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Pumping impervious super-set-retarding concrete and preparation method thereof

An ultra-retarding and concrete technology, applied in the field of building materials, can solve problems such as prolonging, not affecting the later strength of concrete, retarding admixtures not meeting the requirements, etc., and achieving the effect of qualified strength

Inactive Publication Date: 2018-09-28
JIANGSU BAIRUIJI NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the hot summer mass concrete construction and bored occlusal pile projects, a large amount of concrete is poured continuously. For example, in some projects, it is required that the pile body concrete of the bored piles that have been poured in the previous stage be able to Carry out a proper amount of drilling, so that the subsequent construction of the drilled pile and the pre-constructed bored pile can be integrated into a whole. In response to these special needs in the construction, the setting time of the concrete is required to be extended to more than 60h, and the later stage of the concrete cannot be affected. In order to meet the requirements of this type of construction technology, ordinary retarding admixtures can no longer meet the requirements when concrete is mixed.

Method used

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  • Pumping impervious super-set-retarding concrete and preparation method thereof
  • Pumping impervious super-set-retarding concrete and preparation method thereof
  • Pumping impervious super-set-retarding concrete and preparation method thereof

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Effect test

Embodiment 1

[0013] The preparation of embodiment 1 ultra-retarded pumping agent

[0014] 1) Under nitrogen protection conditions, 400g ethyl acetate is added in the reactor of 1L, then reactor is cooled to 5 ℃, then adds dodecylbenzenesulfonic acid 326g (1.0mol) in reactor, then in Under the control of the flowmeter, slowly introduce 8.5g (0.5mol) of anhydrous ammonia gas into the reaction kettle within 1h. After the ammonia gas is introduced, continue the reaction at 5°C for 1-2h, then stop cooling, and the reaction solution will naturally warm up to room temperature. The reaction was continued for 48 hours. After the reaction was completed, an ethyl acetate solution of didodecylbenzenesulfonimide was obtained.

[0015] 2) Place the ethyl acetate solution of didodecylbenzenesulfonimide obtained in the previous step in a 1L reaction flask, cool it to 0-5°C with an ice-water bath, and slowly add 0.3mol of it dropwise while stirring / L of potassium hydroxide solution, the pH value of the s...

Embodiment 2

[0017] 1) Under nitrogen protection conditions, 400g ethyl acetate is added in the reactor of 1L, then reactor is cooled to 5 ℃, then adds dodecylbenzenesulfonic acid 326g (1.0mol) in reactor, then in Under the control of the flow meter, slowly introduce 8.5g (0.5mol) of anhydrous ammonia gas into the reaction kettle within 1h. After the ammonia gas is introduced, continue the reaction at 5°C for 1-2h, then stop cooling, and let the reaction solution warm up to room temperature naturally. , Continue to react for 48h, after the reaction is finished, the ethyl acetate solution of didodecylbenzenesulfonimide is obtained.

[0018] 2) Put the ethyl acetate solution of didodecylbenzenesulfonimide obtained in the previous step into a 1L reaction flask, cool it to 0-5°C with an ice-water bath, and slowly add 0.3mol of it dropwise while stirring / L of sodium hydroxide solution, the pH value of the solution is adjusted to 7, then the solution is placed in a separatory funnel for phase s...

Embodiment 3

[0020] A pumping anti-seepage super retarded concrete, its batching is shown in Table 1;

[0021] Table 1 Pumping anti-seepage super retarded concrete mix ratio (kg / m3)

[0022]

[0023]

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Abstract

The invention discloses pumping impervious super-set-retarding concrete. The pumping impervious super-set-retarding concrete is prepared from, by weight, 1 part of cement, 1-2 parts of mineral powder,2-3 parts of medium sand, 3-4 parts of gravel, 0.6-0.7 part of water and 0.02-0.03 part of super-set-retarding pumping agent. A preparation method of the super-set-retarding pumping agent includes the steps that dodecylbenzene sulfonic acid and ammonia gas react in an organic solvent, after obtained reaction liquid of bis-dodecyl benzenesulfonimide is neutralized with alkaline matter, static layering is carried out, organic phases are removed, obtained water phases are concentrated and dried, and the pumping impervious super-set-retarding concrete is obtained. The alkaline matter is one of potassium hydroxide, sodium hydroxide, potassium carbonate and sodium carbonate. The newly-developed super-set-retarding concrete replaces an existing common set-retarding pumping agent, the set-retarding time initial set of the concrete is longer than 65 hours, the final set is shorter than 80 hours, later strength is achieved, and the strength of 28 d is qualified.

Description

technical field [0001] The invention relates to building materials, in particular to a pumping anti-seepage super retarded concrete and a preparation method thereof. Background technique [0002] In the hot summer mass concrete construction and bored occlusal pile projects, a large amount of concrete is poured continuously. For example, in some projects, it is required that the pile body concrete of the bored piles that have been poured in the previous stage be able to Carry out a proper amount of drilling, so that the subsequent construction of the drilled pile and the pre-constructed bored pile can be integrated into a whole. In response to these special needs in the construction, the setting time of the concrete is required to be extended to more than 60h, and the later stage of the concrete cannot be affected. In order to meet the requirements of this kind of construction technology, ordinary retarding admixtures can no longer meet the requirements when concrete is mixed...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/04C04B111/27
CPCC04B28/04C04B2111/00146C04B2111/27C04B2201/50C04B14/02C04B14/06C04B18/12C04B24/20
Inventor 王亚军卢祎
Owner JIANGSU BAIRUIJI NEW MATERIAL
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