Embodiment 1
[0057] As the anode material, graphite capped with 5% by weight LTO particles and with an average particle size of 10 μm, Super P as the conductive material, and polyvinylidene fluoride (PVDF) as the binder were used in a weight ratio of 90:5:5 After mixing, N-methylpyrrolidone (NMP) was added to the mixture to prepare a slurry. The slurry was stirred vigorously with an overhead stirrer for about 2 hours. The prepared anode slurry was coated on a copper current collector by a doctor blade to form a film, and then the film was dried in a vacuum oven at 90° C., thereby manufacturing an anode.
[0058] LiCoO as the cathode active material 2 , Super P as a conductive material and PVDF as a binder were mixed in a weight ratio of 94:3:3, and then the mixture was dispersed in N-methylpyrrolidone (NMP). The prepared dispersion liquid was coated on an aluminum foil by a doctor blade, and then dried in a vacuum oven at 90° C. to manufacture a cathode.
Embodiment 2
[0061] To modify the surface of carbon-based material particles, graphite was added into a 65 wt% nitric acid bath, and then the slurry was stirred at 500 rpm for 24 hours using a magnetic stirrer. Finally, the carbon-based material particles in nitric acid were collected by filter paper, washed 3 times with deionized water, and then dried.
[0062] A secondary lithium battery was fabricated in the same manner as in Example 1, but using the carbon-based material particles pretreated with 65 wt% nitric acid mentioned in this paragraph as the anode material.
[0063] For any figure or range of values for a given characteristic, a figure or parameter from one range can be combined with another figure or parameter from a different range of the same characteristic to produce a range of values.
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